Veridiana Martins

Isotopic signatures of Paleoproterozoic granitoids from the southern Sao Francisco Craton and implications for the evolution of the Transamazonian Orogeny

Abstract The southern Sao Francisco Craton, northeastern Brazil, consists of an Archean block surrounded by a Paleoproterozoic belt related to the Transamazonian Orogeny (ca. 2.0 Ga). A calc-alkaline plutonic arc developed within the belt and the granitoid plutons comprise two distinct groups. One group displays Archean T DM ages (3.07–2.62 Ga), e Nd( t ) values between −11.0 and −3.8 and high initial 87 Sr/ 86 Sr values, and it consists mainly of peraluminous granites. T DM ages for the other group are Paleoproterozoic (2.43–2.27 Ga), and e Nd( t ) values range between −2.8 and +1.3; the plutons are metaluminous tonalites (trondhjemites) to granodiorites. The Transamazonian granitoids can be related to contrasting source-regions, from mantle- to crust-derived ones. A number of them are probably derived from mixing of Paleoproterozoic juvenile material and variable proportions of Archean crust material. Magmatism related to deep faulting, during the compressional stages of the Transamazonian Orogeny, is a plausible model for granitoid generation. The contribution of mantle-derived material to the granitoid sources supports the idea that a significant episode of new crust formation occurred during the Transamazonian Orogeny.

Origins and processes of groundwater salinization in the urban coastal aquifers of Recife (Pernambuco, Brazil): A multi-isotope approach

In the coastal multilayer aquifer system of a highly urbanized southern city (Recife, Brazil), where groundwaters are affected by salinization, a multi-isotope approach (Sr, B, O, H) was used to investigate the sources and processes of salinization. The high diversity of the geological bodies, built since the Atlantic opening during the Cretaceous, highly constrains the heterogeneity of the groundwater chemistry, e.g. Sr isotope ratios, and needs to be integrated to explain the salinization processes and groundwater pathways. A paleoseawater intrusion, most probably the 120 kyB.P. Pleistocene marine transgression, and cationic exchange are clearly evidenced in the most salinized parts of the Cabo and Beberibe aquifers. All (87)Sr/(86)Sr values are above the past and present-day seawater signatures, meaning that the Sr isotopic signature is altered due to additional Sr inputs from dilution with different freshwaters, and water-rock interactions. Only the Cabo aquifer presents a well-delimitated area of Na-HCO3 water typical of a freshening process. The two deep aquifers also display a broad range of B concentrations and B isotope ratios with values among the highest known to date (63-68.5‰). This suggests multiple sources and processes affecting B behavior, among which mixing with saline water, B sorption on clays and mixing with wastewater. The highly fractionated B isotopic values were explained by infiltration of relatively salty water with B interacting with clays, pointing out the major role played by (palaeo)-channels for the deep Beberibe aquifer recharge. Based on an increase of salinity at the end of the dry season, a present-day seawater intrusion is identified in the surficial Boa Viagem aquifer. Our conceptual model presents a comprehensive understanding of the major groundwater salinization pathways and processes, and should be of benefit for other southern Atlantic coastal aquifers to better address groundwater management issues.

Sr and Nd Characteristics of Brasiliano/Pan-African Granitoid Plutons of the Araçuaí Orogen, Southeastern Brazil: Tectonic Implications

Nd and Sr isotope data were obtained for three plutonic suites (595–505 Ma) and distinct young granitoid intrusions (503 Ma), from the southern part of the Neoproterozoic Aracuai Orogen. The Sr and Nd isotopes (87Sr/86Sr, eNd) and TDM values from the plutons and distinct basement rocks are used to constrain the magma genesis of the granitoid plutons. These isotopic parameters, with eNd values ranging from −4 to −24 and TDM ages from 1.3 to 2.8 Ga, for the granitoid suites, and −5 to −40 and 3.5 to 1.5 Ga, for the distinct Archean and Proterozoic basement complexes, suggest that the Jequitinhonha Complex metasediments are the main crustal source for most of these plutons, except for the youngest granitoid intrusions, which may have a protolith similar to the Mantiqueira and Guanhaes complexes. Furthermore, the isotope data indicate a minor, but important, participation of Neoproterozoic oceanic lithosphere in the granite genesis, which corroborates with a confined orogenic model and a narrow oceanic consumption (B-subduction) for the Aracuai Orogen.

