V. Raj

Formation of ceramic nanocomposite coatings on aluminium by anodisation using magnesium sulphate with silicate additive

Abstract Nanostructured composite coatings on aluminium were fabricated by an anodisation technique. In this study, special attention was also given to investigate the effect of current density (CD) on surface morphology, elemental/phase composition and corrosion behaviour. In addition to this, thickness and growth rate were optimised with respect to anodising time and concentration of the electrolyte. Nanocomposite coatings on aluminium substrates with an average crystallite size of 48 nm were obtained by anodising in an aqueous sulphate electrolyte solution after a comprehensive investigation of the anodisation conditions. Energy dispersive spectroscopy analysis confirmed that the aluminium content in the top of the coatings increases as CD is raised up to 0·15 A cm−2. Atomic force microscopic analysis confirmed that the mean distribution, average roughness and root mean square roughness values increase significantly at CD above 0·15 A cm−2. The corrosion behaviour of the fabricated nanocomposite coatings was also evaluated using Tafel polarisation and electrochemical impedance spectroscopy.

Effect of voltammetric parameters on fabrication of highly ordered nanoporous alumina structures

Abstract The synthetic route of quantum wires, nanorods and nanotubes has recently acquired immense popularity, as the technique is easy, low cost and less skill dependent. In the present work, highly ordered, nanoporous alumina structures have been synthesised on aluminium in oxalic acid electrolyte using cyclic voltammetry by critically controlling the oxidation potential, temperature, time and concentration of the oxalic acid. Self–organised pores were developed over the anodic alumina. The effect of concentration of electrolyte, oxidation potential, temperature and treatment time were correlated with the morphology of the nanoporous alumina layers. The mechanism of the pore formation and its growth with respect to the changes in the nanostructures was also highlighted. Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-Ray diffraction (XRD) were used as the characterisation tools in different stages of the experiment.