Veijo A. Pohjola

Effect of periodic melting on geochemical and isotopic signals in an ice core from Lomonosovfonna, Svalbard

[1] We examine the quality of atmospherically deposited ion and isotope signals in an ice core taken from a periodically melting ice field, Lomonosovfonna in central Spitsbergen, Svalbard. The aim is to determine the degree to which the signals are altered by periodic melting of the ice. We use three diagnostics: (1) the relation between peak values in the ice chemical and isotopic record and ice facies type, (2) the number of apparent annual cycles in these records compared with independently determined number of years represented in the ice core, and (3) a statistical comparison of the isotopic record in the ice core and the isotope records from coastal stations from the same region. We find that during warm summers, as much as 50% of the annual accumulation may melt and percolate into the firn; in a median year this decreases to similar to25%. As a consequence of percolation, the most mobile acids show up to 50% higher concentrations in bubble-poor ice facies compared with facies that are less affected by melt. Most of the other chemical species are less affected than the strong acids, and the stable water isotopes show little evidence of mobility. Annual or biannual cycles are detected in most parameters, and the water isotope record has a comparable statistical distribution to isotopic records from coastal stations. We conclude that ice cores from sites like Lomonosovfonna contain a useful environmental record, despite melt events and percolation and that most parameters preserve an annual, or in the worst cases, a biannual atmospheric signal.

Spatial and temporal variability of snow accumulation using ground-penetrating radar and ice cores on a Svalbard glacier

A 50 MHz ground-penetrating radar was used to detect horizontal layers in the snowpack along a longitudinal profile on Nordenskjoldbreen, a Svalbard glacier. The profile passed two shallow and one deep ice-core sites. Two internal radar reflection layers were dated using parameters measured in the deep core. Radar travel times were converted to water equivalent, yielding snow-accumulation rates along the profile for three time periods: 1986-99, 1963-99 and 1963-86. The results show 40-60% spatial variability in snow accumulation over short distances along the profile. The average annual accumulation rate for 1986-99 was found to be about 12% higher than for the period 1963-86, which indicates increased accumulation in the late 1980s and 1990s.

A new ice-core record from Lomonosovfonna, Svalbard: viewing the 1920-97 data in relation to present climate and environmental conditions

A new ice core record from Lomonosovfonna, Svalbard: viewing the data between 1920-1997 in relation to present climate and environmental conditions

Methanesulfonic acid in a Svalbard ice core as an indicator of ocean climate

Methanesulfonic acid (MSA) is an atmospheric oxidation product of dimethyl sulfide, produced by marine biota. MSA preserved in a Svalbard glacier between 1920 and 1996 is compared with the sea surface temperature (SST) and sea-ice extent of the surrounding ocean over the same period. On decadal timescales high MSA concentrations are found to be associated with warm SST and reduced sea-ice extent. MSA appears to be influenced by climatic changes related to variations in the import of warm Atlantic Water to the Barents Sea. Atlantic Water plays an important role in the Arctic climate system, therefore MSA concentrations may indirectly reflect larger-scale changes in the region and may be useful as a proxy for past climate.

Deposition History of Brominated Flame Retardant Compounds in an Ice Core from Holtedahlfonna, Svalbard, Norway

Brominated flame retardants (BFRs) have been found in Arctic wildlife, lake sediment, and air. To identify the atmospheric BFR deposition history on Svalbard, Norway, we analyzed 19 BFRs, including hexabromocyclododecane (HBCD), 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE), decabromodiphenyl ethane (DBDPE), pentabromoethylbenzene (PBEB), and 15 polybrominated diphenyl ether congeners (PBDE) in the upper 34 m of an ice core (representing 1953-2005) from Holtedahlfonna, the western-most ice sheet on Svalbard. All of the non-PBDE compounds were detected in nearly continuous profiles in the core. Seven PBDEs were not observed above background (28, 47, 66, 100, 99, 154, 153), while 4 were found in 1 or 2 of 6 segments (17, 85, 138, 183). BDEs-49, 71, 190, 209 had nearly continuous profiles but only BDE-209 in large amounts. The greatest inputs were HBCD and BDE-209, 910, and 320 pg cm(-2) yr(-1) from 1995-2005. DBDPE, BTBPE, and PBEB show nearly continuous input growth in recent core segments, but all were <6 pg cm(-2) yr(-1). Long-range atmospheric processes may have moved these particle-bound BFRs to the site, probably during the Arctic haze season. Average air mass trajectories over 10 years show >75% of atmospheric flow to Holtedahlfonna coming from Eurasia during haze periods (March and April).

