Vahid Hosseini

Effects of different cetane number enhancement strategies on HCCI combustion and emissions

Cetane number is the accepted indicator for quantifying the autoignition characteristics of diesel fuels in compression ignition engines. Diesel fuel specifications typically require a minimum cetane number to achieve satisfactory combustion behaviour in conventional diesel engines. In contrast, a high cetane number fuel may not be beneficial for implementing high efficiency, clean combustion strategies such as homogeneous charge compression ignition (HCCI). The purpose of this study was to investigate cetane number effects on HCCI combustion and emissions. The experiments were conducted in a single-cylinder, variable compression ratio, cooperative fuel research engine operated in HCCI combustion mode. The fuels were finely atomized and partially vaporized in the intake manifold. The base fuel was a low cetane refining stream derived from oil sands sources. Three different methods were employed to increase the base fuel cetane number, namely hydroprocessing, cetane improver addition, and blending with a renewable fuel component. Results show that the three methods of cetane number enhancement produce significantly different HCCI combustion behaviour. The hydroprocessed fuels exhibited more stable and complete combustion than the base fuel, which resulted in a wider operating region, reduced carbon monoxide, unburned hydrocarbon, and nitrogen oxide (NO x ) emissions, and lower indicated specific fuel consumption (ISFC). The main disadvantages of the hydroprocessed fuels were the higher exhaust gas recirculation rates required to retard the combustion phasing, which limits the maximum indicated mean effective pressure for a given intake pressure, and increased knock intensity due to a faster combustion process. In comparison, the other two methods of fuel cetane enhancement increased ISFC compared to the base fuel. The addition of nitrate cetane improver resulted in higher NO x emissions, while blending with a renewable fuel component increased hydrocarbon emissions. The experimental data provide evidence that the magnitude and phasing of low temperature heat release, as well as fuel volatility, play important roles in HCCI combustion.

Urban Air Pollution in Iran

Urban air pollution is a major health risk in several large Iranian cities. Transportation, extensive use of fossil fuels, outdated urban fleets of gasoline and diesel vehicles, industrial sources within and close to the city boundaries and natural dust are major contributing factors. Starting with Tehran, emission inventories and mathematical air pollution models are being developed. Air quality is being monitored and reported to the public, though data availability and validity remain a challenge. While national and local air pollution mitigation plans are in place, progress remains slow, coordination is weak, and sources of funding are limited.

Annual and seasonal spatial models for nitrogen oxides in Tehran, Iran

Very few land use regression (LUR) models have been developed for megacities in low- and middle-income countries, but such models are needed to facilitate epidemiologic research on air pollution. We developed annual and seasonal LUR models for ambient oxides of nitrogen (NO, NO2, and NOX) in the Middle Eastern city of Tehran, Iran, using 2010 data from 23 fixed monitoring stations. A novel systematic algorithm was developed for spatial modeling. The R2 values for the LUR models ranged from 0.69 to 0.78 for NO, 0.64 to 0.75 for NO2, and 0.61 to 0.79 for NOx. The most predictive variables were: distance to the traffic access control zone; distance to primary schools; green space; official areas; bridges; and slope. The annual average concentrations of all pollutants were high, approaching those reported for megacities in Asia. At 1000 randomly-selected locations the correlations between cooler and warmer season estimates were 0.64 for NO, 0.58 for NOX, and 0.30 for NO2. Seasonal differences in spatial patterns of pollution are likely driven by differences in source contributions and meteorology. These models provide a basis for understanding long-term exposures and chronic health effects of air pollution in Tehran, where such research has been limited.

Fuel Property Effects on PCCI Combustion in a Heavy-Duty Diesel Engine

An experimental study was performed to investigate fuel property effects on Premixed-Charge Compression Ignition (PCCI) combustion in a heavy-duty diesel engine. A matrix of research diesel fuels designed by the Coordinating Research Council, referred to as the Fuels for Advanced Combustion Engines (FACE), was used. The fuel matrix design covers a wide range of cetane numbers (30 to 55), 90% distillation temperatures (270 to 340°C) and aromatics content (20 to 45%). The fuels were tested in a single-cylinder Caterpillar diesel engine equipped with a common-rail fuel injection system. The engine was operated at 900 rpm, a relative air/fuel ratio of 1.2 and 60% exhaust gas recirculation (EGR) for all fuels. The study was limited to a single fuel injection event starting between −30° and 0°CA with a rail pressure of 150 MPa. The brake mean effective pressure (BMEP) ranged from 3.2 to 3.6 bar depending on the fuel and fuel injection timing. The experimental results show that cetane number was the most important fuel property affecting PCCI combustion behavior. The low cetane number fuels had better BSFC due to more optimized combustion phasing and shorter combustion duration. They also had a longer ignition delay period available for premixing, which led to near-zero soot emissions. The two fuels with high cetane number and high 90% distillation temperature produced significant soot emissions when the start of combustion occurred before the end of fuel injection. The two fuels with high cetane number and high aromatics produced the highest brake specific NOx emissions, although the absolute values were below 0.1 g/kW-hr. Brake specific HC and CO emissions were primarily a function of the combustion phasing, but the low cetane number fuels had slightly higher HC and lower CO emissions than the high cetane number fuels.Copyright

