Vincenzo Tucci

Development of epoxy mixtures for application in aeronautics and aerospace

This work describes a successful attempt toward the development of composite materials based on nanofilled epoxy resins for the realization of structural aeronautic components providing efficient lightning strike protection. The epoxy matrix is prepared by mixing a tetrafunctional epoxy precursor with a reactive diluent which allows the moisture content to be reduced and facilitates the nanofiller dispersion step. The reactive diluent also proves to be beneficial for improving the curing degree of nanofilled epoxy mixtures. It increases the mobility of reactive groups resulting in a higher cure degree than the epoxy precursor alone. This effect is particularly advantageous for nanofilled resins where higher temperature treatments are needed, compared to the unfilled resin, to reach the same cure degree. As nanofiller, different carbon nanostructured fiber-shaped fillers are embedded in the epoxy matrix with the aim of improving the electrical properties of the resin. The results highlight a strong influence of the nanofiller nature on the electrical properties especially in terms of electrical percolation threshold (EPT) and electrical conductivity beyond the EPT. Among the analyzed nanofillers, the highest electrical conductivity is obtained by using multiwalled carbon nanotubes (MWCNTs) and heat-treated carbon nanofibers (CNFs). The achieved results are analyzed by considering the nanofiller morphological parameters and characteristics with respect to the impact on their dispersion effectiveness.

The role of carbon nanofiber defects on the electrical and mechanical properties of CNF-based resins

Heat treatment of carbon nanofibers has proven to be an effective method in removing defects from carbon nanofibers, causing a strong increase in their structural perfection and thermal stability. It affects the bonding states of carbon atoms in the nanofiber structure and causes a significant transformation in the hybridization state of the bonded carbon atoms.Nanofilled resins made of heat-treated CNF show significant increases in their electrical conductivity even at low concentrations. This confirms that enhancement in the perfection of the fiber structure with consequent change in the morphological features plays a prominent role in affecting the electrical properties. Indeed heat-treated CNFs display a stiff structure and a smooth surface which tends to lower the thickness of the unavoidable insulating epoxy layer formed around the CNF which, in turn, plays a fundamental role in the electrical transport properties along the conducting clusters. This might be very beneficial in terms of electrical conductivity but might have negligible effect on the mechanical properties.

Multiconductor transmission line analysis of steep-front surges in machine windings

The numerical evaluation of the electrical stress in the line-end coil of the stator winding of a medium voltage motor fed by a pulsed width modulated (PWM) inverter seems to be indispensable for a rational design of the machine. In order to fulfil such a task, the system, composed of a feeder cable and a stator winding, is modelled and simulated by using multi-conductor transmission line theory. The model can take into account the main phenomena occurring along the lines, i.e. the propagation and the reflection, together with the time dispersion introduced by the losses, eventually dependent on the frequency. The multi-conductor transmission line is solved in the time domain by adopting a technique based on the perturbation theory of the spectrum of symmetric matrices, which sensibly decreases the computational effort with respect to the analysis in the frequency domain. Furthermore, an accurate calculation of the characteristic matrices, which contain the cross-sectional information of the line, is performed by means of a FEM package, so taking into account the effective field distribution in the region of interest. The influence of the accurate evaluation of the capacitance and inductance matrices is considered by comparing the numerical results of the proposed model with those obtained by a simple equivalent circuit, frequently adopted in the literature. In order to validate the proposed model, the simulated results are compared with experimental data.

Optimization of graphene-based materials outperforming host epoxy matrices

The degree of graphite exfoliation and edge-carboxylated layers can be controlled and balanced to design lightweight materials characterized by both low electrical percolation thresholds (EPT) and improved mechanical properties. So far, this challenging task has been undoubtedly very hard to achieve. The results presented in this paper highlight the effect of exfoliation degree and the role of edge-carboxylated graphite layers to give self-assembled structures embedded in the polymeric matrix. Graphene layers inside the matrix may serve as building blocks of complex systems that could outperform the host matrix. Improvements in electrical percolation and mechanical performance have been obtained by a synergic effect due to finely balancing the degree of exfoliation and the chemistry of graphene edges which favors the interfacial interaction between polymer and carbon layers. In particular, for epoxy-based resins including two partially exfoliated graphite samples, differing essentially in the content of carboxylated groups, the percolation threshold reduces from 3 wt% down to 0.3 wt%, as the carboxylated group content increases up to 10 wt%. Edge-carboxylated nanosheets also increase the nanofiller/epoxy matrix interaction, determining a relevant reinforcement in the elastic modulus.

Analysis of the voltage distribution in a motor stator winding subjected to steep-fronted surge voltages by means of a multiconductor lossy transmission line model

In this paper, the effect of steep-fronted voltage waveshapes infringing on a pulse-width-modulated (PWM) inverter fed induction motor is studied. The system, composed of a feeder cable and a stator winding, is modeled and simulated by using multiconductor transmission line theory in order to predict the voltage distribution among the coils of the stator winding. A recently developed time-domain equivalent circuit is used; it allows one to correctly describe the dielectric losses and the skin-effect in the conductors. The relationship among the voltage distribution inside the electrical insulation and parameters like the rise time of the applied voltage, the cable length, and the distributed losses is deeply discussed. Good agreement has been found among experimental and numerical results.

