U. Çevik

Assessment of metal element concentrations in mussel (M. Galloprovincialis) in Eastern Black Sea, Turkey

The main goal of this work is to determine the effects of pollution of copper, lead and zinc mines on the Eastern Black Sea. Metal and heavy metal concentrations in the Eastern Black Sea mussels were measured using Energy Dispersive X-ray Fluorescence (EDXRF) and Flame Atomic Absorption Spectroscopy (FAAS). The analytical results showed that the tissue of mussel in Eastern Black Sea contains K, Ca, Fe, Cu, Zn, and Sr elements, and the shell of mussel contains Ca, Cu, Sr, and Ba elements. Due to the detection limit of EDXRF, the mussels were analyzed with FAAS for Cr, Mn, Ni, Cd and Pb elements. An ANOVA and Pearson correlation analyses were performed. The results showed although that the mean concentrations of Cu and Zn for the tissue of the mussels were markedly above the permissible levels of the Turkish regulations, Zn concentration is in the limits of the Food and Agriculture Organization (FAO).

Radiation dose estimation and mass attenuation coefficients of cement samples used in Turkey.

Different cement samples commonly used in building construction in Turkey have been analyzed for natural radioactivity using gamma-ray spectrometry. The mean activity concentrations observed in the cement samples were 52, 40 and 324 Bq kg(-1) for (226)Ra, (232)Th and (40)K, respectively. The measured activity concentrations for these radionuclides were compared with the reported data of other countries and world average limits. The radiological hazard parameters such as radium equivalent activities (Ra(eq)), gamma index (I(gamma)) and alpha index (I(alpha)) indices as well as terrestrial absorbed dose and annual effective dose rate were calculated and compared with the international data. The Ra(eq) values of cement are lower than the limit of 370 Bq kg(-1), equivalent to a gamma dose of 1.5 mSv y(-1). Moreover, the mass attenuation coefficients were determined experimentally and calculated theoretically using XCOM in some cement samples. Also, chemical compositions analyses of the cement samples were investigated.

Characterization of gas concrete materials used in buildings of Turkey.

The activity concentration of (226)Ra, (232)Th and (40)K in gas concrete samples collected from different suppliers and some provinces in Turkey were measured using gamma-ray spectrometry. Knowledge of radioactivity in gas concrete used in building materials enables one to assess any possible radiological risks to human health. The mean activity concentrations observed in the gas concrete samples were 82.0, 28.2 and 383.9 Bq kg(-1) for (226)Ra, (232)Th and (40)K, respectively. The radium equivalent activity, external and internal hazard indices as well as terrestrial absorbed dose and annual effective dose rate was calculated. The results indicate that the radium equivalent activity values of gas concrete samples are lower than the limit of 370 Bq kg(-1), equivalent to a gamma-dose of 1.5 mSv y(-1). Moreover, mass attenuation coefficients were measured in some gas concrete samples. It was found that the mass attenuation coefficients decreased with increasing photon energies. Also, chemical compositions and structural analysis (XRD and SEM) of the gas concrete samples were investigated.

Ecological half-life of 137Cs in mosses and lichens in the Ordu province, Turkey by Cevik and Celik

Twenty-one years after the Chernobyl accident, lichen and moss samples were collected from the Ordu province, which was already chosen for a related study some years ago. It was observed that 137Cs activity concentration ranged from 31 to 469 Bq kg(-1) in the moss and from 132 to 1508 Bq kg(-1) in the lichen samples. The decrease of the activity concentrations in the present measurements (2007) relative to those in 1997 (over a period of 10 y) indicated ecological half-lives between 1.8 and 10.4 y for the moss and between 2.1 and 13.7 y for the lichen samples. It was observed that 137Cs was still eminent in the area studied. Moreover, 40K activity concentrations and K element concentrations were measured and their relationships were discussed.

Measurement of K to L shell vacancy transfer probabilities for the elements 52⩽Z⩽68

Abstract The probabilities for transfer of vacancies from K to L shell were measured using intensity ratio of Kα and total Lx X-rays. The Kα and total Lx X-rays yields from the targets excited by 59.5 keV incident photon were obtained using a Si(Li) detector. These experimental results were compared with the theoretically calculated values using radiative and radiationless transitions. The radiative transitions of these elements were observed from the relativistic Hartree–Slater model, which was proposed by Scofield (Atom. Data Nucl. Data Tables 14 (1974) 121). The radiationless transitions were observed from the Dirac–Hartree–Slater model, which was proposed by Chen et al. (Atom. Data Nucl. Data Tables 24 (1979) 13). A fairly good agreement is found between the experimental and calculated values.

