Wang XinMin

Citric and Oxalic Acids Effect on Pb and Zn Uptake by Maize and Winter Wheat

Abstract A pot experiment was conducted to investigate the influence of citric and oxalic acids effect on Pb and Zn uptake by corn and winter wheat. The experiment was employed with citric acid (CA) applied at 3 rates (0, 1.5 and 3.0 mmol kg−1 soil), oxalic acid (OA) at 3 rates (0, 1.5 and 3.0mmol kg−1 soil) and citric acid combined with oxalic acid (1.5 mmol citric acid combined with 1.5 mmol oxalic acid kg−1). Two types of soil were chose in the experiment. One was collected from the agricultural soil near a battery-recycling factory in Anhui province, China (site A) and the other was collected from a Pb-Zn mine residues in Hunan province, China (site B). The results showed that soil pH varied with the different treatment of citric and oxalic acids. However, there were no differences in all the treatments. 3.0mmol CA kg−1 soil addition significantly increased the concentrations of the CaCl2-extractable Pb and Zn and other treatments have no significantly increased. The highest shoot concentrations of Pb and Zn in both species occurred in application of 3.0 mmol CA/kg−1 soil and shoot concentrations of Pb and Zn in both species were significantly higher than the controls in this treatment. Shoot yields declined with application of citric and oxalic acids, indicating that the plants were sensitive to the toxicity of the metals or the amendments. The highest Pb uptake values by maize and wheat werell2.3 and 77.2 μg pot1 in soil of site A, and occurred with the control and 3.0 mmol CA/kg−1 soil respectively.