Ulf Linnemann

Neoproterozoic - early Palaeozoic tectonostratigraphy and palaeogeography of the peri-Gondwanan terranes: Amazonian v. West African connections

Abstract Within the Appalachian–Variscan orogen of North America and southern Europe lie a collection of terranes that were distributed along the northern margin of West Gondwana in the late Neoproterozoic and early Palaeozoic. These peri-Gondwanan terranes are characterized by voluminous late Neoproterozoic (c. 640–570 Ma) arc magmatism and cogenetic basins, and their tectonothermal histories provide fundamental constraints on the palaeogeography of this margin and on palaeocontinental reconstructions for this important period in Earth history. Field and geochemical studies indicate that arc magmatism generally terminated diachronously with the formation of a transform margin, leading by the Early–Middle Cambrian to the development of a shallow-marine platform–passive margin characterized by Gondwanan fauna. However, important differences exist between these terranes that constrain their relative palaeogeography in the late Neoproterozoic and permit changes in the geometry of the margin from the late Neoproterozoic to the Early Cambrian to be reconstructed. On the basis of basement isotopic composition, the terranes can be subdivided into: (1) Avalonian-type (e.g. West Avalonia, East Avalonia, Meguma, Carolinia, Moravia–Silesia), which developed on juvenile, c. 1.3–1.0 Ga crust originating within the Panthalassa-like Mirovoi Ocean surrounding Rodinia, and which were accreted to the northern Gondwanan margin by c. 650 Ma; (2) Cadomian-type (e.g. North Armorican Massif, Ossa–Morena, Saxo-Thuringia, Moldanubia), which formed along the West African margin by recycling ancient (c. 2.0–2.2 Ga) West African crust; (3) Ganderian-type (e.g. Ganderia, Florida, the Maya terrane and possible the NW Iberian domain and South Armorican Massif), which formed along the Amazonian margin of Gondwana by recycling Avalonian and older Amazonian basement; and (4) cratonic terranes (e.g. Oaxaquia and the Chortis block), which represent displaced Amazonian portions of cratonic Gondwana. These contrasts imply the existence of fundamental sutures between these terranes prior to c. 650 Ma. Derivation of the Cadomian-type terranes from the West African craton is further supported by detrital zircon data from their Neoproterozoic–Ediacaran clastic rocks, which contrast with such data from the Avalonian- and Ganderian-type terranes that suggest derivation from the Amazonian craton. Differences in Neoproterozoic and Ediacaran palaeogeography are also matched in some terranes by contrasts in Cambrian faunal and sedimentary provenance data. Platformal assemblages in certain Avalonian-type terranes (e.g. West Avalonia and East Avalonia) have cool-water, high-latitude fauna and detrital zircon signatures consistent with proximity to the Amazonian craton. Conversely, platformal assemblages in certain Cadomian-type terranes (e.g. North Armorican Massif, Ossa–Morena) show a transition from tropical to temperate waters and detrital zircon signatures that suggest continuing proximity to the West African craton. Other terranes (e.g. NW Iberian domain, Meguma) show Avalonian-type basement and/or detrital zircon signatures in the Neoproterozoic, but develop Cadomian-type signatures in the Cambrian. This change suggests tectonic slivering and lateral transport of terranes along the northern margin of West Gondwana consistent with the transform termination of arc magmatism. In the early Palaeozoic, several peri-Gondwanan terranes (e.g. Avalonia, Carolinia, Ganderia, Meguma) separated from West Gondwana, either separately or together, and had accreted to Laurentia by the Silurian–Devonian. Others (e.g. Cadomian-type terranes, Florida, Maya terrane, Oaxaquia, Chortis block) remained attached to Gondwana and were transferred to Laurussia only with the closure of the Rheic Ocean in the late Palaeozoic.

