Tomas Kohout

Mineralogy, reflectance spectra, and physical properties of the Chelyabinsk LL5 chondrite – Insight into shock-induced changes in asteroid regoliths

Abstract The mineralogy and physical properties of Chelyabinsk meteorites (fall, February 15, 2013) are presented. Three types of meteorite material are present, described as the light-colored, dark-colored, and impact-melt lithologies. All are of LL5 composition with the impact-melt lithology being close to whole-rock melt and the dark-colored lithology being shock-darkened due to partial melting of iron metal and sulfides. This enables us to study the effect of increasing shock on material with identical composition and origin. Based on the magnetic susceptibility, the Chelyabinsk meteorites are richer in metallic iron as compared to other LL chondrites. The measured bulk and grain densities and the porosity closely resemble other LL chondrites. Shock darkening does not have a significant effect on the material physical properties, but causes a decrease of reflectance and decrease in silicate absorption bands in the reflectance spectra. This is similar to the space weathering effects observed on asteroids. However, compared to space-weathered materials, there is a negligible to minor slope change observed in impact-melt and shock-darkened meteorite spectra. Thus, it is possible that some dark asteroids with invisible silicate absorption bands may be composed of relatively fresh shock-darkened chondritic material.

Orbit and dynamic origin of the recently recovered Annama's H5 chondrite

We describe the fall of Annama meteorite occurred in the remote Kola Peninsula (Russia) close to Finnish border on April 19, 2014 (local time). The fireball was instrumentally observed by the Finnish Fireball Network. From these observations the strewnfield was computed and two first meteorites were found only a few hundred meters from the predicted landing site on May 29th and May 30th 2014, so that the meteorite (an H4-5 chondrite) experienced only minimal terrestrial alteration. The accuracy of the observations allowed a precise geocentric radiant to be obtained, and the heliocentric orbit for the progenitor meteoroid to be calculated. Backward integrations of the orbits of selected near-Earth asteroids and the Annama meteoroid showed that they rapidly diverged so that the Annama meteorites are unlikely related to them. The only exception seems to be the recently discovered 2014UR116 that shows a plausible dynamic relationship. Instead, analysis of the heliocentric orbit of the meteoroid suggests that the delivery of Annama onto an Earth-crossing Apollo type orbit occurred via the 4:1 mean motion resonance with Jupiter or the nu6 secular resonance, dynamic mechanisms that are responsible for delivering to Earth most meteorites studied so far.

pH‐Switch Nanoprecipitation of Polymeric Nanoparticles for Multimodal Cancer Targeting and Intracellular Triggered Delivery of Doxorubicin

Theranostic nanoparticles are emerging as potent tools for noninvasive diagnosis, treatment, and monitoring of solid tumors. Herein, an advanced targeted and multistimuli responsive theranostic platform is presented for the intracellular triggered delivery of doxorubicin. The system consists of a polymeric-drug conjugate solid nanoparticle containing encapsulated superparamagnetic iron oxide nanoparticles (IO@PNP) and decorated with a tumor homing peptide, iRGD. The production of this nanosystem is based on a pH-switch nanoprecipitation method in organic-free solvents, making it ideal for biomedical applications. The nanosystem shows sufficient magnetization saturation for magnetically guided therapy along with reduced cytotoxicity and hemolytic effects. IO@PNP are largely internalized by endothelial and metastatic cancer cells and iRGD decorated IO@PNP moderately enhance their internalization into endothelial cells, while no enhancement is found for the metastatic cancer cells. Poly(ethylene glycol)-block-poly(histidine) with pH-responsive and proton-sponge properties promotes prompt lysosomal escape once the nanoparticles are endocyted. In addition, the polymer-doxorubicin conjugate solid nanoparticles show both intracellular lysosomal escape and efficient translocation of doxorubicin to the nuclei of the cells via cleavage of the amide bond. Overall, IO@PNP-doxorubicin and the iRGD decorated counterpart demonstrate to enhance the toxicity of doxorubicin in cancer cells by improving the intracellular delivery of the drug carried in the IO@PNP.

Structure of nickel nanoparticles in a microcrystalline cellulose matrix studied using anomalous small-angle X-ray scattering

Nickel nanoparticles were synthesized by adding aqueous nickel salt into a microcrystalline cellulose matrix. The NiII ions were reduced with either sodium borohydride, NaBH_4, or potassium hypophosphite, KH_2PO_2, in water or aqueous NH_3 medium. The mass fraction of Ni in the samples was between 3.7 and 8.9%. X-ray absorption spectra at the Ni K-edge showed that Ni was partially oxidized only in a sample reduced with NaBH_4. Wide-angle X-ray scattering results showed that nickel was in nanocrystalline or amorphous form in the samples. Upon heating fcc Ni, hcp Ni, NiO, Ni_3P and other Ni–P phases formed depending on the reduction parameters. Using anomalous small-angle X-ray scattering the nanometre-scale particle size distributions of the Ni particles were determined. A large fraction of particles less than 15 nm in size were observed in the samples reduced in aqueous ammonium compared with the samples reduced in water. Particles reduced in aqueous ammonium had a large ferromagnetic component.