Development of Hot Exhaust Emission Factors for Iranian-Made Euro-2 Certified Light-Duty Vehicles

Emission factors (EFs) are fundamental, necessary data for air pollution research and scenario implementation. With the vision of generating national EFs of the Iranian transportation system, a portable emission measurement system (PEMS) was used to develop the basic EFs for a statistically significant sample of Iranian gasoline-fueled privately owned light duty vehicles (LDVs) operated in Tehran. A smaller sample size of the same fleet was examined by chassis dynamometer (CD) bag emission measurement tests to quantify the systematic differences between the PEMS and CD methods. The selected fleet was tested over four different routes of uphill highways, flat highways, uphill urban streets, and flat urban streets. Real driving emissions (RDEs) and fuel consumption (FC) rates were calculated by weighted averaging of the results from each route. The activity of the fleet over each route type was assumed as a weighting factor. The activity data were obtained from a Tehran traffic model. The RDEs of the selected fleet were considerably higher than the certified emission levels of all vehicles. Differences between Tehran real driving cycles and the New European Driving Cycle (NEDC) was attributed to the lower loading of NEDC. A table of EFs based on RDEs was developed for the sample fleet.

Land Use Regression Models for Alkylbenzenes in a Middle Eastern Megacity: Tehran Study of Exposure Prediction for Environmental Health Research (Tehran SEPEHR)

Land use regression (LUR) has not been applied thus far to ambient alkylbenzenes in highly polluted megacities. We advanced LUR models for benzene, toluene, ethylbenzene, p-xylene, m-xylene, o-xylene (BTEX), and total BTEX using measurement based estimates of annual means at 179 sites in Tehran megacity, Iran. Overall, 520 predictors were evaluated, such as The Weather Research and Forecasting Model meteorology predictions, emission inventory, and several new others. The final models with R2 values ranging from 0.64 for p-xylene to 0.70 for benzene were mainly driven by traffic-related variables but the proximity to sewage treatment plants was present in all models indicating a major local source of alkylbenzenes not used in any previous study. We further found that large buffers are needed to explain annual mean concentrations of alkylbenzenes in complex situations of a megacity. About 83% of Tehrans surface had benzene concentrations above air quality standard of 5 μg/m3 set by European Union and Iranian Government. Toluene was the predominant alkylbenzene, and the most polluted area was the city center. Our analyses on differences between wealthier and poorer areas also showed somewhat higher concentrations for the latter. This is the largest LUR study to predict all BTEX species in a megacity.

The Effect of Iso-Octane Addition on Combustion and Emission Characteristics of a HCCI Engine Fueled With n-Heptane

This paper investigates the effects of iso-octane addition on the combustion and emission characteristics of a single-cylinder, variable compression ratio, homogeneous charge compression ignition (HCCI) engine fueled with n-heptane. The engine was operated with four fuel blends containing up to 50% iso-octane by liquid volume at 900 rpm, 50:1 air-to-fuel ratio, no exhaust gas recirculation, and an intake mixture temperature of 30°C. A detailed analysis of the regulated and unregulated emissions was performed including validation of the experimental results using a multizone model with detailed fuel chemistry. The results show that iso-octane addition reduced HCCI combustion efficiency and retarded the combustion phasing. The range of engine compression ratios where satisfactory HCCI combustion occurred was found to narrow with increasing iso-octane percentage in the fuel. NOx emissions increased with iso-octane addition at advanced combustion phasing, but the influence of iso-octane addition was negligible once CA50 (crank angle position at which 50% heat is released) was close to or after top dead center. The total unburned hydrocarbons (THC) in the exhaust consisted primarily of alkanes, alkenes, and oxygenated hydrocarbons. The percentage of alkanes, the dominant class of THC emissions, was found to be relatively constant. The alkanes were composed primarily of unburned fuel compounds, and iso-octane addition monotonically increased and decreased the iso-octane and n-heptane percentages in the THC emissions, respectively. The percentage of alkenes in the THC was not significantly affected by iso-octane addition. Iso-octane addition increased the percentage of oxygenated hydrocarbons. Small quantities of cycloalkanes and aromatics were detected when the iso-octane percentage was increased beyond 30%.

