Timo Ruskeeniemi

U-series disequilibria in a groundwater flow route as an indicator of uranium migration processes

U-series data relating to groundwater, fracture coatings and the adjoining rock matrix in a groundwater flow system at the Palmottu natural analogue site was examined. The aim was to obtain an experimental reference for migration modelling in a transport section defined within the flow system. The U-series reference obtained turned out to be a very useful tool for fine tuning the flow route and for migration mechanism considerations. The U-series data are well in line with other interpretations of the migration system.

LiDAR DEM detection and classification of postglacial faults and seismically-induced landforms in Finland: a paleoseismic database

Abstract During the last decades, postglacial faults (PGFs) have been found in northern Fennoscandia, the first fault scarps being discovered in western Finnish Lapland in the 1960s. With LiDAR-based digital elevation models (DEMs), a new and accurate remote sensing mapping methodology has been acquired. It allows the relatively rapid and low-cost detection and mapping of late- or PGFs and, for instance, mapping of landslides from areas where they have not previously been recognized. We describe the approach of the Geological Survey of Finland to the systematic search for (screening) and mapping of PGFs, paleolandslides, and other morphological features of Quaternary deposits related to post- and late-glacial seismic activity in Finland. The observations have been collected and classified into a file geodatabase with ArcGis (© ESRI) using a procedure that includes several steps. We also provide examples from western and northern Finland of how sites of late- and postglacial fault scarps and landslides have been detected and described from LiDAR DEM data.

Hydrogeology, Chemical and Microbial Activity Measurement Through Deep Permafrost

Little is known about hydrogeochemical conditions beneath thick permafrost, particularly in fractured crystalline rock, due to difficulty in accessing this environment. The purpose of this investigation was to develop methods to obtain physical, chemical, and microbial information about the subpermafrost environment from a surface-drilled borehole. Using a U-tube, gas and water samples were collected, along with temperature, pressure, and hydraulic conductivity measurements, 420 m below ground surface, within a 535 m long, angled borehole at High Lake, Nunavut, Canada, in an area with 460-m-thick permafrost. Piezometric head was well above the base of the permafrost, near land surface. Initial water samples were contaminated with drill fluid, with later samples <40% drill fluid. The salinity of the non-drill fluid component was <20,000 mg/L, had a Ca/Na ratio above 1, with δ(18) O values ∼5‰ lower than the local surface water. The fluid isotopic composition was affected by the permafrost-formation process. Nonbacteriogenic CH(4) was present and the sample location was within methane hydrate stability field. Sampling lines froze before uncontaminated samples from the subpermafrost environment could be obtained, yet the available time to obtain water samples was extended compared to previous studies. Temperature measurements collected from a distributed temperature sensor indicated that this issue can be overcome easily in the future. The lack of methanogenic CH(4) is consistent with the high sulfate concentrations observed in cores. The combined surface-drilled borehole/U-tube approach can provide a large amount of physical, chemical, and microbial data from the subpermafrost environment with few, controllable, sources of contamination.

Challenges for Coring Deep Permafrost on Earth and Mars

A scientific drilling expedition to the High Lake region of Nunavut, Canada, was recently completed with the goals of collecting samples and delineating gradients in salinity, gas composition, pH, pe, and microbial abundance in a 400 m thick permafrost zone and accessing the underlying pristine subpermafrost brine. With a triple-barrel wireline tool and the use of stringent quality assurance and quality control (QA/QC) protocols, 200 m of frozen, Archean, mafic volcanic rock was collected from the lower boundary that separates the permafrost layer and subpermafrost saline water. Hot water was used to remove cuttings and prevent the drill rods from freezing in place. No cryopegs were detected during penetration through the permafrost. Coring stopped at the 535 m depth, and the drill water was bailed from the hole while saline water replaced it. Within 24 hours, the borehole iced closed at 125 m depth due to vapor condensation from atmospheric moisture and, initially, warm water leaking through the casing, which blocked further access. Preliminary data suggest that the recovered cores contain viable anaerobic microorganisms that are not contaminants even though isotopic analyses of the saline borehole water suggests that it is a residue of the drilling brine used to remove the ice from the upper, older portion of the borehole. Any proposed coring mission to Mars that seeks to access subpermafrost brine will not only require borehole stability but also a means by which to generate substantial heating along the borehole string to prevent closure of the borehole from condensation of water vapor generated by drilling.

Characterization of the Altered Zone Around a Fracture in Palmottu Natural Analogue

A drill core sample penetrating at a natural fracture has been analysed by helium gas techniques and by α-autoradiography. Porosity and diffusivity profiles away from the fracture have been determined and compared with structural profiles. Model calculations are used to determine the effects of sample size on the measured porosities and diffusivities.

