U. Scotti di Uccio

Conducting interfaces between band insulating oxides: The LaGaO3/SrTiO3 heterostructure

We show that the growth of the heterostructure LaGaO3/SrTiO3 yields the formation of a highly conductive interface. Our samples were carefully analyzed by high resolution electron microscopy, in order to assess their crystal perfection and to evaluate the abruptness of the interface. Their carrier density and sheet resistance are compared to the case of LaAlO3/SrTiO3 and a superconducting transition is found. The results open the route to widening the field of polar-nonpolar interfaces, pose some phenomenological constrains to their underlying physics and highlight the chance of tailoring their properties for future applications by adopting suitable polar materials.

Pulsed laser deposition of SrTiO3/LaGaO3 and SrTiO3/LaAlO3: Plasma plume effects

Pulsed laser deposition of SrTiO3/LaGaO3 and SrTiO3/LaAlO3 interfaces has been analyzed with a focus on the kinetic energy of the ablated species. LaGaO3 and LaAlO3 plasma plumes were studied by fast photography and space-resolved optical emission spectroscopy. Reflection high energy electron diffraction was performed proving a layer-by-layer growth up to 10-1 mbar oxygen pressure. The role of the energetic plasma plume on the two-dimensional growth and the presence of interfacial defects at different oxygen growth pressure has been discussed in view of the conducting properties developing at such polar/non-polar interfaces.

Polar catastrophe and electronic reconstructions at the LaAlO3/SrTiO3 interface: evidence from optical second harmonic generation

The so-called “polar catastrophe,” a sudden electronic reconstruction taking place to compensate for the interfacial ionic polar discontinuity, is currently considered as a likely factor to explain the surprising conductivity of the interface between the insulators LaAlO3 and SrTiO3. We applied optical second harmonic generation, a technique that a priori can detect both mobile and localized interfacial electrons, to investigating the electronic polar reconstructions taking place at the interface. As the LaAlO3 film thickness is increased, we identify two abrupt electronic rearrangements: the first takes place at a thickness of unit cells, in the insulating state; the second occurs at a thickness of 4–6 unit cells, i.e., just above the threshold for which the samples become conducting. Two possible physical scenarios behind these observations are proposed. The first is based on an electronic transfer into localized electronic states at the interface that acts as a precursor of the conductivity onset. In the second scenario, the signal variations are attributed to the strong ionic relaxations taking place in the LaAlO3 layer.

Transport properties in manganite thin films

The resistivity of thin La0.7A0.3MnO3 films sA =C a,S rd is investigated in a wide temperature range. The comparison of the resistivities is made among films grown by different techniques and on several substrates allowing to analyze samples with different amounts of disorder. In the low-temperature nearly half-metallic ferromagnetic state the prominent contribution to the resistivity scales as T a with a . 2.5 for intermediate strengths of disorder supporting the theoretical proposal of single magnon scattering in presence of minority spin states localized by the disorder. For large values of disorder the low-temperature behavior of the resistivity is well described by the law T 3 characteristic of anomalous single magnon scattering processes, while in the regime of low disorder the a exponent tends to a value near 2. In the high temperature insulating paramagnetic phase the resistivity shows the activated behavior characteristic of polaronic carriers. Finally in the whole range of temperatures the experimental data are found to be consistent with a phase separation scenario also in films doped with strontiumsA =S rd.

Optimization of La0.7Ba0.3MnO3−δ complex oxide laser ablation conditions by plume imaging and optical emission spectroscopy

The properties of thin films of complex oxides, such as La1−xDxMnO3−δ (D=Ba, Ca, Sr, etc.), produced by pulsed laser deposition depend critically on the experimental parameters in which laser ablation is carried out. Here, we report a comparative analysis of the pulsed laser ablation process of La0.7Ba0.3MnO3−δ, in oxygen background, in the ambient pressure range from 10−2 to 1 mbar, typically employed in pulsed laser deposition of manganites. The laser ablation plume was studied by using time-gated imaging and optical emission spectroscopy techniques. It was found that at a pressure of ≈10−2 mbar, the plume species arriving at the substrate are characterized by hyperthermal kinetic energy (≈10 eV), and high degree of excitation. On the contrary, at larger oxygen pressure (0.1–1 mbar), the velocity of plume species reaching the substrate, and their degree of excitation are much reduced by the confining effects of the background gas. These features explain why an appropriate choice of the experimental cond...

