Tingguang Liu

Three-dimensional geometrical and topological characteristics of grains in conventional and grain boundary engineered 316L stainless steel

The three-dimensional microstructures of a conventional 316L stainless steel and the same material after grain boundary (GB) engineering have been measured by serial sectioning coupled with electron backscatter diffraction mapping. While it is well known that GB engineered materials are differentiated from conventional materials because of the proportion of coincidence site lattice boundaries, the size of their twin-related domains, and their reduced random boundary connectivity, this work provides a quantitative comparison of the geometrical and topological characteristics of grains in 316L stainless steel before and after GB engineering. Specifically, the numbers of grain faces, triple lines, and quadruple unions per grain have been measured and compared. In addition, the distributions of grain sizes, surface areas, and grain boundary areas have been measured and compared. The results show that, in many ways, the three-dimensional geometrical and topological characteristics of the grains in the GB engineered and conventional materials are similar. In both materials, the distributions of the geometrical parameters are well represented by a log-normal distribution. Comparatively, the GB engineered microstructure has grains that, on average, have both fewer faces and higher (specific) surface areas that deviate more from an ideal equiaxed shape, but there are several eccentric or non-compact shaped grains that have a huge number of faces and extremely large surface area in the GB engineered material. All of these characteristics are likely to be a result of the increased number of twins in the GB engineered microstructure. These eccentric grains would have a positive influence on increasing the resistance to intergranular degradation.

Twins and twin-related domains in a grain boundary-engineered 304 stainless steel

ABSTRACT The grain boundary (GB) network of a GB-engineered 304 stainless steel was investigated in three dimensions. The GB-engineered sample had a high proportion of twin-related boundaries (∼70%). However, these boundaries were not distributed uniformly, but rather in large-sized twin-related domains (TRDs). All grains within a TRD can be connected by a tree-shaped twin-chain. Any two grains within a TRD have ∑3n-type misorientation, where the n-value could be determined according to the twin-chain. These results show that the formation of large-sized TRDs is correlated with extensively progressed multiple-twinning processes. A quadruple-junction has three twin-boundaries at most. Furthermore, all observed quadruple-junctions within TRDs have at least one twin-boundary. The common spatial morphologies of twin-boundaries are plane-shape, tunnel-shape and semi-closed tunnel-shape. This paper is part of a thematic issue on Nuclear Materials.