Valentin Soloiu

Tribological Effects of Mineral-Oil Lubricant Contamination with Biofuels: A Pin-on-Disk Tribometry and Wear Study

Use of biodiesel produces engine oil dilution because of unburned biodiesel impinging on cold walls of the combustion chamber, being scrapped to the oil pan, and leading to changes of oil friction, wear and lubricity properties. In this paper, mixtures of SAE 15W-40 oil, which were contaminated by known percentages of the biodiesels from canola oil, peanut oil, soybean oil, and chicken fat, were tested in a pin-on-disk tribometer. A contact was employed of AISI 1018 steel disk and AISI 316 stainless-steel ball for pin material, and friction force and specific wear were measured. Wear on the disk surfaces showed that any degree of mineral-oil dilution by the tested biodiesels reduces the wear protection of engine oil even at small mixture percentages. However, these reductions were not substantially different than those observed for same percentages of dilution of mineral oil by fossil diesel. The tested mixture of oil contaminated with animal fat feedstock (e.g., chicken fat) biodiesel showed the best wear behavior as compared to those for the other tested mixtures (of mineral oil with vegetable feedstock biodiesel dilutions). Obtained results are discussed as baseline for further studies in a renewable energy multidisciplinary approach on biofuels and biolubes.

Investigation of Low Temperature Combustion Regimes of Biodiesel With N-Butanol Injected in the Intake Manifold of a Compression Ignition Engine

In this study, the in-cylinder soot and NOx trade off was investigated in a compression engine by implementing premixed charge compression ignition (PCCI) coupled with low temperature combustion (LTC) for selected regimes of 1–3 bars IMEP. In order to achieve that, an omnivorous (multifuel) single cylinder diesel engine was developed by injecting n-butanol in the intake port while being fueled with biodiesel by direct injection in the combustion chamber. By applying this methodology, the in-cylinder pressure decreased by 25% and peak pressure was delayed in the power stroke by about 8 CAD for the cycles in which the n-butanol was injected in the intake manifold at the engine speed of 800 rpm and low engine loads, corresponding to 1–3 bars IMEP. Compared with the baseline taken with ultra-low sulfur diesel no. 2 (USLD#2), the heat release presented a more complex shape. t 1–2 bars IMEP, the premixed charge stage of the combustion totally disappeared and a prolonged diffusion stage was found instead. At 3 bars IMEP, an early low temperature heat release was present that started 6 deg (1.25 ms) earlier than the diesel reference heat release with a peak at 350 CAD corresponding to 1200 K. Heat losses from radiation of burned gas in the combustion chamber decreased by 10–50% while the soot emissions showed a significant decrease of about 98%, concomitantly with a 98% NOx reduction at 1 IMEP, and 77% at 3 IMEP, by controlling the combustion phases. Gaseous emissions were measured using an AVL SESAM FTIR and showed that there were high increases in CO, HC and NMHC emissions as a result of PCCI/LTC strategy; nevertheless, the technology is still under development. The results of this work indicate that n-butanol an be a very promising fuel alternative including for LTC regimes.

Combustion and Emissions Characteristics of a Polypropylene Blended Diesel Fuel in a Direct Injection Compression Engine

The authors investigated the formulation, combustion and emissions of polypropylene (PP)–diesel fuel mixtures in a direct injection diesel engine. The fuel has been obtained by an original technology they developed, in which the low or high density polypropylene (LDPP, HDPP), have been mixed in a nitrogen atmosphere at 200 °C, 10–40% by wt. in diesel fuel. The kinematic viscosity of the polypropylene-diesel fuels was investigated between 25–250 °C and the results showed that viscosity of the plastic mixtures is much higher than that of diesel alone, ranging from 10 cSt to 500 cSt, and depending on the plastic structure, content, and temperature. The TGA and DTA analysis has been conducted to investigate the oxidation and combustion properties of pure PP and polymerdiesel fuels. The results showed that at about 125 °C, the LDPP melts, but does not decompose up 240 °C, when the oxidation starts, and has a peak of heat release at 340–350 °C, and the process is completed at 400 °C. The engine’s injection system used, was a piston-barrel type pump, capable of an injection pressure of 200 bars. The injector had 4 × 0.200 mm nozzles with a conical tip needle. The 25% PP-diesel mixture had a successful ignition in a direct injection 110 mm bore, omega combustion chamber engine. The ignition delay for polypropylene-diesel mixtures was longer by about 0.5 ms (at 1200 rpm), compared with diesel. The heat release showed a different development compared with the reference diesel fuel, the premixed phase being inhibited while a slow diffusion combustion phase fully developed. The maximum combustion pressure has been 83 bars for diesel and decreased by 2 bars for the blended fuel, while the bulk gas maximum temperature (calculated) reached about 2500 K for diesel vs 2600 K for polypropylene mixture. The heat flux calculated by the Annand model has shown lower values for diesel fuel with a maximum of about 2.7 MW/m2 compared with 3.0 MW/m2 for PP blended fuel with similar values for convection flux for both fuels at about 1.57 MW/m2 and a higher radiation flux of about 1.44 MW/m2 for PP fuel versus 1.27 MW/m2 for diesel. The heat lost during the cycle shows low values for the premixed combustion stage and increased values for the diffusion stage for both fuels. The exhaust temperatures have been practically identical for both fuels for all loads, with emissions of NOx, and CO reduced by 40% for the alternative fuel, while the CO2 exhibited almost the same values for both fuels. The smoke emissions decreased by 60–90% for the polypropylene blended fuel depending on the load, The engines’ overall efficiency was slightly lower for PP fuel at low loads compared with diesel combustion but at 100% load both reached 36%. The study showed that the new formulation process proposed by the authors is able to produce a new class of fuels from diesel blended with low density polypropylene, and resulted in hybrid fuels with very promising combustion prospects. The engine investigation proved that 25% PP fuels can be injected and burnt in a diesel engine at a residence time of about 5 ms from the start of injection, and the engine’s nominal power could be reached, with lower emissions than reference diesel fuel.Copyright

