Umesh Kumar Singh

Co-occurrence perspective of arsenic and fluoride in the groundwater of Diphu, Assam, Northeastern India

Considerable lacunae exists in As and F(-) co-contamination investigation in the Brahmaputra and Gangetic floodplains. Therefore we selected Diphu a township in the Karbi Plateau rising from the Brahmaputra floodplains for evaluation of As and F co-occurrence, correlation with coexisting ions of the aquifer system and elucidation of potential processes for releasing As and F(-) in the groundwater. Our initial appraisal used generic plots for identification of hydro geochemical processes and major water types. Subsequently, As and F(-) co-occurrence with pH, depth, HCO3(-), SO4(2-), Ca(2+) and Fe were probed for possible correlation followed by hierarchical cluster analyses to identify key processes for co-occurrence. Finally, saturation indices of groundwater minerals were calculated using MINTEQA2 to elucidate prospective As and F(-) release into groundwater. Results indicate F(-) and As presence in Ca-HCO3 rich water along with positive correlation between Ca(2+) and F(-) possibly due to limestone reserves in adjoining areas. Multivariate analyses suggest the presence of high concentrations of PO4(3-), and H4SiO4 either individually or in combination can enhance the mobility of both As and F(-) and possibly abet conditions conducive for co-contamination of aquifers. Initial release of As and F(-) from the parent rock seems driven by the anthropogenic activities while mobilization depends on chemical interactions and individual affinities of the elements. The results of speciation highlight further mobilization of As and F(-) into the groundwater which in turn require regular attention for sustainable management of scarce water resource present in the area.

Movement of toxic metals from small-scale industrial areas: a case study from Delhi, India

In India, an estimated 70% of the total industrial pollution load is attributed to Small and Medium Enterprises (SMEs). Among SMEs, small-scale industries continue to use obsolete technologies with no stringent rules for pollution control. Consequently, waste generated from them is generally dumped without treatment. These facts are strengthened from the analysis conducted on solid waste and wastewater samples from five industrial areas, water samples of river Yamuna, the tributary of river Ganges and solid waste samples of landfill areas in Delhi. Toxic metal concentrations were analysed and found in high concentration in collected samples. Besides that, fractionation study was also done. The data obtained from this study identify that the wastes with high concentrations of toxic metals, calling for the introduction of point source control of waste generation.

Groundwater chemistry and human health risk assessment in the mining region of East Singhbhum, Jharkhand, India.

Groundwater chemistry of mining region of East Singhbhum district having complex contaminant sources were investigated based on heavy metals loads and other hydrochemical constituents. This study aimed to identify the degree of heavy metals exposure and their potential health risk to local population. The results of hydrochemical analysis showed that Na+, K+, and Ca2+ ions are the dominant cations in the groundwater, while HCO3-, F- and Cl- ions dominate the anionic part of the groundwater. The weathering process was considered the dominant factor to determine the major ionic composition in the study area. Compositional analysis for heavy metal has identified that groundwater of the study area is contaminated by Cd, Pb and Cr elements. Source of these metals have been identified as an anthropogenic inputs from mining activities and mineral processing units. Health risk analysis of individual heavy metal for chronic daily intake (CDI) and hazard quotient (HQ) was found in the order of Cr > As > Cd > Pb which is indicating high health risk for the population. In addition, Hazard Index (HI) analysis for heavy metals was found significantly high (>1) which is considered as a threat for human population because they have the tendency to accumulate in the body and cause variety of diseases like kidney problem, dysfunction of liver and renal cortex as well as cancer.

Groundwater fluoride contamination, probable release, and containment mechanisms: a review on Indian context

Fluoride contamination in the groundwater has got great attention in last few decades due to their toxicity, persistent capacity and accumulation in human bodies. There are several sources of fluoride in the environment and different pathways to enter in the drinking water resources, which is responsible for potential effect on human health. Presence of high concentration of fluoride ion in groundwater is a major issue and it makes the water unsuitable for drinking purpose. Availability of fluoride in groundwater indicates various geochemical processes and subsurface contamination of a particular area. Fluoride-bearing aquifers, geological factors, rate of weathering, ion-exchange reaction, residence time and leaching of subsurface contaminants are major responsible factors for availability of fluoride in groundwater. In India, several studies have reported that the groundwater of several states are contaminated with high fluoride. The undesirable level of fluoride in groundwater is one of the most natural groundwater quality problem, which affects large portion of arid and semiarid regions of India. Rajasthan, Andhra Pradesh, Telangana, Tamil Nadu, Gujarat, and West Bengal are the relatively high-fluoride-contaminated states in India. Chronic ingestion of high doses of fluoride-rich water leads to fluorosis on human and animal. Over 66 million Indian populations are at risk due to excess fluoride-contaminated water. Therefore, groundwater contamination subject to undesirable level of fluoride needs urgent attention to understand the role of geochemistry, hydrogeology and climatic factors along with anthropogenic inputs in fluoride pollution.

Stochastic Analysis of Maize (Zea mays) Production in Betul and Madhya Pradesh

Maize (Zea mays) is the third most important cereal crop in the world after wheat and rice. Maize is a domesticated grass of tropical mexican origin which belongs to large and important family of Poaceae. It is a tropical crop and most of the area under this crop is however in the warmer parts of temperate region and in humid subtropical climate and is highest in area having the warmest month isotherms from 21 0 c to 27 0 c and a frostfree season of (120 180) days. Maize grains serve as raw material for manufacture of starch, syrup, dextrose, maltoidextrin, oil, lactic acid and butyl alcohol. In truth starch serve as raw material for paper, textile, adhesive, binding material, braveries and pharmaceutical industries. In India during 2011-12 maize was cultivated in area of about 7.27 million hectare with a production of about 15.86 million tonnes and 2181 kg/ha productivity (Agropedia, 2011-12). Madhya Pradesh is a maize producing state contributing (5.7 percent) to the national production.

Source apportionment of heavy metals and their ecological risk in a tropical river basin system

Surface water and sediment samples were collected from Ajay River basin to appraise the behavior of heavy metals with surrounding environments and their inter-elemental relationships. Parameters like pH and organic carbon are having a minimal role in heavy metal distribution while some elements like Fe and Cu showed great affinity for organic matter based on linear regression analysis (LRA). Ficklin diagram justified that river basin is not contaminated through acidic pollutants. The river basin is highly enriched with Cu, Cd, Pb, and Ni which were much higher than world average values, average shale standard, effect range low (ERL), and threshold effect level (TEL). PCA and LRA verified that Cu, Cd, Pb, and Ni were mainly derived from anthropogenic inputs, and others like Fe, Mn, Zn, and Co came from geogenic sources. Pollution indices revealed that river basin is moderately to highly contaminated by Cu, Cd, and Ni. Furthermore, Ajay River basin is under strong potential ecological risk based on the obtained value of risk index and probable effect level/effect range median quotient index. However, river basin is strongly influenced by lithological properties, diversified hydrogeological settings, mineralization and mobilization of subsurface materials, and urban and industrial effluents which are controlling the heavy metals.