Viktor A. Podolskiy

Plasmonic nanorod metamaterials for biosensing.

Label-free plasmonic biosensors rely either on surface plasmon polaritons or on localized surface plasmons on continuous or nanostructured noble-metal surfaces to detect molecular-binding events. Despite undisputed advantages, including spectral tunability, strong enhancement of the local electric field and much better adaptability to modern nanobiotechnology architectures, localized plasmons demonstrate orders of magnitude lower sensitivity compared with their guided counterparts. Here, we demonstrate an improvement in biosensing technology using a plasmonic metamaterial that is capable of supporting a guided mode in a porous nanorod layer. Benefiting from a substantial overlap between the probing field and the active biological substance incorporated between the nanorods and a strong plasmon-mediated energy confinement inside the layer, this metamaterial provides an enhanced sensitivity to refractive-index variations of the medium between the rods (more than 30,000 nm per refractive-index unit). We demonstrate the feasibility of our approach using a standard streptavidin-biotin affinity model and record considerable improvement in the detection limit of small analytes compared with conventional label-free plasmonic devices.

Designed ultrafast optical nonlinearity in a plasmonic nanorod metamaterial enhanced by nonlocality

All-optical signal processing enables modulation and transmission speeds not achievable using electronics alone. However, its practical applications are limited by the inherently weak nonlinear effects that govern photon-photon interactions in conventional materials, particularly at high switching rates. Here, we show that the recently discovered nonlocal optical behaviour of plasmonic nanorod metamaterials enables an enhanced, ultrafast, nonlinear optical response. We observe a large (80%) change of transmission through a subwavelength thick slab of metamaterial subjected to a low control light fluence of 7 mJ cm(-2), with switching frequencies in the terahertz range. We show that both the response time and the nonlinearity can be engineered by appropriate design of the metamaterial nanostructure. The use of nonlocality to enhance the nonlinear optical response of metamaterials, demonstrated here in plasmonic nanorod composites, could lead to ultrafast, low-power all-optical information processing in subwavelength-scale devices.

Strongly anisotropic waveguide as a nonmagnetic left-handed system

We develop a new approach to build a material with negative refraction index. In contrast to conventional designs which make use of a resonant behavior to achieve a non-zero magnetic response, our material is intrinsically non-magnetic and relies on an anisotropic dielectric constant to provide a left-handed response in waveguide geometry. We demonstrate that the proposed material can support surface (polariton) waves, and show the connection between polaritons and the enhancement of evanescent fields, also referred to as super-lensing.

Stimulated emission of surface plasmon polaritons

We have observed stimulated emission of surface plasmon polaritons (SPPs) propagating at the interface between a silver film and a film of optically pumped polymethyl methacrylate (PMMA) doped with rhodamine 6G (R6G) dye.

Near-sighted superlens

We consider the problem of subwavelength imaging via a slab of a left-handed medium (LHM) in the presence of material losses. We derive the analytical expression for the resolution limit of a LHM-based lens and demonstrate that the area of its subwavelength performance is usually limited to the near-field zone.

Plasmon modes and negative refraction in metal nanowire composites.

Optical properties of metal nanowires and nanowire composite materials are studied. An incident electromagnetic wave can effectively couple to the propagating surface plasmon polariton (SPP) modes in metal nanowires resulting in very large local fields. The excited SPP modes depend on the structure of nanowires and their orientation with respect to incident radiation. A nanowire percolation composite is shown to have a broadband spectrum of localized plasmon modes. We also show that a composite of nanowires arranged into parallel pairs can act as a left-handed material with the effective magnetic permeability and dielectric permittivity both negative in the visible and near-infrared spectral ranges.

PLASMON MODES IN METAL NANOWIRES AND LEFT-HANDED MATERIALS

The electromagnetic eld distribution for thin metal nanowires is found, by using the discrete dipole approximation. The plasmon polariton modes in wires are numerically simulated. These modes are found to be dependent on the incident light wavelength and direction of propagation. The existence of localized plasmon modes and strong local eld enhancement in percolation nanowire composites is demonstrated. Novel left-handed materials in the near-infrared and visible are proposed based on nanowire composites.

Nanowire metamaterials with extreme optical anisotropy

The authors study perspectives of nanowire metamaterials for negative-refraction waveguides, high-performance polarizers, and polarization-sensitive biosensors. They demonstrate that the behavior of these composites is strongly influenced by the concentration, distribution, and geometry of the nanowires, derive an analytical description of electromagnetism in anisotropic nanowire-based metamaterials, and explore the limitations of their approach via three-dimensional numerical simulations. Finally, they illustrate the developed approach on the examples of nanowire-based high-energy-density waveguides and nonmagnetic negative-index imaging systems with far-field resolution of one-sixth of vacuum wavelength.

Nonlocal effects in effective-medium response of nanolayered metamaterials

We demonstrate that the majority pf plasmonic nanolayered composites, despite being subwanelength, are not described by effective medium theory and develop an adequate description of electromagnetism in these systems.

Hyperbolic metamaterials: new physics behind a classical problem

Hyperbolic materials enable numerous surprising applications that include far-field subwavelength imaging, nanolithography, and emission engineering. The wavevector of a plane wave in these media follows the surface of a hyperboloid in contrast to an ellipsoid for conventional anisotropic dielectric. The consequences of hyperbolic dispersion were first studied in the 50s pertaining to the problems of electromagnetic wave propagation in the Earths ionosphere and in the stratified artificial materials of transmission lines. Recent years have brought explosive growth in optics and photonics of hyperbolic media based on metamaterials across the optical spectrum. Here we summarize earlier theories in the Clemmows prescription for transformation of the electromagnetic field in hyperbolic media and provide a review of recent developments in this active research area.