Timothy G. Haskell

Platelet ice and the land-fast sea ice of McMurdo Sound, Antarctica

Abstract Dendritic crystals of platelet ice appear beneath the columnar land-fast sea ice of McMurdo Sound, Antarctica. These leaf-like crystals are frozen into place by the advancing columnar growth. The platelets most probably begin to appear during July although in some parts of the Sound they may not appear at all. In addition, the amount and extent of platelet ice within the Sound varies from year to year. Previous authors have suggested that the formation of platelet ice is linked to the presence of the nearby ice shelf. It is a matter of debate whether these platelets form at depth and then float upwards or whether they grow in slightly supercooled water at the ice/water interface. The phenomenon is similar to that observed in the Weddell Sea region, but previous authors have suggested the two regions may experience different processes. This paper presents the results of field-work conducted in McMurdo Sound in 1999. Ice-structure analysis, isotopic analysis and salinity and temperature measurements near the ice/water interface are presented. Freezing points are calculated, and the possible existence of supercooling is discussed in relation to existing conjectures about the origin of platelets.

A simple, novel method for the preparation of polymer-tetherable, zwitterionic merocyanine NLO-chromophores

A suite of polymer-ready nonlinear optical merocyanines has been synthesised and characterised. The tethering functionality—a vicinal dihydroxypropyl residue—is introduced onto the donor nitrogen of the chromophore precursor without the need for protection/deprotection steps, thereby giving ready access to potentially high Tg condensation polymer systems. An X-ray crystal structure determination on a representative chromophore 5 confirms the largely zwitterionic nature of these systems and experimental measurements of second-order nonlinear response [β(0)], by hyper-Raleigh scattering, indicate that a pyridylidene donor–quinomethide acceptor combination gives rise to the largest nonlinearity.

Simple zwitterionic merocyanines as potential NLO chromophores

A suite of zwitterionic pyridylidene-based merocyanines that contain no interconnecting π-bridge between the donor and acceptor rings has been synthesised and their second-order NLO properties evaluated largely by semi-empirical computational methods (MOPAC 97/AM1). Contrary to expectation, increasing the degree of inter-ring twist (θ), at least up to 55°, in these new pyridylideneazolone chromophores is found to have little or no effect on the figure of merit [μβ(0)]. An X-ray crystallographic appraisal of one of these chromophores, 14, reveals however that the twist angle (albeit in the solid state) is greater than that predicted by computation and that all other features are consistent with the highly zwitterionic nature of these systems. In spite of this, a combination of factors—insufficient acceptor strength, insufficient extent of conjugation and perhaps insufficient twist angle, in particular—clearly leads to the low values of the quadratic hyperpolarisabilities. The trade-off between targeting a more modest β from a minimum of π-conjugating framework between D and A (and therefore synthetic expediency) and seeking a moderate-to-high dipole moment has therefore resulted in only low figures of merit for these systems.Calculations performed on a suite of readily accessible, isoelectronic cyanines, in which the acceptor is a stabilised cyclopentadienide carbocycle rather than a heterocycle, have revealed the potential that these systems, exemplified by 27, have as NLO chromophores. Representative polymer-tetherable derivatives of this system have been prepared as have the corresponding TDI-based polyurethanes.

Lifetime estimation for a land-fast ice sheet subjected to ocean swell

Abstract It is well known that an incoming ocean swell produces a strain field in a land-fast ice sheet. The attenuation and spectral content of this strain field can be calculated and has been measured. The response of the sea ice to this type of cyclic forcing has also been measured, and in particular we are able to estimate the number of cycles to failure for sea ice loaded at constant amplitude. In this paper we consider the response of the land-fast ice sheet or vast floe to a measured ice-coupled wave field of variable amplitude. We use the Palmgren-Miner cumulative damage law and stress-lifetime curves taken from field experiments to predict the lifetime of the sea-ice sheet as a function of significant wave height and sea-ice brine fraction. Calculations are performed to account for the swell entering a land-fast sea-ice sheet at arbitrary angle, and the influence of c-axis alignment and the presence of pre-existing cracks are discussed.

Heat transport in McMurdo Sound first‐year fast ice

We have monitored the temperature field within first-year sea ice in McMurdo Sound over two winter seasons, with sufficient resolution to determine the thermal conductivity from the thermal waves propagating down through the ice. Data reduction has been accomplished by direct reference to energy conservation, relating the rate of change of the internal energy density to the divergence of the heat current density. Use of this procedure, rather than the wave attenuation predicted by the thermal diffusion equation, avoids difficulties arising from a strongly temperature dependent thermal diffusivity. The thermal conductivity is an input parameter for ice growth and climate models, and the values commonly used in the models are predicted to depend on temperature, salinity, and the volume fraction of air. The present measurements were performed at depths in the ice where the air volume is small and the salinity is nearly constant, and they permit the determination of the absolute magnitude of the thermal conductivity and its temperature dependence. The weak temperature dependence is similar to that predicted by the models in the literature, but the magnitude is smaller by ∼10% than the predicted value most commonly used in climate and sea ice models. In the first season we find an additional scatter in the results at driving temperature gradients larger than ∼10–15 °C/m. We suggest that the scatter arises from a nonlinear contribution to the heat current, possibly associated with the onset of convective motion in brine inclusions. Episodic convective events are also observed. We have further determined the growth rate of the ice and compared it with the rate explained by the heat flux from the ice-water interface. The data show a sudden rise of growth rate, without a rise in heat flux through the ice, which coincides in time and depth with the appearance of platelet ice. Finally, we discuss the observation of radiative solar heating at depth in the ice and demonstrate that the absorption exceeds that in the ice alone; dust or algae must contribute to the absorption.

