Vitaly Svetovoy

Optical properties of gold films and the Casimir force

Precise optical properties of metals are very important for accurate prediction of the Casimir force acting between two metallic plates. Therefore we measured ellipsometrically the optical responses of Au films in a wide range of wavelengths from 0.14 to 33 mu m. The films at various thicknesses were deposited at different conditions on silicon or mica substrates. Considerable variation of the frequency dependent dielectric function from sample to sample was found. Detailed analysis of the dielectric functions was performed to check the Kramers-Kronig consistency, and extract the Drude parameters of the films. It was found that the plasma frequency varies in the range from 6.8 to 8.4 eV. It is suggested that this variation is related with the film density. X-ray reflectivity measurements support qualitatively this conclusion. The Casimir force is evaluated for the dielectric functions corresponding to our samples, and for that typically used in the precise prediction of the force. The force for our films was found to be 5%-14% smaller at a distance of 100 nm between the plates. Noise in the optical data is responsible for the force variation within 1%. It is concluded that prediction of the Casimir force between metals with a precision better than 10% must be based on the material optical response measured from visible to mid-infrared range.

Plasmon enhanced near-field radiative heat transfer for graphene covered dielectrics

It is shown that a graphene layer on top of a dielectric slab can dramatically influence the ability of this dielectric for radiative heat exchange turning a poor heat emitter/absorber into a good one and vice versa. The effect of graphene is related to thermally excited plasmons. The frequency of these resonances lies in the terahertz region and can be tuned by varying the Fermi level through doping or gating. It makes possible the fast modulation of the heat flux by electrical means, which opens up new possibilities for very fast manipulations with the heat flux. The heat transfer between two dielectrics covered with graphene can be larger than that between best known materials and becomes especially efficient below the room temperature.

Casimir-Lifshitz force out of thermal equilibrium

We study the Casimir-Lifshitz interaction out of thermal equilibrium, when the interacting objects are at different temperatures. The analysis is focused on the surface-surface, surface-rarefied body, and surface-atom configurations. A systematic investigation of the contributions to the force coming from the propagating and evanescent components of the electromagnetic radiation is performed. The large distance behaviors of such interactions is discussed, and both analytical and numerical results are compared with the equilibrium ones. A detailed analysis of the crossing between the surface-surface and the surface-rarefied body, and finally the surface-atom force is shown, and a complete derivation and discussion of the recently predicted nonadditivity effects and asymptotic behaviors is presented.

Switching Casimir forces with phase-change materials

We demonstrate here a controllable variation in the Casimir force. Changes in the force of up to 20% at separations of similar to 100 nm between Au and Ag-In-Sb-Te (AIST) surfaces were achieved on crystallization of an amorphous sample of AIST. This material is well known for its structural transformation, which produces a significant change in the optical properties and is exploited in optical data storage systems. The finding paves the way to the control of forces in nanosystems, such as micro- or nanoswitches, by stimulating the phase-change transition via localized heat sources.

Graphene-on-Silicon Near-Field Thermophotovoltaic Cell

A graphene layer on top of a dielectric can dramatically influence ability of the material to radiative heat transfer. This property of graphene is used to improve the performance and reduce costs of near-field thermophotovoltaic cells. Instead of low bandgap semiconductors it is proposed to use graphene-on-silicon Schottky photovoltaic cells. One layer of graphene absorbs around 90% of incoming radiation and increases the heat transfer. This is due to excitation of plasmons in graphene, which are automatically tuned in resonance with the emitted light in the mid infrared range. The absorbed radiation excites electron-hole pairs in graphene, which are separated by the surface field induced by the Schottky barrier. For a quasi-monochromatic source the generated power is one order of magnitude larger and efficiency is on the same level as for semiconductor photovoltaic cells.

