Victor V. Koledov

Magnetocaloric effect in ribbon samples of Heusler alloys Ni–Mn–M (M=In,Sn)

Direct measurements of the magnetocaloric effect in samples of rapidly quenched ribbons of Mn50Ni40In10 and Ni50Mn37Sn13 Heusler alloys with potential applications in magnetic refrigeration technology are carried out. The measurements were made by a precise method based on the measurement of the oscillation amplitude of the temperature in the sample while is subjected to a modulated magnetic field. In the studied compositions both direct and inverse magnetocaloric effects associated with magnetic (paramagnet-ferromagnet-antiferromagnet) and structural (austenite-martensite) phase transitions are found. Additional inverse magnetocaloric effects of small value are observed around the ferromagnetic transitions.

Direct Measurement of Magnetocaloric Effect in Metamagnetic Ni 43 Mn 37.9 In 12.1 Co 7 Heusler Alloy

The magnetocaloric effect in the metamagnetic Ni43Mn37.9In12.1Co7 Heusler alloy is directly studied experimentally under the adiabatic and quasi-isothermal conditions in a magnetic field with induction of up to 14 T.

Magnetocaloric and thermomagnetic properties of Ni2.18Mn0.82Ga Heusler alloy in high magnetic fields up to 140 kOe

Measurements of the adiabatic temperature change (ΔT) and the specific heat transfer (ΔQ) of Ni2.18Mn0.82Ga Heusler alloy were taken in order to quantify the direct giant magnetocaloric effect of the alloy when it is in the vicinity of magneto-structural phase transition (PT) from paramagnetic austenite to ferromagnetic martensite, and their results are presented. A new vacuum calorimeter was used to simultaneously measure ΔT and ΔQ of magnetocaloric materials with a Bitter coil magnet in fields of up to H = 140 kOe. Other thermomagnetic properties of this alloy were investigated using standard differential scanning calorimetry and PPMS equipment. The maximal values of magnetocaloric effect in H = 140 kOe were found to be ΔT = 8.4 K at initial temperature 340 K and ΔQ = 4900 J/kg at 343 K. Using this direct method, we show that the alloy indeed demonstrates the largest value of ΔQ as compared with previously published results for direct measurements of magnetocaloric materials, even though at 140 kOe the ...

Reversible magnetocaloric effect in materials with first order phase transitions in cyclic magnetic fields: Fe48Rh52 and Sm0.6Sr0.4MnO3

The magnetocaloric effect (MCE) in an Fe48Rh52 alloy and Sm0.6Sr0.4MnO3 manganite was studied in cyclic magnetic fields. The adiabatic temperature change in the Fe48Rh52 alloy for a magnetic field change (ΔB) of 8 T and a frequency (f) of 0.13 Hz reaches the highest value of (ΔTad) of −20.2 K at 298 K. The magnitude of the MCE in Sm0.6Sr0.4MnO3 reaches ΔTad = 6.1 K at the same magnetic field change at 143 K. The temperature regions, where a strong MCE is exhibited in an alternating magnetic field, are bounded in both compounds. In the case of the Fe48Rh52 alloy, the temperature range for this phenomenon is bounded above by the ferromagnetic to antiferromagnetic transition temperature in the zero field condition during cooling. In the case of the Sm0.6Sr0.4MnO3 manganite, the temperature range for the MCE is bounded below by the ferromagnetic-paramagnetic transition temperature in zero field during heating. The presence of these phase boundaries is a consequence of the existence of areas of irreversible ma...

Thermodynamic and Relaxation Processes near Curie Point in Gadolinium

An experimental method is suggested for the determination of the rate of magnetic phase transitions. The method is based on the measurement of the change of magnetic susceptibility of a ferromagnetic sample in the vicinity of the phase transition in response to an abrupt change of the sample temperature. This paper describes the measurement of the change of the magnetic susceptibility of a thin gadolinium plates, cooled by water-flow at a temperature below the Curie point (TC=292 K). It was found that the relaxation time of the magnetic susceptibility of gadolinium in the temperature range from 289.9 to 291.3 K can be approximated using the Landau-Khalatnikov equation with a kinetic coefficient value γ = 3.9×10-8 cm3/(erg×s). The linear approximation does not fit well in the range from 291.3 to 293.2 K. The fundamental restriction of specific power of the magnetocaloric refrigerator (made by gadolinium plates) was estimated.

