Udo Niederreuther

Organometallphosphin-substituierteübergangsmetallkomplexe XI. Organometallphosphincyclopentadienyldicarbonyl- und -methylcyclopentadienyldicarbonyl-mangan-komplexe

Summary The reaction of π-cyclopentadienylmanganese tricarbonyl or π-methylcyclopentadienylmanganese tricarbonyl with tri(tert-butyl)phosphine, tris(trimethylsilyl)-, tris(trimethylgermyl)-, and tris(trimethylstannyl)phosphine results in the elimination of one CO-ligand and the formation of corresponding (organometalphosphine)cyclopentadienylmanganese dicarbonyl and (organometalphosphine)methylcyclopentadienylmanganese dicarbonyl complexes. The IR, UV, 1 H NMR and 31 P NMR spectra are reported and discussed.