The Glória quartz-monzodiorite: isotopic and chemical evidence of arc-related magmatism in the central part of the Paleoproterozoic Mineiro belt, Minas Gerais State, Brazil

The Glória quartz-monzodiorite, one of the mafic plutons of the Paleoproterozoic Mineiro belt, is intrusive into banded gneisses, amphibolites, schists and phyllites of the Rio das Mortes greenstone belt, in the southern portion of the São Francisco Craton, State of Minas Gerais, Brazil. The Glória quartz-monzodiorite yields a SHRIMP U-Pb zircon age of 2188 +/- 29 Ma, suggesting a tectonic relationship with the pre-collisional phase of the Mineiro belt. According to the Nd isotopic evidence (epsilonNd(T) = -3.4; T DM = 2.68 Ga) the original magmas was formed by a mixture among Archean crustal material and Paleoproterozoic juvenile magma. The Glória quartz-monzodiorite shows metaluminous and calc-alkaline tendency with intermediate K content, comparable to that of volcanic-arc rocks. The primary mineralogical assemblage was partly modified by metamorphism, dated between 2131-2121 Ma in nearby coeval plutons. Such metamorphism is significantly older than the reported metamorphic episodes of the Mineiro belt in the Quadrilátero Ferrífero region (2059-2041 Ma) in the eastern portion of the study area. This evidence, together with chemical and isotopic data from other mafic and felsic plutons coeval with the Glória quartz-monzodiorite, indicate a tectonic and magmatic migration within the Mineiro belt from west to east.

Multi-layered water resources, management, and uses under the impacts of global changes in a southern coastal metropolis: When will it be already too late? Crossed analysis in Recife, NE Brazil

Coastal water resources are a worldwide key socio-environmental issue considering the increasing concentration of population in these areas. Here, we propose an integrative transdisciplinary approach of water resource, water management and water access in Recife (NE Brazil). The present-day water situation is conceptualized as an imbricated multi-layered system: a multi-layered water resource, managed by a multi-layered governance system and used by a multi-layered social population. This allows identifying processes of quantitative, qualitative, and sanitary conflicts between governance and population strategies regarding water supply, as well as the institutional and individual denials of these conflicts. Based on this model, we anticipate future water-related problematic fates. Concerning the water resource system, the rapid groundwater level decrease due to unsustainable water predatory strategies, and the very low recharge rate have drastically modified the aquifer system functioning, inducing hydraulic connection between shallow groundwater (contaminated and locally salty) and deep ones (mostly fresh, with local inherited salinity), threatening the deep strategic water resource. Concerning the water governance system, the investments to increase the capacity storage of surface water, the water regulation agencies and the public/private partnership should shortly improve the water supply and wastewater issue. Nevertheless, the water situation will remain highly fragile due to the expected water demand increase, the precipitation decrease and the sea-level increase. Concerning the water access system, the population variably perceives these current and further effects and the possible mitigation policies, and develops alternative individual strategies. Authorities, policymakers and water managers will have to implement a well-balanced water governance, taking into account the specificities of the PPP, public and private groundwater users, and with a strong political willingness for a sustainable water management to ensure water supply for all the population. In other words, an anticipatory and integrated vision is necessary to reduce the discrepancies in this complex system.

Analytical procedures for determining Pb and Sr isotopic compositions in water samples by ID-TIMS

Few articles deal with lead and strontium isotopic analysis of water samples. The aim of this study was to define the chemical procedures for Pb and Sr isotopic analyses of groundwater samples from an urban sedimentary aquifer. Thirty lead and fourteen strontium isotopic analyses were performed to test different analytical procedures. Pb and Sr isotopic ratios as well as Sr concentration did not vary using different chemical procedures. However, the Pb concentrations were very dependent on the different procedures. Therefore, the choice of the best analytical procedure was based on the Pb results, which indicated a higher reproducibility from samples that had been filtered and acidified before the evaporation, had their residues totally dissolved, and were purified by ion chromatography using the Biorad® column. Our results showed no changes in Pb ratios with the storage time.