Jet-Impingement Effects of Alumina-Nanofluid on Aluminum and Copper

Nanofluids are nanosize-powder suspensions that are of interest for their enhanced thermal transport properties. They are studied as promising alternatives to ordinary cooling fluids, but the tribiological effects of nanofluids on cooling-system materials are largely unknown. The authors have developed methodology that uses jet impingement on typical cooling-system materials to test such effects. The work is presented of the authors’ research on the interactions of a typical nanofluid (2% volume of alumina nanopowders in a solution of ethylene glycol in water) which is impinged on aluminum and copper specimens for tests as long as 112 hours. The surface changes were assessed by roughness measurements and optical-microscope studies. Comparative roughness indicate that both the reference cooling fluid of ethylene glycol and water and its nanofluid with 2% alumina produce roughness changes in aluminum (even for the shortest 3-hour test), but no significant roughness differences were observed between them. No significant roughness changes were observed for copper. Microscopy observations, however, show different surface modifications in both aluminum and copper by both the nanofluid and its base fluid. The possible mechanisms of early erosion are discussed. These investigations demonstrate suitable methods for the testing of nanofluid effects on cooling system-materials.

RCCI Operation With PFI of n-Butanol and DI of Biodiesel Compared With DI of Binary Mixtures of n-Butanol and Biodiesel

In this study the Reactive Controlled Combustion Ignition (RCCI) obtained by early port fuel injection (PFI) of n-butanol and direct injection (DI) of biodiesel were compared with in cylinder direct injected binary mixture of n-butanol and biodiesel with the same mass ratio of 3:1 in both fuelling strategies. The combustion and emissions characteristics were investigated at 5 bars IMEP at 1400 rpm. The ignition for DI of n-butanol-biodiesel binary blends showed a delay by approximately 7.5°CAD compared with the PFI case. For the binary mixture, n-butanol-biodiesel, the combustion pressure has decreased by 50% compared to the PFI of butanol. The maximum in cylinder gas temperature decreased by 100K for the n-butanol-biodiesel mixture versus ULSD#2 and has also experienced a 10° CAD delay. The premixed charge combustion has been split into two regions of high temperature heat release, an early one BTDC, and a second stage, ATDC for the PFI strategy. Increasing the load to 7.5 bars IMEP, heavy knock occurred for the PFI case. The soot emissions showed a 90% decrease with n-butanol injection PFI and by 98% reduction for DI of n-butanol binary mixture with the biodiesel, while the NOx emissions were reduced by 40% in both cases. The aldehyde emissions exhibited a significant 95% decrease for the n-butanol-biodiesel binary mixture compared with the n-butanol PFI. The mechanical efficiency at 80% and thermal efficiency and 38% were found similar, for both fuelling strategies.The results of this work suggest that the DI of n-butanol-biodiesel binary mixtures is more effective in reducing emissions than PFI of n-butanol combined with DI of biodiesel and also less likely to produce knock.Copyright

RCCI of synthetic kerosene with PFI of N-butanol-combustion and emissions characteristics