The Rheic Ocean: Origin, Evolution, and Significance

The Rheic Ocean, which separated Laurussia from Gondwana after the closure of Iapetus, was one of the principal oceans of the Paleozoic. Its suture extends over 10,000 km from Middle America to Eastern Europe, and its closure assembled the greater part of Pangea with the formation of the Ouachita-Alleghanian-Variscan orogen. The Rheic Ocean opened in the Early Ordovician, following protracted Cambrian rifting that represented a continuum of Neoproterozoic orogenic processes, with the separation of several Neoproterozoic arc terranes from the continental margin of northern Gondwana. Separation likely occurred along a former Neoproterozoic suture in response to slab pull in the outboard Iapetus Ocean. The Rheic Ocean broadened at the expense of Iapetus and attained its greatest width (>4000 km) in the Silurian, by which time Baltica had sutured to Laurentia and the Neoproterozoic arc terranes had accreted to Laurussia, closing Iapetus in the process. Closure of the Rheic Ocean began in the Devonian and was largely complete by the Mississippian as Gondwana and Laurussia sutured to build Pangea. In this process, North Africa collided with southern Europe to create the Variscan orogen in the Devono-Carboniferous, and West Africa and South America sutured to North America to form the Alleghanian and Ouachita orogens, respectively, during the Permo-Carboniferous. The Rheic Ocean has long been recognized as the major Paleozoic ocean in southern Europe, where its history dominates the basement geology. In North America, however, the Rheic has historically received less attention than Iapetus because its suture is not exposed. Yet, it was the Rheic Ocean that played the dominant role in creating the AppalachianOuachita orogen, and an important record of its history may be preserved in Mexico.

From Cadomian subduction to Early Palaeozoic rifting: the evolution of Saxo-Thuringia at the margin of Gondwana in the light of single zircon geochronology and basin development (Central European Variscides, Germany)

Abstract Saxo-Thuringia is classified as a tectonostratigraphic terrane belonging to the Armorican Terrane Collage (Cadomia). As a former part of the Avalonian-Cadomian Orogenic Belt, it became (after Cadomian orogenic events, rift-related Cambro-Ordovician geodynamic processes and a northward drift within Late Ordovician to Early Silurian times), during Late Devonian to Early Carboniferous continent-continent collision, a part of the Central European Variscides. By making use of single zircon geochronology, geochemistry and basin analysis, geological processes were reconstructed from latest Neoproterozoic to Ordovician time: (1) 660–540 Ma: subduction, back-arc sedimentation and tectonomagmatic activity in a Cadomian continental island-arc setting marginal to Gondwana; (2) 540 Ma: obduction and deformation of the island arc and marginal basins; (3) 540–530 Ma: widespread plutonism related to the obduction-related Cadomian heating event and crustal extension; (4) 530–500 Ma: transform margin regime connected with strike-slip generated formation of Early to Mid-Cambrian pull-apart basins; (5) 500–490 Ma: Late Cambrian uplift and formation of a chemical weathering crust; (6) 490–470 Ma: Ordovician rift setting with related sedimentation regime and intense igneous activity; (7) 440–435 Ma: division from Gondwana and start of northward drift. The West African and the Amazonian Cratons of Gondwana, as well as parts of Brittany, were singled out by a study of inherited and detrital zircons as potential source areas in the hinterland of Saxo-Thuringia.

The Cadomian Orogeny in Saxo-Thuringia, Germany: geochemical and Nd-Sr-Pb isotopic characterization of marginal basins with constraints to geotectonic setting and provenance

