Toney Teddy Fernandez

Diamond photonics platform enabled by femtosecond laser writing

Diamond is a promising platform for sensing and quantum processing owing to the remarkable properties of the nitrogen-vacancy (NV) impurity. The electrons of the NV center, largely localized at the vacancy site, combine to form a spin triplet, which can be polarized with 532 nm laser light, even at room temperature. The NV’s states are isolated from environmental perturbations making their spin coherence comparable to trapped ions. An important breakthrough would be in connecting, using waveguides, multiple diamond NVs together optically. However, still lacking is an efficient photonic fabrication method for diamond akin to the photolithographic methods that have revolutionized silicon photonics. Here, we report the first demonstration of three dimensional buried optical waveguides in diamond, inscribed by focused femtosecond high repetition rate laser pulses. Within the waveguides, high quality NV properties are observed, making them promising for integrated magnetometer or quantum information systems on a diamond chip.

Controlling plasma distributions as driving forces for ion migration during fs laser writing

The properties of structures written inside dielectrics with high repetition rate femtosecond lasers are known to depend strongly on the complex interplay of a large number of writing parameters. Recently, ion migration within the laser-excited volume has been identified as a powerful mechanism for changing the local element distribution and producing efficient optical waveguides. In this work it is shown that the transient plasma distribution induced during laser irradiation is a reliable monitor for predicting the final refractive index distribution of the waveguide caused by ion migration. By performing in-situ plasma emission microscopy during the writing process inside a La-phosphate glass it is found that the long axis of the plasma distribution determines the axis of ion migration, being responsible for the local refractive index increase. This observation is also valid when strong positive or negative spherical aberration is induced, greatly deforming the focal volume and inverting the index profile. Even subtle changes in the writing conditions, such as an inversion of the writing direction (quill writing effect), show up in the form of a modified plasma distribution, which manifests as a modified index distribution. Finally, it is shown that the superior control over the waveguide properties employing the slit shaping technique is caused by the more confined plasma distribution produced. The underlying reasons for this unexpected result are discussed in terms of non-linear propagation and heat accumulation.

Control of waveguide properties by tuning femtosecond laser induced compositional changes

Local compositional changes induced by high repetition rate fs-laser irradiation can be used to produce high performance optical waveguides in phosphate-based glasses. The waveguide refractive index contrast is determined by the local concentration of La, which can be changed by the action of the writing laser pulses. In this work, we have investigated the degree of control that can be exerted using this waveguide writing mechanism over the cross-section of the guiding region, and the local refractive index and compositional changes induced. These variables can be smoothly controlled via processing parameters using the slit shaping technique with moderate Numerical Aperture (NA 0.68) writing optics. The combined use of X-ray microanalysis and near field refractive index profilometry evidences a neat linear correlation between local La content and refractive index increase over a broad Δn interval (>3 x 10^2). This result further confirms the feasibility of generating efficient, integrated optics elements via spatially selective modification of the glass composition.

3D laser-written silica glass step-index high-contrast waveguides for the 3.5 μm mid-infrared range.

We report on the direct laser fabrication of step-index waveguides in fused silica substrates for operation in the 3.5 μm mid-infrared wavelength range. We demonstrate core-cladding index contrasts of 0.7% at 3.39 μm and propagation losses of 1.3 (6.5) dB/cm at 3.39 (3.68) μm, close to the intrinsic losses of the glass. We also report on the existence of three different laser modified SiO₂ glass volumes, their different micro-Raman spectra, and their different temperature-dependent populations of color centers, tentatively clarifying the SiO₂ lattice changes that are related to the large index changes.

Glass–polymer superlattice for integrated optics

Abstract. Glass and polymer interstacked superlattice like nanolayers were fabricated by nanosecond-pulsed laser deposition with a 193-nm-ultraviolet laser. The individual layer thickness of this highly transparent thin film could be scaled down to 2 nm, proving a near atomic scale deposition of complex multilayered optical and electronic materials. The layers were selectively doped with Er3+ and Eu3+ ions, making it optically active and targeted for integrated sensor application.

Active Mid-IR emissions from rare-earth doped tellurite glass ceramics for bio applications

Intense emission peaking at 2.18 μm was successfully obtained from erbium upon carefully designed engineering of its glass host both thermally and spectroscopically. Highly localized crystallization of erbium sites is verified by micro Raman and micro-PL along with TEM characterizations.

Multi-ion diffusion in silica glass using femtosecond pulsed laser deposition

We demonstrate simultaneous implantation of Tellurium, Zinc, Sodium and Erbium ions in silica glass via fs-PLD. 1.3μm deep uniform diffusion with Δnmax of 0.169 was produced. Process is explained using existing models with experimental verification.

Femtosecond laser written diamond waveguides: A step towards integrated photonics in the far infrared

Abstract A first demonstration and complete characterization of mid-infrared waveguides in single crystal diamond are reported. Waveguides were designed for 2.4 μm and 8.6 μm waveguiding, with their group velocity dispersion analyzed using femtosecond pulses at 2.4 μm wavelength propagated through the waveguide and the bulk substrate. The total dispersion was found to be dominated by the bulk material rather than the waveguide, and was on the range of 275 fs2/mm, demonstrating that femtosecond laser written modifications in diamond introduce negligible perturbations to the pristine material.

Global optimization via evolutionary approach of a Dy3+:ZBLAN fiber amplifier for MID-IR applications

A Dy3+-doped ZBLAN fiber amplifier based on an in-band pumped configuration is designed and optimized via an evolutionary approach. In the proposed model, the rate equations are coupled with the power propagation equations for the pump and signal beams. The complete amplifier model allows the definition of the fitness function to be optimized. Realistic values for optical and spectroscopic parameters are considered. For a fiber with dopant concentration of 2000 ppm, by employing an input pump power of 1 W at 2.72 μm wavelength, an optical gain of about 15.56 dB at 2.95 μm wavelength is obtained.

Photonic waveguide engineering using pulsed lasers — A novel approach for non-clean room fabrication!

Over the last 25 years has seen an unprecedented increase in the growth of phonic components based on semiconductor and solid-state lasers, glass and polymer based optical fibres, and organic LEDs. Emerging technology for component engineering must embed dissimilar materials based devices into an integrated form which is more efficient. In this article, we demonstrate techniques for overcoming the materials related limitations by adopting thin-film deposition techniques based on nano- and femto-second pulsed laser deposition. Three examples of thin-film fabrication for near-IR devices using Er3+-ion doped glass-on-GaAs, Er3+-ion doped glass-polydimethyl silane (PDMS) polymer, and Tm3+-doped nano-silicon thin films and gain medium waveguides are discussed. The modelling tools are used a priori for waveguide engineering for ascertaining the extent to which the structural incompatibility due to mismatch strain can be minimized. The structure and spectroscopic properties of Er3+-ion doped thin films on silica, polymer, and semiconductor GaAs substrates were examined in detail and are reported. We demonstrate the formation of glass-polymer superlattice structures for waveguide fabrication for overcoming the solubility limits of Er3+-ions in PDMS polymers. For inscribing waveguides in superlattice structures and nano silicon structures, the ablation machining using fs-pulsed Ti-sapphire laser was used, and the resulting spectroscopic properties of waveguides are discussed.