In this study, the combustion and emissions characteristics of Reactivity Controlled Compression Ignition (RCCI) obtained by direct injection (DI) of S8 and port fuel injection (PFI) of n-butanol were compared with RCCI of ultra-low sulfur diesel #2 (ULSD#2) and PFI of n-butanol at 6 bar indicated mean effective pressure (IMEP) and 1500 rpm. S8 is a synthetic paraffinic kerosene (C6–C18) developed by Syntroleum and is derived from natural gas. S8 is a Fischer-Tropsch fuel that contains a low aromatic percentage (0.5 vol. %) and has a cetane number of 63 versus 47 of ULSD#2. Baselines of DI conventional diesel combustion (CDC), with 100% ULSD#2 and also DI of S8 were conducted. For both RCCI cases, the mass ratio of DI to PFI was set at 1:1. The ignition delay for the ULSD#2 baseline was found to be 10.9 CAD (1.21 ms) and for S8 was shorter at 10.1 CAD (1.12 ms). In RCCI, the premixed charge combustion has been split into two regions of high temperature heat release, an early one BTDC from ignition of ULSD#2 or S8, and a second stage, ATDC from n-butanol combustion. RCCI with n-butanol increased the NOx because the n-butanol contains 21% oxygen, while S8 alone produced 30% less NOx emissions when compared to the ULSD#2 baseline. The RCCI reduced soot by 80–90% (more efficient for S8). However, S8 alone showed a considerable increase in soot emissions compared with ULSD#2. The indicated thermal efficiency was the highest for the ULSD#2 and S8 baseline at 44%. The RCCI strategies showed a decrease in indicated thermal efficiency at 40% ULSD#2-RCCI and 42% and for S8-RCCI, respectively.S8 as a single fuel proved to be a very capable alternative to ULSD#2 in terms of combustion performance nevertheless, exhibited higher soot emissions that have been mitigated with the RCCI strategy without penalty in engine performance.Copyright

Cotton Seed FAME Combustion and Emissions Research in a DI Diesel Engine

This study investigates the combustion characteristics of cotton seed fatty acid methyl esters (FAME), with C100 (100% cotton seed biodiesel) and C20 (20% cotton seed biodiesel, 80% ultra-low sulfur diesel #2), in a direct injection diesel engine and compares the results with ultra-low sulfur diesel #2 (ULSD#2). The dynamic viscosity of C100 was found to meet the American Society for Testing and Materials (ASTM) standard. The lower heating value obtained for C100 was 37.7 MJ/kg, compared to 42.7 MJ/kg for ULSD#2. ULSD#2 and C100 displayed ignition delays of 9.6 crank angle degrees (CAD) and 7 CAD representing 1.14 ms and 0.83 ms respectively and a combustion time of 4ms (35 CAD) at 1400 rpm and 8 bar indicated mean effective pressure (IMEP) (100% load). The apparent heat release of the tested fuels at 8 bar IMEP showed both a premixed and diffusion phase and produced maximum values of 122 and 209 J/CAD for C100 and ULSD#2 respectively, with a decreasing trend occurring with increase in percentage of FAME. The 50% mass burnt (CA50) for 100% biodiesel was found to be 3 CAD advanced, compared with ULSD#2. The maximum total heat flux rates showed a value of 3.2 MW/m2 for ULSD#2 at 8 bar IMEP with a 6% increase observed for C100. Mechanical efficiency of ULSD#2 was 83% and presented a 5.35% decrease for C100, while the overall efficiency was 36% for ULSD#2 and 33% for C100 at 8 bar IMEP. The nitrogen oxides (NOx) for C100 presented an 11% decrease compared with ULSD#2. Unburned hydrocarbons value (UHC) for ULSD#2 was 2.8 g/kWh at 8 bar IMEP, and improved by 18% for C100. The carbon monoxide (CO) emissions for C100 decreased by 6% when compared to ULSD#2 at 3 bar IMEP but were relatively constant at 8 bar IMEP, presenting a value of 0.82 g/kWh for both fuels. The carbon dioxide (CO2) emissions for C100 increased by 1% compared with ULSD#2, at 3 bar IMEP. The soot value for ULSD#2 was 1.5 g/kWh and presented a 42% decrease for C100 at 8 bar IMEP. The results suggest a very good performance of cotton seed biodiesel, even at very high content of 100%, especially on the emissions side that showed decreasing values for regulated and non-regulated species.Copyright

NVH of RCCI With DI ULSD and PFI With 50% N-Butanol

The noise of diesel engines is dependent upon numerous factors such as: load, speed, fuel injection strategies and fuel type, design of the piston, piston-pin and cylinder and their tolerances, bearings, valves and rocker arm clearances, and designs of the manifolds.In this study, engine sound and vibrations analysis have been conducted using two types of fueling and combustion strategies: classical ULSD combustion and the new RCCI with n-butanol injected in the intake manifold. The analyses add to the understanding of the influence of combustion characteristics’ effect on mechanical noise and vibrations throughout the engine’s operating cycle.The sound and vibration signals were both analyzed in the frequency and angle domain spectrum. Overall NVH spectrum from ULSD combustion was compared to that of RCCI with 50% by mass PFI of n-butanol (the 50% remaining ULSD fuel was directly injected).Frequency analyses were performed using the FFT and CPB methods with Bruel & Kjaer’s Pulse sound and vibrations analysis software. Angle domain analyses were performed, referencing 0 CAD as TDC in combustion.The engine tests were conducted at 1500 rpm and 4 bar IMEP. The COV of IMEP for DI ULSD and RCCI were 2.4 and 2.2, respectively. The correlations between sound, three dimensional vibration levels, and timings were found for: pressure gradients from combustion process, intake and exhaust valve actuations and gas exchange, and piston slap on the cylinder liner.The measurements were extracted and analyzed, and the results determined that virtually all the noise and vibration values pertinent to RCCI were lower than those of ULSD classical combustion.Copyright