Distance upon contact: Determination from roughness profile

The point at which two random rough surfaces make contact takes place at the contact of the highest asperities. The distance upon contact d0 in the limit of zero load has crucial importance for determination of dispersive forces. Using gold films as an example we demonstrate that for two parallel plates d0 is a function of the nominal size of the contact area L and give a simple expression for d0(L) via the surface roughness characteristics. In the case of a sphere of fixed radius R and a plate the scale dependence manifests itself as an additional uncertainty δd(L) in the separation, where the scale L is related with the separation d via the effective area of interaction L2∼πRd. This uncertainty depends on the roughness of interacting bodies and disappears in the limit L→∞.

Application of the Lifshitz Theory to Poor Conductors

The Lifshitz formula for dispersive forces is generalized to the materials, which cannot be described with the local dielectric response. The principal nonlocality of poor conductors is related to the finite screening length of the penetrating field and collisional relaxation; at low temperatures the role of collisions plays the Landau damping. Spatial dispersion makes the theory self-consistent. Our predictions are compared with the recent experiment. It is demonstrated that at low temperatures Casimir-Lifshitz entropy disappears as T in the case of degenerate plasma and as T2 for the nondegenerate one.

Sample dependence of the Casimir force

We have analysed available optical data for Au in the mid-infrared range which is important for a precise prediction of the Casimir force. Significant variation of the data demonstrates genuine sample dependence of the dielectric function. We demonstrate that the Casimir force is largely determined by the material properties in the low frequency domain and argue that therefore the precise values of the Drude parameters are crucial for an accurate evaluation of the force. These parameters can be estimated by two different methods, either by fitting real and imaginary parts of the dielectric function at low frequencies, or via a Kramers–Kronig analysis based on the imaginary part of the dielectric function in the extended frequency range. Both methods lead to very similar results. We show that the variation of the Casimir force calculated with the use of different optical data can be as large as 5% and at any rate cannot be ignored. To have a reliable prediction of the force with a precision of 1%, one has to measure the optical properties of metallic films used for the force measurement.

Correction to the casimir force due to the anomalous skin effect

The surface impedance approach is discussed in connection with the precise calculation of the Casimir force between metallic plates. It allows us to take into account the nonlocal connection between the current density and electric field inside of metals. In general, a material has to be described by two impedances Zs(omega,q) and Zp(omega,q) corresponding to two different polarization states. In contrast with the approximate Leontovich impedance they depend not only on frequency omega but also on the wave vector along the plate q. In this paper only the nonlocal effects happening at frequencies omega<omegap (plasma frequency) are analyzed. We refer to all of them as the anomalous skin effect. The impedances are calculated for the propagating and evanescent fields in the Boltzmann approximation. It is found that Zp significantly deviates from the local impedance as a result of the Thomas-Fermi screening. The nonlocal correction to the Casimir force is calculated at zero temperature. This correction is small but observable at small separations between bodies. The same theory can be used to find more significant nonlocal contribution at omega~omegap due to the plasmon excitation

Influence of surface roughness on dispersion forces

Surface roughness occurs in a wide variety of processes where it is both difficult to avoid and control. When two bodies are separated by a small distance the roughness starts to play an important role in the interaction between the bodies, their adhesion, and friction. Control of this short-distance interaction is crucial for micro and nanoelectromechanical devices, microfluidics, and for micro and nanotechnology. An important short-distance interaction is the dispersion forces, which are omnipresent due to their quantum origin. These forces between flat bodies can be described by the Lifshitz theory that takes into account the actual optical properties of interacting materials. However, this theory cannot describe rough bodies. The problem is complicated by the nonadditivity of the dispersion forces. Evaluation of the roughness effect becomes extremely difficult when roughness is comparable with the distance between bodies. In this paper we review the current state of the problem. Introduction for non-experts to physical origin of the dispersion forces is given in the paper. Critical experiments demonstrating the nonadditivity of the forces and strong influence of roughness on the interaction between bodies are reviewed. We also describe existing theoretical approaches to the problem. Recent advances in understanding the role of high asperities on the forces at distances close to contact are emphasized. Finally, some opinions about currently unsolved problems are also presented.