Simple model for the nucleation of (0 0 1) and (1 0 0) oriented grains in YBCO films

Abstract A thermodynamical model, set up to describe the nucleation of vapour-deposited YBCO thin films, is reported. The role of the surface energy of YBCO nuclei is discussed. Information on the surface Gibbs energy of YBCO (1 0 0), (0 1 0) and (0 0 1) surfaces is obtained both from experimental results reported in the literature and from ab initio calculations. These data allow us to estimate the surface energy of the nuclei and to achieve a qualitative description of the crossover from (0 0 1) to (1 0 0) orientation at increasing supersaturation.

Substrate heating influence on the deposition rate of oxides during pulsed laser deposition in ambient gas

We investigate the effects of ambient pressure and substrate temperature on the deposition rate of oxides grown by pulsed laser deposition in oxygen atmosphere. The deposition rate of LaGaO3 (LGO) and LaAlO3 (LAO) is studied at room temperature by means of a quartz crystal microbalance and at 800 °C by exploiting reflection high energy electron diffraction. We observe a clear dependence of the deposition rate on temperature for an oxygen pressure between 10−2 and 1 mbar. A simple model based on multiple-elastic-scattering processes thoroughly describes the observed dependence of the deposition rate on the pressure/density of the background gas.

Blue luminescence of SrTiO3 under intense optical excitation

The blue-green photoluminescence emitted by pure and electron-doped strontium titanate under intense pulsed near-ultraviolet excitation is studied experimentally, as a function of excitation intensity and temperature. Both emission spectra and time-resolved decays of the emission are measured and analyzed in the framework of simple phenomenological models. We find an interesting blue-to-green transition occurring for increasing temperatures in pure samples, which is instead absent in doped materials. The luminescence yield and decay rate measured as a function of temperature can be modeled well as standard activated behaviors. The leading electron-hole recombination process taking place in the initial decay is established to be second-order, or bimolecular, in contrast to recent reports favoring a third-order interpretation as an Auger process. The temporal decay of the luminescence can be described well by a model based on two interacting populations of excitations, respectively identified with interacting defect-trapped (possibly forming excitons) and mobile charges. Finally, from the measured doping and sample dependence of the luminescence yield, we conclude that the radiative centers responsible for the luminescence are probably intrinsic structural defects other than bulk oxygen vacancies.

Observation of a two-dimensional electron gas at the surface of annealed SrTiO3 single crystals by scanning tunneling spectroscopy

An extensive surface characterization of hydrofluoric acid (HF) etched and annealed SrTiO3 single crystals, vacuum-annealed below 300 degrees C, reveals the formation of a two-dimensional electron gas (2DEG). A joint scanning tunneling spectroscopy and low-energy electron diffraction analysis allows us to associate the surface metallic state (characterized by the presence of a nonzero density of states close to the Fermi level) with the low-temperature-annealed highly ordered 1 x 1 reconstructed SrTiO3 surface hosting two-dimensional carriers. Meanwhile, a gap opens in the tunneling spectrum of 2 x 1 reconstructed, high-temperature-annealed surfaces. X-ray photoemission spectroscopy shows that the metallic state is associated with the surface formation of Ti3+. Recently published photoemission data demonstrated the formation of a 2DEG on the surface of cleaved SrTiO3, while scanning tunneling spectroscopy on crystals heated at high temperature revealed gaplike features: Our results can help reconcile this seemingly contradicting phenomenology observed so far by scanning tunneling spectroscopy and photoemission spectroscopy.

Current-induced domain wall depinning and magnetoresistance in La0.7Sr0.3MnO3 planar spin valves

The authors have performed experiments on current-induced domain wall (DW) displacement in La0.7Sr0.3MnO3 nanostructures patterned by gallium (Ga) focused-ion-beam milling. A dc current is found to assist or hinder, according to polarity, an external magnetic field in the depinning of a DW trapped in a nanoconstriction. For large enough currents, the DW depinning occurs in the absence of external magnetic field. The depinning current depends on the transverse anisotropy constant of the region toward which the DW is displaced.