Effective formulation and processing of nanofilled carbon fiber reinforced composites

This work describes a successful approach toward the development of a carbon fiber-reinforced composite based on an optimized nanofilled resin for industrial applications. The epoxy matrix is prepared by mixing a tetrafunctional epoxy precursor with a reactive diluent which allows reduction of the viscosity of the epoxy precursor and facilitation of the dispersion of 0.5% wt multiwall carbon nanotubes. The proper choice of the viscosity value and the infusion technique allow improvement of the electrical properties of the panels. The obtained in-plane electrical conductivity is about 20 kS m � 1 , whereas a value of 3.9 S m � 1 is achieved for the out of plane value. Such results confirm that the fibers govern the conduction mechanisms in the direction parallel to the fibers, whereas the percolating path created by the effective distribution of carbon nanotubes achieved by resin formulation and adopted processing approach lead to a significant enhancement of the overall electrical performance of the composites.

Carbon nanotube induced structural and physical property transitions of syndiotactic polypropylene

In this paper we have studied the effect of increasing carbon multi-walled nanotube (CNT) concentration in composites of syndiotactic polypropylene (sPP) having the same crystalline form but different morphologies. The attention was focused on the form I of sPP with different degrees of perfection (in terms of percentages of chains in helical conformation, crystal dimensions and crystallinity) obtained using two different quenching temperatures from the melt, i.e. 25 and 100 °C. We observed a decreasing effect of the crystallization temperature on increasing the nanotube content up to the samples with 10% of CNT, that show a very similar structural organization independent of the undercooling. Only the amorphous phase turns out more relaxed in the samples crystallized at the highest temperature. Either the thermal or the mechanical properties are improved on increasing the CNT content in both series of samples. The electrical conductivity increases in a similar manner in both series of samples and between 1 and 3 wt% it shows a sizable step of about eight orders of magnitude, a phenomenon that can be regarded as the onset of a percolating structure for which charge transport may take place.

A Galerkin model to study the field distribution in electrical components employing nonlinear stress grading materials

An effective model is presented for the evaluation of the electric field dynamics inside electrical components, using nonlinear stress grading materials. The model, implemented in a numerical procedure, permits the solution of the Laplace equation and the diffusion equation by adopting the Galerkin method. Two-dimensional domains, even of very complex shapes and the finite thickness of the grading materials are properly taken into account, allowing an accurate evaluation of the electric field distribution and a sound understanding of the influence of the different types of nonlinearities on the stress grading efficiency. The proposed technique has been applied to study the field distributions inside a cable termination equipped with a stress control tube and in a suspension cap-and-pin glass insulator covered with an anti-corona layer. Numerical results for sinusoidal power frequency and standard impulse voltages elucidate the different role of resistive and capacitive contributions in determining the overall potential maps.

Simulation and experimental characterization of polymer/carbon nanotubes composites for strain sensor applications

In this paper, a numerical model is presented in order to analyze the electrical characteristics of polymer composites filled by carbon nanotubes (CNTs) subject to tensile stress and investigate the possible usage of such materials as innovative sensors for small values of strain. The simulated mechano-electrical response of the nanocomposite is obtained through a multi-step approach which, through different modeling stages, provides a simple and effective tool for material analysis and design. In particular, at first, the morphological structures of the composites are numerically simulated by adopting a previously presented model based on a Monte Carlo procedure in which uniform distributions of the CNTs, approximated as of solid cylinders and ensuring some physical constraints, are dispersed inside a cubic volume representing the polymer matrix. Second, a geometrical analysis allows to obtain the percolation paths detected in the simulated structures. Suitable electrical networks composed by resistors and capacitors associated to the complex charge transport and polarization mechanisms occurring in the percolation paths are then identified. Finally, the variations of these circuit parameters, which are differently affected by the mechanical stresses applied to the composites, are considered to analyze the electromechanical characteristics of the composites and hence their performances as stress sensors. The proposed approach is used to investigate the impact on the electro-mechanical response of some physical properties of the base materials, such as the type of carbon nanotube, the height of energy barrier of polymer resin, as well as characteristics of the composite, i.e., the volume fraction of the filler. The tunneling effect between neighboring nanotubes is found to play a dominant role in determining the composite sensitivity to mechanical stresses. The simulation results are also compared with the experimental data obtained by performing stress tests on samples of a multi walled CNT filled composite based on poly (e-caprolactone), a polymer which is of interest for its biocompatibility. Model simulations and measured data show generally satisfactory agreement, confirming the effectiveness of the proposed approach to account for the impact of the interactions between CNTs and the insulating resin on the electromechanical response of the composite.

Field distribution in cable terminations from a quasi-static approximation of the Maxwell equations

A new model for the evaluation of the electric field in a cable termination realized through a nonlinear stress control tube (SCT), is presented in this paper. It is based on the electro-quasistatic approximation of the Maxwell equations: the Laplace equation describes the field in the nonconducting regions whereas a diffusion-like equation gives the field dynamics in the stress control tube. A numerical model is devised by solving the Laplace equation by finite difference and diffusion equations by the Galerkin method. It is shown that even the well-known RC transmission line model can be derived from this general approach. The underlying approximations leading to the circuital model are discussed in detail. The proposed model, in contrast with the circuital one, allows us to take into account properly the nonlinear SCT characteristics and the actual boundary conditions: in this way both spatial and temporal effects of the nonlinearity are-considered. The numerical results obtained by considering the general field approach and by using the transmission line model are compared.