Vahid A. Hosseini

Effect of Sigma Phase Morphology on the Degradation of Properties in a Super Duplex Stainless Steel

Sigma phase is commonly considered to be the most deleterious secondary phase precipitating in duplex stainless steels, as it results in an extreme reduction of corrosion resistance and toughness. Previous studies have mainly focused on the kinetics of sigma phase precipitation and influences on properties and only a few works have studied the morphology of sigma phase and its influences on material properties. Therefore, the influence of sigma phase morphology on the degradation of corrosion resistance and mechanical properties of 2507 super duplex stainless steel (SDSS) was studied after 10 h of arc heat treatment using optical and scanning electron microscopy, electron backscattered diffraction analysis, corrosion testing, and thermodynamic calculations. A stationary arc was applied on the 2507 SDSS disc mounted on a water-cooled chamber, producing a steady-state temperature gradient covering the entire temperature range from room temperature to the melting point. Sigma phase was the major intermetallic precipitating between 630 °C and 1010 °C and its morphology changed from blocky to fine coral-shaped with decreasing aging temperature. At the same time, the average thickness of the precipitates decreased from 2.9 µm to 0.5 µm. The chemical composition of sigma was similar to that predicted by thermodynamic calculations when formed at 800–900 °C, but deviated at higher and lower temperatures. The formation of blocky sigma phase introduced local strain in the bulk of the primary austenite grains. However, the local strain was most pronounced in the secondary austenite grains next to the coral-shaped sigma phase precipitating at lower temperatures. Microstructures with blocky and coral-shaped sigma phase particles were prone to develop microscale cracks and local corrosion, respectively. Local corrosion occurred primarily in ferrite and in secondary austenite, which was predicted by thermodynamic calculations to have a low pitting resistance equivalent. To conclude, the influence of sigma phase morphology on the degradation of properties was summarized in two diagrams as functions of the level of static load and the severity of the corrosive environment.

Effect of welding parameters on semisolid stir welding of Mg–9Al–1Zn magnesium alloy

Abstract Semisolid stir welding of AZ91 was investigated with focus on the joining temperature and rotational speed. An Mg–25%Zn interlayer was located between two AZ91 pieces and the system was heated up to the semisolid state of base metal and interlayer. The weld seam was stirred using a drill-tip at different joining temperatures and rotational speeds. Optical and scanning electron microscopes were employed to study microstructure, cavity formation, and segregation. Hardness profile and shear punch test were also employed to rank the welds based on their quality and homogeneity. Results showed that the lowest cavity content (2.1%) with the maximum ultimate shear strength (about 188 MPa) was obtained in weld with the joining temperature of 530 °C and the rotational speed of 1600 r/min. Low quality welds and a reduction of ultimate shear strength were observed at very high or low rotational speeds and joining temperatures. The process, in conclusion, produced close mechanical properties to those of the base metal and homogenous quality throughout the joint, when the intermediate temperature and rotational speeds were employed.