Vladimir G. Chigrinov

Surface-Induced Parallel Alignment of Liquid Crystals by Linearly Polymerized Photopolymers

Photopolymerization of polymer-coated solid substrates with linearly polarized light is shown to induce an anisotropic, uniaxial orientation of polymer molecules. The linearly photopolymerized (LPP) layers exhibit UV dichroism and optical anisotropy. The resulting anisotropic dispersive surface interaction forces are shown to align adjacent liquid crystals parallel. A qualitative microscopic model is presented. The new LPP-alignment technique allows to generate homogeneous LC-director pattern with different azimuthal director angles on the same substrate requiring no mechanical treatment. The use of LPP substrates in liquid crystal displays (LCDs) is shown to enable to combine different electrooptical effects-such as twisted nematic (TN) and parallel configurations-in the same hybrid LCD. Besides from high-contrast LPP-aligned TN-LCDs, LPP-aligned supertwisted nematic (STN)-LCDs exhibiting steep transmission-voltage characteristics are presented.

Deformed helix ferroelectric liquid crystal display: A new electrooptic mode in ferroelectric chiral smectic C liquid crystals

Abstract A new electrooptic mode of operation of ferroelectric chiral smectic C liquid crystal displays (LCDs) is proposed and demonstrated. The effect, which is called the deformed helical ferroelectric (DHF) effect, is based on the deformation of the helical structure by weak electric fields. In the unbiased device the smectic layers are arranged in the bookshelf geometry with the helix axis parallel to the electrodes [1]. Systems with a very small pitch (<1 μm) and a large tilt angle are especially well suited for this mode. The key characteristics of DHF-LCDs are: (a) low driving fields (1 Vp-pμm−1 for maximum contrast); (b) grey scale which is approximately linear with the applied electric field; (c) easy alignment even for thick cells using standard wall-aligning methods; and (d) response times at room temperature of 300 μs.

Tunable liquid crystal q-plates with arbitrary topological charge

Using a photoalignment technique with a sulphonic azo-dye as the surfactant aligning material, we fabricated electrically tunable liquid crystal q-plates with topological charge 0.5, 1.5 and 3 for generating optical vortex beams with definite orbital angular momentum (OAM) 1,3 and 6 per photon (in units of ¯h), respectively. We carried out several tests on our q-plates, including OAM tomography, finding excellent performances. These devices can have useful applications in general and quantum optics.

Synthesis and properties of azo dye aligning layers for liquid crystal cells

The synthesis and properties of azo dyes that can be used for photoaligning liquid crystals (LCs) have been investigated. The structures and the synthetic procedure for the azo dyes are presented. The photoaligning of azo dyes takes place purely due to the reorientation of the molecular absorption oscillators perpendicular to the UV light polarization. The qualitative model for the phenomenon in terms of the rotational diffusion of the azo dye molecules in the field of the polarized light is discussed. The order parameters S = -0.4 (80% of the maximum absolute value S m = -0.5) were measured from the polarized absorption spectra at the wavelength 372 nm. A temperature stable pretilt angle of 5.3° was obtained by a two-step exposure of the azo dye film using normally incident polarized light followed by oblique non-polarized light. The azimuthal anchoring energy of the photoaligned substrate was Aϕ , 10−4 J m−2, which is the same as the anchoring of the rubbed polyimide (PI) layer. The voltage holding ratio value of a photoaligned LC cell was found to be even higher than for a rubbed PI layer, which enables the applications of azo dyes as aligning layers in active matrix liquid crystal displays. The thermal stability of the photoaligned azo dye layers is sufficiently high, but UV stability has to be improved, e.g. by polymerization. A new LCD aligning technology based on polymerized azo dye layers is envisaged.

Variable liquid crystal pretilt angles generated by photoalignment of a mixed polyimide alignment layer

A method to generate any liquid crystal pretilt angle is proposed and demonstrated. This method is based on deep ultraviolet photoalignment of a layer consisting of nanostructured domains of horizontal and vertical alignment polyimides. Competition between the two types of domains produces the controlled pretilt angle. The obtained anchoring energy is reasonably large.

Liquid-crystal micropolarimeter array for full Stokes polarization imaging in visible spectrum

In this paper, we describe the design, modeling, fabrication, and optical characterization of the first micropolarimeter array enabling full Stokes polarization imaging in visible spectrum. The proposed micropolarimeter is fabricated by patterning a liquid-crystal (LC) layer on top of a visible-regime metal-wire-grid polarizer (MWGP) using ultraviolet sensitive sulfonic-dye-1 as the LC photoalignment material. This arrangement enables the formation of either micrometer-scale LC polarization rotators, neutral density filters or quarter wavelength retarders. These elements are in turn exploited to acquire all components of the Stokes vector, which describes all possible polarization states of light. Reported major principal transmittance of 75% and extinction ratio of 1100 demonstrate that the MWGPs superior optical characteristics are retained. The proposed liquidcrystal micropolarimeter array can be integrated on top of a complementary metal-oxide-semiconductor (CMOS) image sensor for real-time full Stokes polarization imaging.

Thin Photo-Patterned Micropolarizer Array for CMOS Image Sensors

We fabricated and characterized a thin photo-patterned micropolarizer array for complementary metal-oxide-semiconductor (CMOS) image sensors. The proposed micropolarizer fabrication technology completely removes the need for complex selective etching. Instead, it uses the well-controlled process of ultraviolet photolithography to define micropolarizer orientation patterns on a spin-coated azo-dye-1 film. The patterned polymer film micropolarizer (10 mum x 10 mum) exhibits submicron thickness (0.3 mum) and has an extinction ratio of ~ 100. Reported experimental results validate the concept of a thin, high spatial resolution, low-cost photo-patterned micropolarizer array for CMOS image sensors.

Optical polarization grating induced liquid crystal micro-structure using azo-dye command layer

We create planar-periodic alignment in nematic liquid crystal (LC) cell by using a command layer of azo-dye molecules directly deposited on the cell substrates and exposed with two interfering laser beams of opposite circular polarizations. Permanent high efficiency polarization gratings are thus created. The diffraction efficiency of those gratings is controlled by a uniform electric field applied across the cell. The electro-optical properties of such polarization gratings are studied. Obtained gratings can be used for electrically controlled discrimination and detection of polarized components of light.

Fast switchable grating based on orthogonal photo alignments of ferroelectric liquid crystals

We demonstrate a fast switchable grating based on ferroelectric liquid crystals and orthogonal planar alignment by means of photo alignments. Both 1D and 2D gratings have been constructed. The proposed diffracting element provides fast response time of around 20 μs, contrast of 7000:1 and high diffraction efficiency, at the electric field of 6 V/μm. The saturated electro-optical (EO) states up to very high frequency (≈5 kHz) are the real advantage of the proposed switchable grating, which opens several opportunities to improve the quality of existing devices and to find new applications.

Evaluating liquid crystal properties for use in terahertz devices

Despite the wide application of liquid crystals (LCs) in the visible frequency range, their properties in the terahertz range have not yet been extensively investigated. In this paper we have investigated the terahertz properties of LCs E7, BL037, RDP-94990 and RDP-97304 using terahertz time-domain-spectroscopy. We find that RDP-94990 has the largest birefringence and smallest absorption in the terahertz range compared to E7 and BL037. We highlight the importance of investigating all parameters, not just the birefringence, when designing fast, efficient and transmissive terahertz LC devices.