LEVELS OF CESIUM RADIONUCLIDES IN LICHENS AND MOSSES FROM THE PROVINCE OF ORDU IN THE EASTERN BLACK SEA AREA OF TURKEY

Chemobyl nuclear power plant accident in Ukraine in April 26, 1986 has affected Scandinavia and European countries, the Balkans and the northside of Turkey. Radioactive clouds depending on meteorological conditions had contaminated soil surface and flora in the region of Thrace and the seaside of the Black sea. This study has been done on mosses and lichens in which radioactive isotopes can live for a long time. These specimens have been collected in various regions of Ordu located in the Eastern Black Sea region of Turkey. On the basis of the results of this study the geographic distribution of pollution on the flora has been done.

Identification of heavy metal origins related to chemical and morphological soil properties using several non-destructive X-ray analytical methods

Soils are complex mixtures of organic, inorganic materials, and metal compounds from anthropogenic sources. In order to identify the pollution sources, their magnitude and development, several X-ray analytical methods were applied in this study. The concentrations of 16 elements were determined in all the soil samples using energy dispersive X-ray fluorescence spectrometry. Soils of unknown origin were observed by scanning electron microscopy equipped with a Si(Li) X-ray detector using Monte Carlo simulation approach. The mineralogical analyses were carried out using X-ray diffraction spectrometry. Due to the correlations between heavy metals and oxide compounds, the samples were analyzed also by electron probe microanalyzer (EPMA) in order to have information about their oxide contents. On the other hand, soil pH and salinity levels were identified owing to their influence between heavy metal and soil-surface chemistry. Moreover, the geoaccumulation index (Igeo) enables the assessment of contamination by comparing current and pre-industrial concentrations.

Precision and accuracy of ST-EDXRF performance for As determination comparing with ICP-MS and evaluation of As deviation in the soil media

The present study was conducted to (i) determine the precision and accuracy of arsenic measurement in soil samples using ST-EDXRF by comparison with the results of ICP-MS analyses and (ii) identify the relationship of As concentration with soil characteristics. For the analysis of samples, inductively coupled plasma mass spectrometry (ICP-MS) and energy dispersive X-ray fluorescence spectrometry (EDXRF) were performed. According to the results found in the soil samples, the addition of HCl to HNO3, used for the digestion gave significant variations in the recovery of As. However, spectral interferences between peaks for As and Pb can affect detection limits and accuracy for XRF analysis. When comparing the XRF and ICP-MS results a correlation was observed with R(2)=0.8414. This means that using a ST-EDXRF spectrometer, it is possible to achieve accurate and precise analysis by the calibration of certified reference materials and choosing an appropriate secondary target. On the other hand, with regard to soil characteristics analyses, the study highlighted that As is mostly anthropogenically enriched in the studied area.

Evaluation of Outdoor Gamma Dose Rate and Cancer Risk in Artvin Province, Turkey

ABSTRACT In this study, we measured environmental outdoor gamma dose rates (terrestrial and cosmic) in 204 stations across the province of Artvin. The average outdoor gamma dose rate for the province of Artvin was found to be 174.81 nGy/h. The radiological map of Artvin was drawn with the help of measured outdoor gamma dose rates. Annual effective dose equivalent and lifetime cancer risk values were figured up for the adults in Artvin province by using measured outdoor gamma dose rates. The average annual dose equivalent and excess lifetime cancer risk were 214.5 μSv/y and 7.5 × 10−4, respectively. The values acquired were compared with the similar studies done around the world. The average annual effective dose equivalent and excess lifetime cancer risk were found to be approximately three times higher than the world average.

Assessment of Radiological Levels at Schools in Trabzon, Turkey

In this study, a survey on environmental radioactivity in 16 high schools located in north eastern region of Turkey (the black sea region, province of Trabzon) was carried out. Indoor air radon (222Rn) concentrations were measured in spring and autumn 2008 seasons using LR115 solid state nuclear track detectors and gamma radioactivity levels were measured using an HPGe gamma ray detector. It was seen that mean radon activity concentrations in schools ranged from 31 to 157 Bq/m3 for spring season and from 38 to 114 Bq/m3 for autumn season. The mean gamma activity concentrations in located areas of schools are between 18–52, 21–59, 11–97 and 265–759 Bq/kg for 226Ra, 232Th, 137Cs and 40K, respectively. The annual effective doses of students and staff received due to radon and locations’ gamma radioactivity levels are calculated.