Tomasz Safinski

CFD Analysis of the Radiation Distribution in a New Immobilized Catalyst Bubble Column Externally Illuminated Photoreactor

A new externally irradiated photoreactor configuration combining the excellent mass transfer characteristics of a bubble column operation with the separation power of an immobilized catalyst on quartz plates has been investigated using computational fluid dynamics (CFD) simulation. The radiative transport equation (RTE) in conjunction with the Navier-Stokes equations were solved to obtain the light incident radiative flux and the light absorbed by the immobilized titania as a function of the gas superficial velocity, the angle of inclination, and the separating distance between the plates. The model employed water and air as the fluid phases and the results indicated that gas bubbling considerably increased the incident radiation in the gas-liquid mixture enhancing the radiative flux and the absorbed radiation on the titania-coated plates. The CFD results pave the way for the optimization of a solar photocatalytic reactor for the degradation of organic pollutants.

Hydrodynamically-Enhanced Light Intensity Distribution in an Externally-Irradiated Novel Aerated Photoreactor: CFD Simulation and Experimental Studies

The enhancement of the surface incident radiation on the walls of an externally-irradiated bubble tank photoreactor was studied and modeled by solving the radiation transport equation (RTE) in conjunction with the continuity, momentum and k-e turbulence equations. Computational fluid dynamic (CFD) simulation results were complemented with actinometric runs to determine the effect of the gas flow rate on the radiation loss by reflection at the surface of the gas-liquid mixture due to bursting of the bubbles. The model assumed that the gas-liquid mixture is a semitransparent medium where the light is scattered as a result of specular reflection and refraction when the light rays impinge on the air bubbles. The superficial reflectivity at the top of the gas-liquid mixture was linearly correlated with the superficial gas velocity. In particular, the simultaneous solution of the hydrodynamics and radiation transport equation using CFD allowed us to establish the relationship between the light scattering coefficient and the bubble size and the gas hold-up. The excellent agreement obtained between the experimental data and the CFD model validates the proposed model.