Reconstruction of three centuries of annual accumulation rates based on the record of stable isotopes of water from Lomonosovfonna, Svalbard

Abstract We use the upper 81 mof the record of stable isotopes of water from a 122m long ice core from Lomonosovfonna, central Spitsbergen, Svalbard, to construct an ice-core chronology and the annual accumulation rates over the icefield. the isotope cycles are counted in the ice-core record using a model that neglects short-wavelength and low-amplitude cycles. We find approximately the same number of δ18O cycles as years between known reference horizons, and assume these cycles represent annual cycles. Testing the validity of this assumption using cycles in δD shows that both records give similar numbers of cycles. Using the δ18O chronology, and decompressing the accumulation records using the Nye flow model, we calculate the annual accumulation for the ice-core site back to AD 1715. We find that the average accumulation rate from 1715 to 1950 was on average 0.30 mw.e. Accumulation rates increased about 25% during the later part of the 20th century to an average of 0.41 mw.e. for the period 1950–97. the accumulation rates show highly significant 2.1 and 21 year periodicities, which gives credibility to our time-scale.

Thousand years of winter surface air temperature variations in Svalbard and northern Norway reconstructed from ice-core data

Two isotopic ice core records from western Svalbard are calibrated to reconstruct more than 1000 years of past winter surface air temperature variations in Longyearbyen, Svalbard, and Vardø, northern Norway. Analysis of the derived reconstructions suggests that the climate evolution of the last millennium in these study areas comprises three major sub-periods. The cooling stage in Svalbard (ca. 800–1800) is characterized by a progressive winter cooling of approximately 0.9 °C century−1 (0.3 °C century−1 for Vardø) and a lack of distinct signs of abrupt climate transitions. This makes it difficult to associate the onset of the Little Ice Age in Svalbard with any particular time period. During the 1800s, which according to our results was the coldest century in Svalbard, the winter cooling associated with the Little Ice Age was on the order of 4 °C (1.3 °C for Vardø) compared to the 1900s. The rapid warming that commenced at the beginning of the 20th century was accompanied by a parallel decline in sea-ice extent in the study area. However, both the reconstructed winter temperatures as well as indirect indicators of summer temperatures suggest the Medieval period before the 1200s was at least as warm as at the end of the 1990s in Svalbard.

The 800 year long ion record from the Lomonosovfonna (Svalbard) ice core

We present a high-resolution record of water-soluble ion chemistry from a 121 m ice core spanning about 800 years. The core is well dated to 2/3 depth using cycle counting and reference horizons and a simple but close fitting model for the lower 1/3 of the core. This core suffers from modest seasonal melt, and so we present concentration data in decadal running means to minimize percolation effects. Sea-salt ions (Na+, Cl−, Mg2+, and K+) account for more than 70% of all ions. In general, sea-salt ion concentrations are rather variable and have no clear association with climatic variations. Sulfate, with 74% being from non-sea-salt sources, has higher concentrations than seen on Vestfonna ice cap but lower than in Ny-Alesund aerosols, suggesting central Spitsbergen receives more marine (westerly) air masses than Ny-Alesund but more sulfate enriched (easterly) air masses than Nordaustlandet. Clear anthropogenic impacts are found for sulfate, nitrate, and ammonium (and probably excess chloride) after the mid twentieth century, with sulfate showing a significant rise by the end of the nineteenth century. Sulfate and methanesulfonate concentrations correlate well during the twentieth century, and it is clear that most of the preindustrial sulfate is of biogenic origin. Terrestrial component (Ca2+) has the highest concentrations in the coldest part of the Little Ice Age, suggesting more windy conditions, transporting local terrestrial dust to the ice cap. All ion concentrations decrease at the end of the twentieth century, which reflects loss of ions by runoff, with non-sea-salt magnesium being particularly sensitive to melting.

Reconstruction of the historical temperature trend from measurements in a medium-length borehole on the Lomonosovfonna plateau, Svalbard

Abstract A medium-length ice core was drilled at the ice divide on the Lomonosovfonna plateau (1230 m a.s.l.), Svalbard, in May 1997. As part of this project, temperature measurements were performed in the 120m deep borehole. At this site the ice thickness based on radar measurements is 126.5 m and the mean annual accumulation rate is 380 kg m–3. the measurements over the 15–120m depth interval show a nearly isothermal profile with a mean value of –2.8˚C and a standard deviation of 0.2˚C. the measurements reveal a temperature minimum at approximately 70m depth and a temperature gradient of 0.011 ±0.004˚Cm–1 near the bottom. the temperature minimum and relatively low temperature gradient cannot be explained in terms of a steady-state climate. Numerical calculations with a simple one-dimensional diffusion–advection model show that the temperature increased at a maximum rate of 0.02–0.025Ka–1 over the last 100 years, the total temperature increase amounting to 2.0–3.0K. Forcing the model with the observed record at Svalbard airport revealed that in the 19th century the surface temperature was at most 2.5 K lower, and that the instrumental observations started during a period with temperatures comparable to the end of the 19th century. the data are of particular interest for historical simulations since often no other temperature data are available in polar areas.

Separation of melting and environmental signals in an ice core with seasonal melt

We examine the impact of melt water percolation on the soluble ion chemical record from the Lomonosovfonna ice core. Principle component analysis shows that melting produces only simple changes bet ...