Seasonal trends in the composition and sources of PM2.5 and carbonaceous aerosol in Tehran, Iran

Currently PM2.5 is a major air pollution concern in Tehran, Iran due to frequent high levels and possible adverse impacts. In this study, which is the first of its kind to take place in Tehran, composition and sources of PM2.5 and carbonaceous aerosol were determined, and their seasonal trends were studied. In this regard, fine PM samples were collected every six days at a residential station for one year and the chemical constituents including organic marker species, metals, and ions were analyzed by chemical analysis. The source apportionment was performed using organic molecular marker-based CMB receptor modeling. Carbonaceous compounds were the major contributors to fine particulate mass in Tehran, as OC and EC together comprised on average 29% of PM2.5 mass. Major portions of OC in Tehran were water insoluble and are mainly attributed to primary sources. Higher levels of several PAHs, which are organic tracers of incomplete combustion, and hopanes and steranes as organic tracers of mobile sources were obtained in cold months and compared to the warm months. The major contributing source to particulate OC was identified as vehicles, which contributed about 72% of measured OC. Among mobile sources, gasoline-fueled vehicles had the highest impact with a mean contribution of 48% to the measured OC. Mobile sources also were the largest contributor to total PM2.5 (40%), followed by dust (24%) and sulfate (11%). In addition to primary emissions, mobile sources also directly and indirectly played an important role in another 27% of fine particulate mass (secondary organics and ions), which highlights the impact of vehicles in Tehran. Our results highlighted and quantified the role of motor vehicles in fine PM production, particularly during winter time. The results of this study could be used to set more effective regulations and control strategies particularly upon mobile sources.

Evaluation of the main operating parameters of a homogeneous charge compression ignition engine for performance optimization

Homogeneous charge compression ignition engines require a smart control system to regulate the input quantities of the engine in various operational conditions. Achieving an optimum combustion needs an appropriate system response for different engine loads and speeds according to the power acquired from the engine, as well as the amounts of emissions present in the exhaust. Therefore, performing a set of experimental tests together with numerical simulations in a wide range of conditions facilitates calibration of the input parameters of the engine. In this study, the effects of the thermodynamic parameters and the thermokinetic parameters on the engine output in the preliminary design stage were obtained at different speeds to determine the optimum exhaust emissions, the optimum combustion timing and the ranges of misfiring and knock, using multiple-zone thermodynamic modelling. On the assumption that the simulation cycle is closed, the probability density function was used to determine the initial conditions for the temperature and the residual gas from the previous cycle mass distribution in each area inside the cylinder. The results obtained proved that the kinetic properties of the mixture due to the effects of the the air-to-fuel ratio, the percentage of exhaust gas recirculation and the percentage of reformer gas have dominant effects on the output in comparison with the thermodynamic parameters such as the intake pressure and the intake temperature. At low speeds, exhaust gas recirculation retards combustion and delays engine knock. At higher engine speeds, the reformer gas advances combustion and improves misfiring.

Solid nanoparticle and gaseous emissions of a diesel engine with a diesel particulate filter and use of a high-sulphur diesel fuel and a medium-sulphur diesel fuel

High-sulphur and medium-sulphur diesel fuels are still used in several countries. Although diesel particulate filter technology for on-road diesel engines has existed since 1989, the availability of high-sulphur and medium-sulphur diesel fuels in the market causes delays in the use of catalysed filter technologies. However, the situation in places such as Tehran is considered unhealthy because of particles and black carbon, and full distribution of ultra-low-sulphur diesel is awaited eagerly. The purpose of this study is to investigate the effect of the sulphur content in fuels on the gaseous and solid exhaust emissions of a 220 kW Euro II engine equipped with a sintered metal active–passive filter, focusing on the regeneration phenomenon. The results show that the efficiency for filtering the maximum number of particles was 99.9% and that the average was above 99% for steady-state operating conditions for both high-sulphur diesel (7700 ppm) and medium-sulphur diesel (229 ppm). The removal efficiency of the particle mass was low in the case of high-sulphur diesel owing to the sulphate condensate collection effect as the result of using a non-heated sample line. During regeneration, the number of particles increased in comparison with that in the filtration phase but the total number of emitted particles was less than the engine baseline value. The results for both fuels were the same, and the only measurable difference was the high sulphur dioxide production in the high-sulphur diesel during regeneration. This study demonstrates the potential of this type of filter technology for the effective removal of solid particles independent of the sulphur content of the fuel. With the exception of the decrease in the removal efficiency of the particle mass and the high sulphur dioxide production, no other notable difference was observed to be caused by the change in the sulphur content of the diesel fuel.