Targeted Cancer Therapy: pH-Switch Nanoprecipitation of Polymeric Nanoparticles for Multimodal Cancer Targeting and Intracellular Triggered Delivery of Doxorubicin (Adv. Healthcare Mater. 15/2016)

Targeted theranostic nanoparticles with dual pH and magnetic responsive properties for intracellular delivery are described by B. Herranz-Blanco, H. A. Santos, and co-workers on page 1904. Using a pH-switch nanoprecipitation method in organic-free solvents, a polymeric-drug conjugate solid nanoparticle containing encapsulated superparamagnetic iron oxide nanoparticles and decorated with a tumor homing peptide, iRGD, are targeted to endothelial and metastatic cancer cells.

Annama H chondrite—Mineralogy, physical properties, cosmic ray exposure, and parent body history

The fall of the Annama meteorite occurred early morning (local time) on April 19, 2014 on the Kola Peninsula (Russia). Based on mineralogy and physical properties, Annama is a typical H chondrite. It has a high Ar-Ar age of 4.4 Ga. Its cosmic ray exposure history is atypical as it is not part of the large group of H chondrites with a prominent 7 - 8 Ma peak in the exposure age histograms. Instead, its exposure age is within uncertainty of a smaller peak at 30 \pm 4 Ma. The results from short-lived radionuclides are compatible with an atmosperic pre-entry radius of 30 - 40 cm. However, based on noble gas and cosmogenic radionuclide data, Annama must have been part of a larger body (radius >65 cm) for a large part of its cosmic ray exposure history. The 10Be concentration indicates a recent (3 - 5 Ma) breakup which may be responsible for the Annama parent body size reduction to 30 - 35 cm pre-entry radius.

Low-temperature magnetism of alabandite: Crucial role of surface oxidation

Abstract Manganese(II) monosulphide crystallizes into three different polymorphs (α-, β-, and γ-MnS). Out of these, α-MnS, also known as mineral alabandite, is considered the most stable and is widespread in terrestrial materials as well as in extraterrestrial objects such as meteorites. In this study, a low-temperature antiferromagnetic state of α-MnS was investigated using macroscopic magnetic measurements as induced and remanent field-cooled (FC) and zero-field-cooled (ZFC) magnetizations and magnetic hysteresis. Both natural alabandite and synthetic samples show: (1) Néel temperatures in a narrow temperature range around 153 K, and (2) a rapid increase of the magnetization around 40 K. An anomalous magnetic behavior taking place at about 40 K was previously ascribed to the magnetic transition from a high-temperature antiferromagnetic to a low-temperature ferromagnetic state documented for non-stoichiometric α-MnS slightly enriched in manganese. However, our detailed microscopic observations and, in particular, oxidation experiments indicate that the anomalous magnetic behavior around 40 K is caused by the presence of an oxide layer of ferrimagnetic hausmannite (Mn3O4) on the surface of α-MnS rather than being an intrinsic property of nearly stoichiometric α-MnS.

Shock-darkening in ordinary chondrites: Determination of the pressure-temperature conditions by shock physics mesoscale modeling

We determined the shock-darkening pressure range in ordinary chondrites using the iSALE shock physics code. We simulated planar shock waves on a mesoscale in a sample layer at different nominal pressures. Iron and troilite grains were resolved in a porous olivine matrix in the sample layer. We used equations of state (Tillotson EoS and ANEOS) and basic strength and thermal properties to describe the material phases. We used Lagrangian tracers to record peak shock pressures in each material unit. The post-shock temperatures (and the fractions of tracers experiencing temperatures above the melting point) for each material were estimated after the passage of the shock wave and after reflections of the shock at grain boundaries in the heterogeneous materials. The results showed that shock-darkening, associated with troilite melt and the onset of olivine melt, happened between 40 and 50 GPa - with 52 GPa being the pressure at which all tracers in the troilite material reach the melting point. We demonstrate the difficulties of shock heating in iron and also the importance of porosity. Material impedances, grain shapes and the porosity models available in the iSALE code are discussed. We also discussed possible not-shock-related triggers for iron melt.

Non‐Invasive Geophysical Investigation and Thermodynamic Analysis of a Palsa in Lapland, Northwest Finland

Non-invasive geophysical prospecting and a thermodynamic model were used to examine the structure, depth and lateral extent of the frozen core of a palsa near Lake Peerajarvi in northwest Finland. A simple thermodynamic model verified that the current climatic conditions in the study area allow sustainable palsa development. A ground penetrating radar (GPR) survey of the palsa under both winter and summer conditions revealed its internal structure and the size of its frozen core. GPR imaging in summer detected the upper peat/core boundary, and imaging in winter detected a deep reflector that probably represents the lower core boundary. This indicates that only a combined summer and winter GPR survey completely reveals the lateral and vertical extent of the frozen core of the palsa. The core underlies the active layer at a depth of ~ 0.6 m and extends to about 4 m depth. Its lateral extent is ~ 15 m x ~ 30 m. The presence of the frozen core could also be traced as minima in surface temperature and ground conductivity measurements. These field methods and thermodynamic models can be utilised in studies of climate impact on Arctic wetlands. Copyright

In-field 57Fe Mössbauer spectroscopy below spin-flop transition in powdered troilite (FeS) mineral

Powdered troilite (FeS), extracted from the Cape York IIIA octahedrite meteorite, was investigated employing in-field 57Fe Mossbauer spectroscopy. The study identified a typical behavior of polycrystalline antiferromagnetic material under external magnetic fields. The in-field evolution of the 57Fe Mossbauer spectra showed that the spin-flop transition in the FeS system occurs at a field higher than 5 T.