Abstract The Cadomian basement and the Cambro-Ordovician overstep sequence in Saxo-Thuringia is characterized by clastic sedimentation from the Late Neoproterozoic to the Ordovician. Magmatism in the Avalonian–Cadomian Arc preserved in Saxo-Thuringia occurred between ca. 570 and 540 Ma. Peri-Gondwanan basin remnants with Cadomian to Early Palaeozoic rocks are exposed as very low-grade metamorphosed rocks in six areas (Schwarzburg Anticline, Berga Anticline, Doberlug Syncline, North Saxon Anticline, Lausitz Anticline, and Elbe Zone). A hiatus in sedimentation between 540 and 530 Ma (Cadomian unconformity) is related to the Cadomian Orogeny. A second gap in sedimentation occurred during the Upper Cambrian (500 to 490 Ma) and is documented by a disconformity between Lower to Middle Cambrian rocks and overlying Tremadocian sediments. Major and trace-element signatures of the Cadomian sediments reflect an active margin (“continental arc”), those of the Ordovician sediments a passive margin. The Cambrian sediments have inherited the arc signature through the input of relatively unaltered Cadomian detritus. Initial Nd and Pb isotope data from the six Saxo-Thuringian areas demonstrate that there is no change in source area with time for each location, but that there are minor contrasts among the locations. (1) Cadomian sediments from the Lausitz Anticline, the Doberlug Syncline and the Elbe Zone have lower 207Pb/204Pb than all other areas. (2) The core of the Schwarzburg Anticline, which is overprinted by greenschist facies conditions and detached, is isotopically heterogeneous. One part of its metasedimentary units has less radiogenic Nd than sediments from other low-grade units of similar age in the same area. (3) Cadomian sediments from the Schwarzburg Anticline show an input of younger felsic crust. (4) The Rothstein Group shows distinct input of young volcanic material. Also, (5) Cadomian sediments from the Lausitz Anticline, the Elbe Zone and parts of the North Saxon Anticline are characterized by input from an old mafic crust. Nd isotope data of the remaining areas yield average crustal residence ages of the sediment source of 1.5–1.9 Ga, which suggests derivation from an old craton as found for other parts of the Iberian–Armorican Terrane Collage. Similarly, the Pb isotope data of all areas indicate sediment provenance from an old craton. The rapid change of lithologies from greywacke to quartzite from the Late Neoproterozoic (Cadomian basement) to the Ordovician does not reflect changes in sediment provenance, but is essentially due to increased reworking of older sediments and old weathering crusts that formed during various hiatus of sedimentation. This change in sediment maturity takes its chemical expression in lower overall trace-element contents in the quartzite (dilution effect by quartz) and relative enrichment of some trace-elements (Zr, MREE, HREE due to detrital zircon and garnet). The Rb–Sr systematics of the quartzites and one Ordovician tuffite was disturbed (most likely during the Variscan Orogeny), which suggests a lithology-controlled mobility of alkali and calc-alkali elements. By comparison with available data, it seems unlikely that only Nd TDM model ages are useful to distinguish between West African and Amazonian provenance. Nd TDM model ages of 1.5 to 1.9 Ga in combination with paleobiogeographic aspects, age data from detrital zircon, and palaeogeographic constraints, especially through tillites of the Saharan glaciation in the Hirnantian, strongly indicate a provenance of Saxo-Thuringia from the West African Craton.

Variability over time in the sources of South Portuguese Zone turbidites: evidence of denudation of different crustal blocks during the assembly of Pangaea

This study combines geochemical and geochronological data in order to decipher the provenance of Carboniferous turbidites from the South Portuguese Zone (SW Iberia). Major and trace elements of 25 samples of graywackes and mudstones from the Mértola (Visean), Mira (Serpukhovian), and Brejeira (Moscovian) Formations were analyzed, and 363 U-Pb ages were obtained on detrital zircons from five samples of graywackes from the Mira and Brejeira Formations using LA-ICPMS. The results indicate that turbiditic sedimentation during the Carboniferous was marked by variability in the sources, involving the denudation of different crustal blocks and a break in synorogenic volcanism. The Visean is characterized by the accumulation of immature turbidites (Mértola Formation and the base of the Mira Formation) inherited from a terrane with intermediate to mafic source rocks. These source rocks were probably formed in relation to Devonian magmatic arcs poorly influenced by sedimentary recycling, as indicated by the almost total absence of pre-Devonian zircons typical of the Gondwana and/or Laurussia basements. The presence of Carboniferous grains in Visean turbidites indicates that volcanism was active at this time. Later, Serpukhovian to Moscovian turbiditic sedimentation (Mira and Brejeira Formations) included sedimentary detritus derived from felsic mature source rocks situated far from active magmatism. The abundance of Precambrian and Paleozoic zircons reveals strong recycling of the Gondwana and/or Laurussia basements. A peri-Gondwanan provenance is indicated by zircon populations with Neoproterozoic (Cadomian-Avalonian and Pan-African zircon-forming events), Paleoproterozoic, and Archean ages. The presence of late Ordovician and Silurian detrital zircons in Brejeira turbidites, which have no correspondence in the Gondwana basement of SW Iberia, indicates Laurussia as their most probable source.