Evolution of supercooling under coastal Antarctic sea ice during winter

Abstract Here we describe the evolution through winter of a layer of in situ supercooled water beneath the sea ice at a site close to the McMurdo Ice Shelf. From early winter (May), the temperature of the upper water column was below its surface freezing point, implying contact with an ice shelf at depth. By late winter the supercooled layer was c. 40 m deep with a maximum supercooling of c. 25 mK located 1–2 m below the sea ice-water interface. Transitory in situ supercooling events were also observed, one lasting c. 17 hours and reaching a depth of 70 m. In spite of these very low temperatures the isotopic composition of the water was relatively heavy, suggesting little glacial melt. Further, the waters temperature-salinity signature indicates contributions to water mass properties from High Salinity Shelf Water produced in areas of high sea ice production to the north of McMurdo Sound. Our measurements imply the existence of a heat sink beneath the supercooled layer that extracts heat from the ocean to thicken and cool this layer and contributes to the thickness of the sea ice cover. This sink is linked to the circulation pattern of the McMurdo Sound.

Evolution of a supercooled Ice Shelf Water plume with an actively growing subice platelet matrix

We use new observations in Western McMurdo Sound, combined with longitudinal hydrographic transects of the sound, to identify a northward-flowing Ice Shelf Water (ISW) plume exiting the cavity of the McMurdo-Ross Ice Shelf. We estimate the plumes net northward transport at 0.4 ± 0.1 Sv, carving out a corridor approximately 35 km wide aligned with the Victoria Land Coast. Basal topography of the McMurdo Ice Shelf is such that the plume is delivered to the surface without mixing with overlying warmer water, and is therefore able to remain below the surface freezing temperature at the point of observation beneath first-year ice. Thus, the upper ocean was supercooled, by up to 50 mK at the surface, due to pressure relief from recent rapid ascent of the steep basal slope. The 70 m thick supercooled layer supports the growth and maintenance of a thick, semirigid, and porous matrix of platelet ice, which is trapped by buoyancy at the ice-ocean interface. Continued growth of individual platelets in supercooled water creates significant brine rejection at the top of the water column which resulted in convection over the upper 200 m thick, homogeneous layer. By examining the diffusive nature of the intermediate water between layers of ISW and High Salinity Shelf Water, we conclude that the ISW plume must have originated beneath the Ross Ice Shelf and demonstrate that it is likely to expand eastward across McMurdo Sound with the progression of winter.

Thermal and optical properties of polymer hosts for solid-state dye lasers

We present measurements of thermal and optical properties of poly(methyl methacrylate) (PMMA), PMMA modified by the addition of ethanol (MPMMA), and copolymers of methyl methacrylate with 2-hydroxyethyl methacrylate [P(HEMA:MMA)]. Spectral transmission of the polymers is excellent (alpha = 0.5 cm(-1) at 400 nm, decreasing to 0.04 cm(-1) at 633 nm). Measured laser damage thresholds of MPMMA and P(HEMA:MMA) show at least a twofold increase over PMMA. Thermal lensing measured in these hosts doped with Rhodamine 6G is shown to be similar (f = -450 mm for pump power of 200 mW in a 2-mm-diameter spot, scaling with pump intensity). Compared with MPMMA, P(HEMA:MMA) offers an improved surface quality and a more uniform dye distribution.

Impact of the B-15 iceberg “stranding event” on the physical and biological properties of sea ice in McMurdo Sound, Ross Sea, Antarctica

Abstract Ice cores were sampled at four stations in McMurdo Sound (Ross Sea) between 1999 and 2003. At the beginning of year 2000, a very large iceberg (B-15) detached itself from the Ross Ice Shelf and stranded at the entrance of the Sound, preventing the usual oceanic circulation purging of the annual sea ice cover from this area. Ice textural studies showed that a second year sea ice cover was built-up at three out of the four stations: ice thickness increased to about 3 m. Repeated alternation of columnar and platelet ice appeared, and bulk salinity showed a strong decrease, principally in the upper part of the ice sheet, with associated brine volume decrease. Physical modification influenced the biology as well. By decreasing the light and space available for organisms in the sea ice cover, the stranding of B-15 has i) hampered autotrophic productivity, with chlorophyll a concentration and algae biomass significantly lower for second year ice stations, and ii) affected trophic relationships such as the bacterial biomass/chl a concentration correlation, or the autotrophic to heterotrophic ratio.

Dynamic strain response of lake and sea ice to moving loads

Abstract The results from two experiments to measure the strains due to a vehicle moving over ice are discussed in the context of theoretical work derived from existing solutions in the literature. The experiments took place on two very different types of ice; the lake ice of Femund in Norway, and sea ice near Scott Base in the Antarctic. In both cases, strain was measured directly by means of strainmeters developed specifically for use on ice. The existence of a critical velocity at which the strain is resonant is discussed, and using values derived from the data, a dispersion equation for free waves is solved in the super-critical domain to provide wavelength estimates. At subcritical speeds a moving static load calculation provides the equivalent theory. The experimental results for lake ice and sea ice are similar, although some differences do exist. The magnification factor of the critical strain over static strain is, for example, larger for lake ice (2.25) than for sea ice (1.45). A critical velocity of 15.2 ms−1 was observed for lake ice, for sea ice the value was 19.6 ms−1; both are associated with the minimum phase velocity of free wave propagation.