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Wakgari Hirpo

Michigan State University

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Journal of The Chemical Society, Chemical Communications | 1992

Synthesis and structure of the first indium–copper cluster, [Cu6In3(SEt)16]– and its possible relevance to CuInS2

Wakgari Hirpo; Sandeep Dhingra; Mercouri G. Kanatzidis

The cluster (Ph4P)[Cu6In3(SEt)16] has been prepared by the reaction of [Cu(CH3CN)4]PF6 with (Ph4P)[In(SEt)4] and its crystal structure shows an adamantoid framework.

Polyhedron | 1994

Synthesis and characterization of indium thiolates: structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]

Wakgari Hirpo; Anthony C. Sutorik; Sandeep Dhingra; Mercouri G. Kanatzidis

Abstract Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.

Chemistry of Materials | 1996

Redox Intercalative Polymerization of Aniline in V2O5 Xerogel. The Postintercalative Intralamellar Polymer Growth in Polyaniline/Metal Oxide Nanocomposites Is Facilitated by Molecular Oxygen

C.-G. Wu; Donald C. DeGroot; Henry O. Marcy; Jon L. Schindler; Carl R. Kannewurf; Y.-J. Liu; Wakgari Hirpo; Mercouri G. Kanatzidis

Journal of the American Chemical Society | 1993

Synthesis of mixed copper-indium chalcogenolates. Single-source precursors for the photovoltaic materials CuInQ2 (Q=S, Se)

Wakgari Hirpo; Sandeep Dhingra; Anthony C. Sutorik; Mercouri G. Kanatzidis

Journal of the American Chemical Society | 1995

Reaction of Aniline with FeOCl. Formation and Ordering of Conducting Polyaniline in a Crystalline Layered Host

C.-G. Wu; Donald C. DeGroot; Henry O. Marcy; Jon L. Schindler; Carl R. Kannewurf; Thomas Bakas; V. Papaefthymiou; Wakgari Hirpo; J. P. Yesinowski; Yu Liu; Mercouri G. Kanatzidis

Chemistry of Materials | 1996

Synthesis, Structure, and Reactions of Poly(ethylene oxide)/V2O5 Intercalative Nanocomposites

Y.-J. Liu; Jon L. Schindler; Donald C. DeGroot; Carl R. Kannewurf; Wakgari Hirpo; Mercouri G. Kanatzidis

Chemistry of Materials | 1996

Toward Pillared Layered Metal Sulfides. Intercalation of the Chalcogenide Clusters Co6Q8(PR3)6 (Q = S, Se, and Te and R = Alkyl) into MoS2

Rabin Bissessur; Joy Heising; Wakgari Hirpo; Mercouri G. Kanatzidis

Journal of the American Chemical Society | 1988

A folded metallacyclopentatriene and a bicapped-tetrahedral M2C4 cluster obtained from coupling of alkyne ligands. Structures of CpMoCl(C4Ph4) and (CpMoCl)2(.mu.,.eta.4-C5Ar4) (Ar = p-tolyl)

Wakgari Hirpo; M. David Curtis

Organometallics | 1990

Insertion and alkyne coupling reactions on early-transition-metal centers. Structures of CpTa(ME)(. eta. sup 2 -ArCCAr)(. eta. sup 2 -MeCN sup t Bu), CpMeTaC(Ph)C(Ph)C(Me)N sup t Bu, and CpClMo(CPh) sub 4 (Ar = p-tolyl)

M. David Curtis; Julio. Real; Wakgari Hirpo; William M. Butler

Organometallics | 1994

Alkyne coupling with isonitriles and carbon monoxide on tantalum and niobium centers. Molecular structure of Cp*MeTa(CPhCPhCMeO)

Wakgari Hirpo; M. David Curtis

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Mercouri G. Kanatzidis

Northwestern University

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M. David Curtis

University of Michigan

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Carl R. Kannewurf

Northwestern University

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Donald C. DeGroot

Northwestern University

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Jon L. Schindler

Northwestern University

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Sandeep Dhingra

Michigan State University

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Anthony C. Sutorik

Michigan State University

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C.-G. Wu

Michigan State University

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Henry O. Marcy

Northwestern University

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William M. Butler

University of Michigan

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