Magnetocaloric Effect of Gadolinium at Adiabatic and Quasi-Isothermal Conditions in High Magnetic Fields

High cooling power of magnetocaloric refrigeration can be achieved only at large amounts of heat, which can be transferred in one cycle from cold end to hot end at quasi-isothermal conditions. The simple experimental method for direct measurement of the transferred heat from material with magnetocaloric effect (MCE) to massive nonmagnetic block at quasi-isothermal conditions was proposed. The vacuum calorimeter was designed for the simultaneous measurements of MCE both at adiabatic conditions (∆T) and quasi-isothermal conditions (∆Q) in the magnetic fields of Bitter coil magnet. This calorimeter was tested on samples of pure polycrystalline Gd with direct MCE. The maximal obtained values were ∆T = 17.7 K and ∆Q = 5900 J/kg at initial temperature 20 °C in magnetic field 140 kOe.

Effect of thermal cycling on the martensitic transformation in Ni-Mn-In alloys

The influence of thermal cycling on the characteristics of the martensitic transformation in Ni45.4Mn40.9In13.7 alloy was investigated. It was shown that after 1000 repeated thermal cycles trough temperature interval of the martensitic transformation, application of magnetic field of 1.1 T resulted in higher transformation temperatures shift of 10 K/T compared to 7 K/T before cycling. On the other hand, the measurements display a steady increase of electric resistivity with the number of cycles that along with decrease of the transformation latent heat indicate the phase hardening. The means to prevent functional degradation of magnetocaloric materials due to phase hardening are suggested.

Thermoelastic martensitic transition and magnetic properties of the Ni2.14Mn0.81Fe0.05Ga alloy in different structural states

Investigations of the temperature dependence of magnetization revealed that, in the ferromagnetic shape memory Ni2.14Mn0.81Fe0.05Ga alloy, after formation of the nanocrystalline state by a severe plastic deformation method, neither ferromagnetic ordering nor a structural transition takes place. Subsequent annealing leads to the restoration of magnetic ordering. Also, on increasing the temperature of annealing restoration of the structural transition for the first time was observed. It was shown that the temperature of the thermoelastic martensitic transition depends on crystallite sizes. An intermartensitic transition in coarse grained Ni2.14Mn0.81Fe0.05Ga alloy was discovered.

Simulation of the control process applied to the micromechanical device with the shape memory effect

It has recently been proved that, in alloys, e.g., based on the Ti–Ni system, a shape memory effect (SME) is preserved down to the nanoscale sizes of an active alloy layer and demonstrated ultrasmall-sized and fully functional microand nanomechanical devices: actuators and nanotweezers that are fabricated via standard microelectronic technologies relying on composite materials with the SME. In the nearest future, such achievements will enable the creation of the next-generation microand nanomechanical devices whose sizes are quite comparable with those inherent to, e.g., carbon nanotubes, graphene sheets, viruses, etc. Mathematical simulation methods are used to study how the shape-memory micromechanical devices can be activated by means of resistive pulse heating. A decrease in the overall sizes of heating elements (from 1 mm to 10 μm) is demonstrated to be accompanied by the fact that the speed of operation increases sharply from 102 to 105 s–1 and, simultaneously, the energy consumption diminishes from 10–3 to 10–8 J per operation. The preliminary results of experiments whereby the control of the composite nanotweezer exhibiting the SME is perfected with the help of the automatic pulsed heating technology, as well as the prospects for creating high-speed and high-performance microrobotic systems incorporating newly developed components, are discussed.

Fine-grained structure and properties of a Ni2MnIn alloy after a settling plastic deformation

The structure and properties of a polycrystalline Ni–Mn–In Heusler alloy have been studied after a plastic deformation by upsetting. An analysis of points of a martensitic and magnetic phase transformations shows that the martensite transformation takes place at temperatures lower than the Curie point. At high temperatures in the range 930–1110 K the alloy undergoes the phase transformation of ordered phase L21 to disordered phase B2, and the melting temperature of the alloy is 1245 K. The flow curves of the alloy cylindrical samples at temperatures 773, 873, and 973 K have been built. An analysis of the alloy microstructure after upsetting at a temperature of 773 K leads to the conclusion that many macrocracks are initiated in the sample. The treatment at 873 and 973 K causes a fragmentation of the grains with grain sizes from several to several dozen micrometers. However, the upsetting at 873 K leads to insignificant scatter in the grain sizes, and the microstructure is more homogeneous and worked out.