Tobias Brögelmann

Fundamental study of an industrial reactive HPPMS (Cr,Al)N process

In this work, a fundamental investigation of an industrial (Cr,Al)N reactive high power pulsed magnetron sputtering (HPPMS) process is presented. The results will be used to improve the coating development for the addressed application, which is the tool coating for plastics processing industry. Substrate-oriented plasma diagnostics and deposition of the (Cr,Al)N coatings were performed for a variation of the HPPMS pulse frequency with values from f = 300 Hz to f = 2000 Hz at constant average power P = 2.5 kW and pulse length ton = 40 μs. The plasma was investigated using an oscilloscope, an intensified charge coupled device camera, phase-resolved optical emission spectroscopy, and an energy-dispersive mass spectrometer. The coating properties were determined by means of scanning electron microscopy, glow discharge optical emission spectroscopy, cantilever stress sensors, nanoindentation, and synchrotron X-ray diffraction. Regarding the plasma properties, it was found that the average energy within the pl...

Correlative plasma-surface model for metastable Cr-Al-N: Frenkel pair formation and influence of the stress state on the elastic properties

Correlatively employing density functional theory and experiments congregated around high power pulsed magnetron sputtering, a plasma-surface model for metastable Cr0.8Al0.2N (space group Fm 3 ¯m) is developed. This plasma-surface model relates plasma energetics with film composition, crystal structure, mass density, stress state, and elastic properties. It is predicted that N Frenkel pairs form during Cr0.8Al0.2N growth due to high-energy ion irradiation, yielding a mass density of 5.69 g cm−3 at room temperature and Youngs modulus of 358–130 GPa in the temperature range of 50–700 K for the stress-free state and about 150 GPa larger values for the compressive stress of 4 GPa. Our measurements are consistent with the quantum mechanical predictions within 5% for the mass density and 3% for Youngs modulus. The hypothesis of a stress-induced Youngs modulus change may at least in part explain the spread in the reported elasticity data ranging from 250 to 420 GPa.

Space-resolved plasma diagnostics in a hybrid (Cr,Al)N process

The concurrent usage of direct current magnetron sputtering (dcMS) and high power pulsed magnetron sputtering (HPPMS), the so-called dcMS/HPPMS hybrid technology, enables the combination of the advantages of both technologies. These are well known to be a higher deposition rate, compared to HPPMS processes, as well as an improved roughness, microstructure, and mechanical properties, compared to dcMS processes. However, there have not been investigations which thematically focus on the understanding of the influence of different dcMS/HPPMS plasma zones on the deposition rate and the coating properties. Hence, in the present work, a dcMS/HPPMS hybrid (Cr,Al)N process was analyzed regarding the plasma and coating properties. The measurements were carried out in an industrial scale physical vapor deposition coating unit. The plasma was analyzed space-resolved and substrate oriented to map the entire area in front and beside of the cathodes. The mean ion energy decreased from the area in front and beside of th...

Replication of micro-structured injection molds using physical vapor deposition coating and dynamic laser mold tempering

Abstract Plastics parts with micro-structured surfaces enable the development of innovative products such as optical components in sensors or light management systems for laser and LED applications. Moreover, micro-structured parts can be utilized in the medical and packaging industry for hydrophobic or antibacterial products. The production of micro-structured parts causes challenges in molding and demolding. Rough surfaces of the laser-structured mold inserts offer flow resistance during injection phase as well as increased demolding forces which cause failures of the replicated structures during ejection. Therefore, an innovative approach combines coated mold inserts by means of physical vapor deposition (PVD) and a highly dynamic laser tempering system to improve the replication of micro-structured plastics parts. Both uncoated and coated micro-structured mold inserts were used in a series of molding experiments by means of conventional and dynamic mold tempering. Based on the results, it can be shown that significant improvements of the replication of micro-structures of different sizes can be achieved by use of PVD mold coatings. This is attributed to the tribological interactions between coating and plastics melt. Furthermore, results indicate an influence of the thermal conductivity of PVD coatings to enhance replication quality.

Forward impact extrusion of surface textured steel blanks using coated tooling

A method to enable dry metal forming by the means of a self-lubricating coating and surface textures was researched using an innovative Pin-On-Cylinder-Tribometer. The experimental analysis was complemented by a numerical model of the complex contact conditions between coated tools and the surface textured specimen at the micro-level. Based on the results, the explanation of the tribological interactions between surface textured specimens and the tool in dry full forward extrusion is the objective of this work. Therefore, experimental dry extrusion tests were performed using a tool system. The extruded specimens were evaluated regarding their geometry as well as by the required punch force. Thereby, the effectiveness and the feasibility of dry metal forming on the example of full forward extrusion was evaluated. Thus, one more step towards the technical realization of dry metal forming of low alloy steels under industrial conditions was realized.

Multi-technology products

Development of technical solutions that lead to widening the use of multi-technological products as well as in assessing ecological and economic potentials of multi-technological products have not yet been studied intensively. The activities conducted in the context of this research area focus on these aspects. The aforementioned aspects have been examined, evaluated and quantified on the basis of three example products resulting from the first funding period. The research activities conducted on the example components deliver the basis for the layout of different integrated multi-technology production systems. Technical solutions that enable coupling of different process steps with each other as well as the integration of different functionalities and different materials in final multi-technology products have been proposed. The complex interdependencies of the products themselves and their associated production processes have been researched and evaluated intensively. Finally, a profitability assessment of the proposed solutions was conducted and future research topics identified.

Improved molding of micro structures using PVD-coated mold inserts

Abstract Micro structured optical plastics components are intensively used, i.e. in consumer electronics, for optical sensors in metrology, innovative LED-lighting, or laser technology. Injection molding has been proven successful for the large-scale production of these parts. However, the production of these parts still causes difficulties due to challenges in the molding and demolding of plastics parts created with laser-structured mold inserts. A complete molding of the structures often leads to increased demolding forces, which then cause a breaking of the structures and a clogging of the mold. An innovative approach is to combine physical vapor deposition (PVD)-coated, laser-structured inserts and a variothermal molding process to create functional micro structures in a one-step process. Therefore, a PVD coating is applied after the laser-structuring process in order to improve the wear resistance and the anti-adhesive properties against the plastics melt. In a series of molding trials with polycarbonate (PC) and polymethyl methacrylate (PMMA) using different coated molds, the mold temperature during injection was varied in the range of the glass transition and the melt temperature of the polymers. Subsequently, the surface topography of the molded parts was evaluated by digital three-dimensional laser-scanning microscopy. The influence of the molding parameters and the coating of the mold insert on the molding accuracy and the demolding behavior were analyzed. It was shown that micro structures created by ultra-short pulse laser ablation can be successfully replicated in a variothermal molding process. Due to the mold coating, significant improvements could be achieved in producing micro structured optical plastics components.