Valentin Barna

Random lasing and weak localization of light in dye-doped nematic liquid crystals

The first observation of random laser action in a partially ordered, optically anisotropic nematic liquid crystal with long-range dielectric tensor fluctuations is reported. Above a given pump power the fluorescence curve collapses and the typical narrowing and explosion effect leads to discrete sharp peaks. The unexpected surviving of interference effects in recurrent multiple scattering provide the required optical feedback for lasing in nematics. Coherent backscattering of light waves in orientationally ordered nematic liquid crystals manifests a weak localization of light which strongly supports diffusive laser action in presence of gain medium. Intensity fluctuations of the speckle-like emission pattern indicate the typical spatio-temporal randomness of diffusive laser emission. A comparison of the laser action is reported for systems with different order degree: fully disordered semiconductor powders, self-ordered cholesterics and partially ordered nematic liquid crystals.

Random lasing in freely suspended dye-doped nematic liquid crystals.

Random lasing in fully disordered systems having organic and inorganic nature has been the subject of extensive studies since the beginning of the past decade. The interest mainly emerges from the unexpected role played by disorder in the laser action. The disorder was considered detrimental for the optical feedback in cavity laser, until it was demonstrated that multiple-scattering materials including a gain medium act as random laser. Here, a completely new approach is reported, where freely suspended complex fluid films doped with fluorescent molecules under optical excitation generate narrowband lasing peaks. The constellation of localized modes is selected by properly choosing the gain profile. The idea to have laser action in absence of mirrors and boundaries realizes an unparalleled tunable and moldable laser source.

Thermal behavior of random lasing in dye doped nematic liquid crystals

The role of the thermally modulated order parameter in the diffusive laser action observed in dye doped nematic liquid crystals was investigated. Above a given pump energy a randomly distributed series of bright tiny spots appear, giving rise to a strongly fluctuating emission pattern. The spectral analysis reveals discrete sharp peaks (about 0.5nm) slightly blueshifted with respect to the highest efficiency region of the gain medium. A comparative study was performed in systems having different sizes and confining geometries, corroborating the idea that the random lasing observed in dye doped nematic phase is fluctuation driven through a recurrent multiple scattering process.

Periodic and aperiodic liquid crystal-polymer composite structures realized via spatial light modulator direct holography

In this work we present the first realization and characterization of two-dimensional periodic and aperiodic POLICRYPS (Polymer Liquid Crystal Polymer Slices) structures, obtained by means of a single-beam holographic technique exploiting a high resolution spatial light modulator (SLM). A first investigation shows that the gratings, operating in the Raman Nath regime, exhibit a morphology and a electro-optical behavior that are typical of the POLICRYPS gratings realized by two-beam interference holography.

Thermo-recurrent nematic random laser

This experimental work is aimed to investigate the thermal behavior of random laser action in dye doped nematic liquid crystals. The study evidenced an important temperature dependence of the random lasing characteristics in the nematic phase and in close proximity of the nematicisotropic (N-I) phase transition. A lowering of the laser emission intensity as the temperature increases is strictly related to the shift of the lasing threshold as function of the temperature even though the pump energy is kept fixed. The optical losses increasing owing to the thermal fluctuation enhanced scattering drive the input-output smoother behavior until the system stops to lase, because below threshold. The unexpected reoccurrence of random lasing at higher temperature, in proximity of N-I transition is found to be related to a different scattering mechanism, the micro-droplets nucleation and critical opalescence.

Distributed feedback micro-laser array: helixed liquid crystals embedded in holographically sculptured polymeric microcavities

We report a detailed physical characterization of a novel array of organic distributed feedback microcavity lasers possessing a high ratio between the quality factor Q of the resonant cavity and its volume V. The optical microcavity was obtained by confining self-organized mesophases doped with fluorescent guest molecules into holographically patterned polymeric microchannels. The liquid crystal microchannels act as mirror-less cavity lasers, where the emitted laser light propagates along the liquid crystal helical axis behaving as Bragg resonator. This miniaturization process allows us to obtain a micro-laser array possessing an ultralow lasing threshold (25nJ/pulse) while having directional control on the lasing emission, a fine wavelength tunability and the control over the emission intensity.

Fast electro-optic switching in nematic liquid crystals

The switching between on and off states of nematic liquid crystal pixels can be controlled with the well-known electro-optic effect. This effect however presents a fast response at switching on the electric field but a slow response at switching it off. Here we show a suitable choice of materials, cell geometries, surface preparations, and time dependence of the applied voltage that leads to a switch off response as fast as that at switch on. This is due to the particular conductivity mechanism in polymers with aromatic rings leading to rectifying properties when deposited on top of indium tin oxide surface. A transient negative charge at polymer–liquid crystal interface favors a faster and stronger planar orientation of the nematic molecules diminishing drastically the switch off time and increasing the contrast ratio. These facts, interesting enough from a fundamental point of view, could also lead to important technological consequences.

Nanoscale alignment and optical nanoimaging of a birefringent liquid.

An anisotropic nanopatterning method, based on a technique of atomic force microscopy (AFM) scribing of a thin polyimide film, is used to generate an alignment layer whose topography depends on the writing direction. Detailed experimental measurements are presented for the topographical anisotropy that arises when the polyimide alignment layer is scribed parallel and antiparallel to the AFM cantilever orientation. By means of a novel nanotomographic approach, the optical retardation δ of an alignable birefringent liquid that covers the scribed substrate is measured with unprecedented resolution of only a few tens of nanometers. In this technique a thin optical fiber is raster-scanned at several fixed heights inside the birefringent liquid, and the transmitted polarized light is collected downstream. The optical retardation δ from the fibers tip to the polyimide interface was measured as a function of position x,y,z, with the results reflecting the spatially varying depth of the medium due to the polymer film surface topography. Theoretical calculations for δ are in excellent agreement with both the topographical and the high resolution nanoimaging experimental results obtained.

Band edge and defect modes lasing due to confinement of helixed liquid crystals in cylindrical microcavities

Peculiar light emission properties have been observed in cylindrical microcavity hosting dye-doped helixed liquid crystals, which behaves as a fiber-like multidirectional distributed feedback laser. Experimental studies performed for this level of confinement show that laser action is exhibited both axially and radially, indicating a self-organized three-dimensional blue phase-like configuration. Thermal wavelength tunability was observed for both orientations emphasizing two different linear behaviors. The distributed feedback mechanism and the Q factor of the mirrorless resonant cavity result enhanced for axial stimulated emission because of the significant increase in the number of helical periods. In addition, long-lived spectrally narrow defect modes appear within the photonic band gap owing to optical phase jumps which take place in local structural defects.

Analytical approach for type-II semiconductor spherical core–shell quantum dots heterostructures with wide band gaps

Abstract A one-band model within the effective mass approximation is adopted to characterize the energy structure and oscillator strength of type-II semiconductor spherical core–shell quantum dots. The heteroepitaxial strain of the core–shell heterostructure is modeled by the elastic continuum approach. The model is applied to ZnTe/ZnSe core–shell, a wide band gap type-II heterostructure. The simulated absorption spectra are in fair agreement with available experimental results.