Detrital zircon and tectonostratigraphy of the Parautochthon under the Morais Complex (NE Portugal): implications for the Variscan accretionary history of the Iberian Massif

Zircon geochronology using laser ablation inductively coupled plasma mass spectrometry, combined with a new detailed geological map and a stratigraphic study of the Parautochthon at the eastern rim of the Morais Allochthonous Complex, has provided new insights into the evolution of the Iberian Variscan belt. The data confirmed that the Parautochthon is composed of two structural units. The higher and more deformed, called the Upper Parautochthon, consists of recumbently folded pre-Variscan low-grade metasediments deposited in the northern Gondwana passive margin during the opening of the Rheic Ocean. It represents the Variscan tectonic duplication of the NW Iberian autochthonous sedimentary sequence triggered by the advance of a stack of allochthonous units formed previously in an accretionary prism. Below this unit, the Lower Parautochthon is a less pervasively deformed tectonic slice including two lithostratigraphic units (Travanca and Vila Chã formations) composed of Culm-type synorogenic low-grade metasediments deposited in a tectonic trench located between the accretionary prism and a peripheral bulge, with detrital zircon age populations pointing to a Late Devonian–Early Carboniferous age. These sediments were subsequently detached from the Autochthon along mechanically weak Silurian carbonaceous slates. The provenance study on the detrital zircons implies that this basin was fed mainly from the active margin. Supplementary material: The complete U–Pb age results obtained by LA-ICP-MS analysis are available at http://www.geolsoc.org.uk/SUP18781.

Timing of dextral strike-slip processes and basement exhumation in the Elbe Zone (Saxo-Thuringian Zone): the final pulse of the Variscan Orogeny in the Bohemian Massif constrained by LA-SF-ICP-MS U-Pb zircon data

Abstract The final pulse of the Variscan Orogeny in the northern Bohemian Massif (Saxo-Thuringian Zone) is related to the closure of the Rheic Ocean, which resulted in subduction-related D1-deformation followed by dextral strike-slip activity (D2-deformation, the Elbe Zone). Taken together, these deformation events reflect the amalgamation of Pangaea in central Europe. Lateral extrusion of high-grade metamorphosed rocks from an allochthonous domain (Saxonian Granulitgebirge) and the top–NW-directed transport of these domains (Erzgebirge nappe complex, Saxonian Granulitgebirge) are responsible for these dextral strike-slip movements. Geochronological data presented herein, together with published data, allow the timing of the final pulse of the Variscan Orogeny and related plutonic, volcano-sedimentary and tectonic processes. Marine sedimentation lasted at least until the Tournaisian (357 Ma). Onset of Variscan strike-slip along the Elbe Zone is assumed to be coeval with the beginning of the top–NW-directed lateral extrusion of the Saxonian Granulitgebirge at 342 Ma (D2-deformation). The sigmoidal shape of the Meissen Massif indicates that strike-slip activity was coexistent with intrusion of the pluton at c. 334 Ma into the schist belt of the Elbe Zone. In contrast, the intrusion of the Markersbach Granite provides a minimum age of c. 327 Ma for the termination of D2 strike-slip activity, because this undeformed pluton cross-cuts all strike-slip related tectonic structures. Geochronological data of an ash bed from the Permo-Carboniferous Döhlen Basin show clearly that post-orogenic sedimentation of Variscan molasse in that area was already active at 305 Ma. This pull-apart basin is a local example of regional Permo-Carboniferous extension within Pangaea. The uplift and denudation of the Variscan basement in the Saxo-Thuringian Zone occurred between c. 327–305 Ma.