The Influence of Peanut Fatty Acid Methyl Ester Blends on Combustion in an Indirect Injection Diesel Engine

The project investigates the effects of peanut FAME on diesel engine combustion and thermal efficiency. The cold flow properties and viscosity were tested and were found that the cloud point (CP) and pour point (PP) of peanut FAME were 17°C and 8°C respectively, and was able to achieve CP of 0°C when blended 20:80 (wt%) with diesel No. 2 (P20). The dynamic viscosity of peanut FAME was 4.2cP (P100) and 2.85cP at 54°C (P20), both fuels are within the ASTM standard for biodiesel. The lower heating value (LHV) of peanut FAME was 37.10MJ/kg (P100) and 41.3MJ/kg (P20) compared to 41.7MJ/kg for diesel No.2 (D100), which supports the usage of peanut FAME in compression ignition engines. At residence time of 5ms from start of injection, P50 has shown positive combustion characteristics with ignition delay of 1.072ms at 2600rpm, 4.78 bmep (100% load). The P50 heat release displayed similar development compared with diesel No. 2, where premixed phase combined with diffusion combustion and reaching a maximum of 20.0J/CAD, which was higher than 17.5J/CAD for D100. Convection flux for both D100 and P50 had values of 1.4MW/m2 . The total heat flux, calculated by Annand model, produced maximum values of 2.1MW/m2 for D100 compared with 2.3MW/m2 for the P50. The mechanical efficiency was only a 4% loss when observing the transition from D100 to P50. These findings support peanut FAME as a viable option when blended and used with diesel engines in order to meet the standards set forth by the RSF-2 and EISA allowing the U.S. to decrease foreign energy dependency and benefiting society through a cleaner burning fuel than is currently in use.Copyright

Aerodynamic Performance and Vibration Analyses of Small Scale Horizontal Axis Wind Turbine with Various Number of Blades

The need to generate power from renewable sources to reduce demand for fossil fuels and the damage of their resulting carbon dioxide emissions is now well understood. Wind is among the most popular and fastest growing sources of alternative energy in the world. It is an inexhaustible, indigenous resource, pollution-free, and available almost any time of the day, especially in coastal regions. As a sustainable energy resource, electrical power generation from the wind is increasingly important in national and international energy policy in response to climate change. Experts predict that, with proper development, wind energy can meet up to 20% of US needs. Horizontal Axis Wind Turbines (HAWTs) are the most popular because of their higher efficiency. The aerodynamic characteristics and vibration of small scale HAWT with various numbers of blade designs have been investigated in this numerical study in order to improve its performance. SolidWorks was used for designing Computer Aided Design (CAD) models, and ANSYS software was used to study the dynamic flow around the turbine. Two, three, and five bladed HAWTs of 87 cm rotor diameter were designed. A HAWT tower of 100 cm long and 6 cm diameter was considered during this study while a shaft of 10.02 cm diameter was chosen. A good choice of airfoils and angle of attack is a key in the designing of a blade of rough surface and maintaining the maximum lift to drag ratio. The S818, S825 and S826 airfoils were used from the root to the tip and 4° critical angle of attack was considered. In this paper, a more appropriate numerical models and an improved method have been adopted in comparable with other models and methods in the literature. The wind flow around the whole wind turbine and static behavior of the HAWT rotor was solved using Moving Reference Frame (MRF) solver. The HAWT rotor results were used to initialize the Sliding Mesh Models (SMM) solver and study the dynamic behavior of HAWT rotor. The pressure and velocity contours on different blades surfaces were analyzed and presented in this work. The pressure and velocity contours around the entire turbine models were also analyzed. The power coefficient was calculated using the Tip Speed Ratio (TSR) and the moment coefficient and the results were compared to the theoretical and other research. The results show that the increase of number of blades from two to three increases the efficiency; however, the power coefficient remains relatively the same or sometimes decreases for five bladed turbine models. HAWT rotors and shaft vibrations were analyzed for two different materials using an applied pressure load imported from ANSYS fluent environment. It has proven that a good choice of material is crucial during the design process.