Selective extractions in uranium migration studies—findings from a natural analogue study at Palmottu, southern Finland

The usefulness of chemical extractions in the study of uranium migration through fractured rock is considered in the light of the results of a natural analogue study conducted at Palmottu in southern Finland. Chemical extractions provide a method for producing information of the mass transfer of U and its fixation in geochemical cycling. The present detailed study provides more specific information on the fixation of U on silicate material and its sorption in rock pores. The many observations made at the Palmottu study site show the potential of the method for filling the gap in interpretations between the natural partitioning of U as a results of water-rock interaction and the distribution of artificial tracers determined by the short-term laboratory experiments.

Release of uranium from rock matrix--a record of glacial meltwater intrusions?

Uranium release observed in a rock matrix around water-carrying fractures was studied using U-series disequilibrium (USD) modelling and mass balance calculations. Several release scenarios were tested, with specific attention to the glacial aspects. The release appears to have occurred in two or three violent episodes during the last 300 ky. A release after the last glaciation can be excluded on mass flow grounds. Continuous release for more than 300 ky can be excluded on radioactive disequilibrium grounds. Repeated inflows of oxic glacial meltwater seem to have triggered the release episodes.

Dating of paleolandslides in western Finnish Lapland: Dating of paleolandslides in western Finnish Lapland

The dating of landslide-buried organic materials potentially indicates non-stationary seismicity in northern Finland attributable to the release of lithospheric stresses during and after retreat of the Scandinavian Ice Sheet. The landslide age data reveals three episodes of increased slope instability and formation of landslides, from 9000 to 11 000 cal BP, from 5000 to 6000 cal BP, and from 1000 to 3000 cal BP. While a seismogenic origin cannot be unequivocally established, we interpret that at least the early Holocene episode reflects increased seismic activity in northern Finland in association with late-glacial and postglacial faulting. The foci of slope instabilities changes through time, implying that different segments of the postglacial fault systems were active at different times during the Holocene. We also show that the correlation of landslide ages with the surface roughness and backwall slope is complicated. The morphology of landslide scarps is significantly affected by thickness of glacial sediments, liquefaction during landslide formation, and accumulation of peat upon landslide scars and deposits, and thus, the time-dependent erosional smoothing of the surfaces should be considered as descriptive and non-qualitative. Copyright

Uranium mineral - groundwater equilibration at the Palmottu natural analogue study site, Finland

The redox-potential, pH, chemical composition of fracture waters, and uraninite alteration associated with the Palmottu uranium mineralization, have been studied. The data have been interpreted by means of thermodynamic calculations. The results indicate equilibrium between uraninite, ferric hydroxide and groundwater in the bedrock of the study site. Partially oxidized uraninite (UO{sub 2.33}) and ferric hydroxide are in equilibrium with the fresh, slightly acidic and oxidized water type, while primary uraninite is stable with deeper waters that have a higher pH and lower Eh. Measured Eh-pH values of groundwater cluster within a relatively narrow range indicating buffering by heterogeneous redox-processes. A good consistency between measured Eh and analyzed uranium oxidation states was observed.

A landscape-isotopic approach to the geochemical characterization of lakes in the Kangerlussuaq region, west Greenland

ABSTRACT In west Greenland, an approximate chronosequence of landscape evolution and weathering exists between the coast, which has been ice free for long periods, and more recently deglaciated areas along the present day ice margin. Traditional geochemical and isotopic analyses (δ18O, δ2H, 3H, δ34S/δ18O (SO4), and 87Sr/86Sr) along with novel isotopic tools, such as δ37Cl and δ81Br, were used to provide new insights into lake geochemical processes along a transect of lakes from the coast to the ice margin in the Kangerlussuaq region. Evaporation was found to be a key process impacting lake chemistry and isotopic signatures in the ice marginal area, with decreasing importance toward the coast. Evaporative processes were apparent in the δ37Cl and δ81Br isotopic signatures of lake-water chemistry. Consistent with previous work elsewhere (e.g., Blum and Erel, 1995) on increased biotite weathering in glaciated environments, 87Sr/86Sr isotopic ratios were found to be more radiogenic (>0.73) in lakes found in more recently glaciated terrain. Sulfide oxidation was the main source of sulfur (as sulfate) in lakes in the ice marginal area, while the influence of marine aerosols and bacterial sulfate reduction increased further away from the ice sheet around the fjord Kangerlussuaq. Groundwater discharge significant enough to impact lake chemistry was not observed in any of the lakes studied, suggesting that little groundwater–surface water interaction occurs in the study area or that recharge conditions are present in the majority of the lakes studied.