Significance of detrital zircons in Siluro-Devonian rocks from Iberia

Seven samples of Siluro-Devonian sedimentary rocks from the Cantabrian and Central Iberian zones of the Iberian Variscan belt have been investigated for provenance and contain four main age populations in variable relative proportion: Ediacaran–Cryogenian (c. 0.55–0.8 Ga), Tonian–Stenian (0.85–1.2 Ga), Palaeoproterozoic (c. 1.8–2.2 Ga) and Archaean (c. 2.5–3.3 Ga). Five samples contain very minor Palaeozoic (Cambrian) zircons and six samples contain minor but significant zircons of Middle and Early Mesoproterozoic (Ectasian–Calymmian, 1.6–1.8) age. These data highlight the transition from an arc environment to a stable platform following the opening of the Rheic Ocean. Variations in detrital zircon populations in Middle–Late Devonian times reflect the onset of Variscan convergence between Laurussia and Gondwana. The presence of a high proportion of zircons of Tonian–Stenian age in Devonian sedimentary rocks may be interpreted as (1) the existence of a large Tonian–Stenian arc terrane exposed in the NE African realm (in or around the Arabian–Nubian Shield), (2) the participation, from the Ordovician time, of a more easterly alongshore provenance of Tonian–Stenian zircons, and (3) an increase in the relative proportion of Tonian–Stenian zircons with respect to the Ediacaran–Cryogenian population owing to the drift of the Avalonian–Cadomian ribbon continent, or the progressive burial of Ediacaran–Cryogenian rocks coeval with the denudation of older source rocks from the craton interior. Supplementary material: Tables with the analytical data and the geochronological results are available at http://www.geolsoc.org.uk/SUP18812.

The zircon evidence of temporally changing sediment transport—the NW Gondwana margin during Cambrian to Devonian time (Aoucert and Smara areas, Moroccan Sahara)

Detrital zircon provenance studies are an established tool to develop palaeogeographic models, mostly based on zircon of siliciclastic rocks and isotope data. But zircon is more than just istopes and features well definable morphological characteristics. The latter may indicate single grain transport histories independent of the individual grade of concordance. This additional tool for palaeogeoraphic reconstructions was tested on zircon from siliciclastic and carbonate sedimentary rocks of Palaeozoic age from the Aoucert and Smara areas of the Souttoufides, while findings of zircon in limestone generally open new archives for sedimentary provenance analysis. The morphologies—length, width, roundness, grain surfaces—of 834 detrital zircons from sediments of allochthonous Cambrian, and (par-)autochthonous Ordovician, and Devonian units were studied, while 772 of them were analysed for their U–Th–Pb isotopes by LA-ICP-MS. Mesoproterozoic zircon contents of more than 10% in the Cambrian sediments exclude the West African Craton (WAC) as exclusive source area. Thus, at least one additional external source is suggested. This is likely the western Adrar Souttouf Massif with its significant Mesoproterozoic zircon inheritance, or comparable, yet unknown sources. Decreasing Mesoproterozoic zircon age populations in Ordovician sediments are thought to be linked to the rifting of the terranes in the course of the Rheic Ocean opening and a predominant supply of WAC detritus. The Devonian sediments likely contain reworked material from the Cambrian siliciclastics, which is shown by the zircon age distribution pattern and the zircon morphologies. Therefore, multiple shifts in the direction of sedimentary transport are indicated.

Provenance of upper Triassic sandstone, southwest Iberia (Alentejo and Algarve basins): tracing variability in the sources

Laser ablation ICP-MS U–Pb analyses have been conducted on detrital zircon of Upper Triassic sandstone from the Alentejo and Algarve basins in southwest Iberia. The predominance of Neoproterozoic, Devonian, Paleoproterozoic and Carboniferous detrital zircon ages confirms previous studies that indicate the locus of the sediment source of the late Triassic Alentejo Basin in the pre-Mesozoic basement of the South Portuguese and Ossa-Morena zones. Suitable sources for the Upper Triassic Algarve sandstone are the Upper Devonian–Lower Carboniferous of the South Portuguese Zone (Phyllite–Quartzite and Tercenas formations) and the Meguma Terrane (present-day in Nova Scotia). Spatial variations of the sediment sources of both Upper Triassic basins suggest a more complex history of drainage than previously documented involving other source rocks located outside present-day Iberia. The two Triassic basins were isolated from each other with the detrital transport being controlled by two independent drainage systems. This study is important for the reconstruction of the late Triassic paleogeography in a place where, later, the opening of the Central Atlantic Ocean took place separating Europe from North America.