Valeria Pettarin

Recycling of waste tire rubber: Microwave devulcanization and incorporation in a thermoset resin

This study focused on the possibility of recycling Waste Tire Rubber (WTR) to be used as polymer modifier. Thus, WTR was grinded into powder, at ambient temperature, with a disc mill PQ500 and microwave electromagnetic energy was used to devulcanize this powder with the final aim of producing a new composite by its incorporation in a thermoset resin. The influence of the treatment microwave energy on the devulcanization ratio was investigated. FTIR analysis revealed that rupture of Sulfur-Sulfur (SS) and Carbon-Sulfur (CS) bonds have occurred during the treatment. Swelling analysis showed that the microwave treatment can lead to a very significant degree of devulcanization. The Ground Tire Rubber (GTR) and the Devulcanized Ground Tire Rubber (DGTR) were then separately used to prepare epoxy based composites. It appeared that epoxy composites filled with DGTR have better mechanical properties than those filled with untreated GTR. This result agrees with scanning electron microscopy observations which highlighted a better interface coherence between DGTR and epoxy. A complementary analysis pointed out a linear relationship between the rubber modulus and the number of crosslink per chain.

Mechanical evaluation of propylene polymers under static and dynamic loading conditions

The present investigation is concerned with the evaluation of the impact toughness of commercial-grade Propylene polymers. Conventional impact static stress–strain and static fracture experiments were carried out. Static stress–strain experiments revealed different pattern behaviors among the materials that were reflected in the fracture behavior. Under static conditions, all materials exhibited ductile behavior and crack grew under J-controlled conditions displaying stress whitening through the whole fracture surface with the sole exception of the homopolymer, which displayed a ductile instability after some stable crack growth. Under dynamic conditions the homopolymer exhibited brittle behavior, the block copolymer exhibited some plastic deformation at the crack tip, and the random copolymer samples exhibited a whitening effect due to voiding and craze formation through the whole fracture surface, indicating that stable crack propagation was occurring. Fracture mechanics tests were analyzed by following different methods, depending on the mode of fracture presented by the polymer. The Normalization J-method was used under static conditions. The elastic method, the corrected elastic method, and the essential work of fracture methodology were used to characterize brittle, semibrittle, and ductile behavior, respectively. Fracture mechanics parameters arisen from both static and dynamic conditions are compared.

Mechanical Behavior of Starch–Carbon Nanotubes Composites

This chapter is focused on the mechanical behavior of plasticized starch-based nanocomposites reinforced with carbon nanotubes. It starts with a general introduction about the most important materials that involve those nanocomposites, such as starch and multiwalled carbon nanotubes. Then, a presentation of the most relevant published results on the mechanical properties of starch matrix and starch–carbon nanotubes composites is reported. Factors affecting these properties such as crystallinity, water content and plasticizers are discussed. The mechanical behavior of these composites is discussed in separate sections regarding tensile properties, impact behavior, and viscoelastic behavior as well as the most important influencing factors on these properties. Finally, concluding remarks and future trends on the improvement of the mechanical response of starch–carbon nanotubes composites are presented.

Thermal Degradation Behavior, Permeation Properties and Impact Response of Polyethylene/Organo-montmorillonite/(Ethylene Methacrylic Acid) Ternary Nanocomposites

Through this work we explored the effect of melt compounding a commercial grade of HDPE with organoclays of different precedence using EMAA as compatibilizing agent on the thermal behavior, barrier properties and biaxial impact response of composites. Morphology was examined by XRD and TEM. Crystalline structure was examined by DSC. Thermal behavior was evaluated by TGA. Barrier properties to low-molecular-weight penetrants were experimentally determined employing a gravimetric technique. Mechanical properties under impact conditions were evaluated by instrumented puncture tests. Intercalated nanocomposites were obtained. Throughout the thermal degradation of the nanocomposites in oxidant atmosphere a charring process of the PE, which is normally a non-char-forming polymer, was observed. The addition of OMMT improves barrier properties due to its contribution to tortuosity path and to the reduction of molecular mobility. Impact properties were only slightly reduced by nanocomposite formation. Results demonstrate that EMAA did not improve exfoliation, but it enhanced polymer–organoclay interactions giving rise to better thermal and permeation properties, without detriment of impact response.

Preparation, Physical and Mechanical Characterization of Montmorillonite/polyethylene Nanocomposites

In this paper, we report the preparation of polyethylene composites with organically modified montmorillonite. Three different Na+-montmorillonites were modified in order to obtain organoclays and two grades of high-density polyethylene were used as composite matrices. All composites were prepared by melt blending, and their physical and mechanical properties were thoroughly characterized. The extent of clay platelet exfoliation in the composites was confirmed by X-ray diffraction (XRD). Mechanical properties under static and impact conditions were evaluated to assess the influence of the reinforcement on the properties of polyethylene.

Fracture Behavior of Recyclable All-Polypropylene Composites Composed of α- and β-Modifications

The fracture behavior of all-PP composites was studied under quasi-static loading conditions. Fracture toughness was evaluated by means of different fracture mechanics approaches depending on materials’ behavior. Composites consolidated at low temperature exhibited pop-in features and the failure occurs typically by delamination and tape stretching and fracture. With increasing consolidation quality – i.e., with increasing processing temperature – the delamination became less pronounced, and so the tape stretching occurred, before the specimens break. In composites consolidated at the highest temperature investigated (190°C), the laminate-like structure typical of self-reinforced composites produced according to film-stacking method was lost. Accordingly, composites behave as if they were only α-PP and β-PP matrices: α-rPP exhibited typical brittle fracture of α-PP, while β-rPP exhibited the stable behavior with fully yielded ligament before crack propagation commonly observed for β-PP. In general, stress–strain behavior changed from stable to unstable and fracture toughness strongly decreased as consolidation quality increased. Based on these results and previous findings, it can be concluded that the properties of self-reinforced PP composites can be tailored for a given application through the quality of consolidation.

Assessment of multiaxial mechanical response of rigid polyurethane foams

Multiaxial deformation behavior and failure surface of rigid polyurethane foams were determined using standard experimental facilities. Two commercial foams of different densities were assayed under uniaxial, biaxial, and triaxial stress states. These different stress states were reached in a uniaxial universal testing machine using suitable testing configurations which imply the use of special grips and lateral restricted samples. Actual strains were monitored with a video extensometer. Polyurethane foams exhibited typical isotropic brittle behavior, except under compressive loads where the response turned out to be ductile. A general failure surface in the stress space which accounts for density effects could be successfully generated. All of failure data, determined at the loss of linear elasticity point, collapsed in a single locus defined as the combination of a brittle crushing of closed-cell cellular materials criterion capped by an elastic buckling criterion.