Warren W. Wood

Large-scale natural gradient tracer test in sand and gravel, Cape Cod, Massachusetts: 1. Experimental design and observed tracer movement

A large-scale natural gradient tracer experiment was conducted on Cape Cod, Massachusetts, to examine the transport and dispersion of solutes in a sand and gravel aquifer. The nonreactive tracer, bromide, and the reactive tracers, lithium and molybdate, were injected as a pulse in July 1985 and monitored in three dimensions as they moved as far as 280 m down-gradient through an array of multilevel samplers. The bromide cloud moved horizontally at a rate of 0.42 m per day. It also moved downward about 4 m because of density-induced sinking early in the test and accretion of areal recharge from precipitation. After 200 m of transport, the bromide cloud had spread more than 80 m in the direction of flow, but was only 14 m wide and 4-6 m thick. The lithium and molybdate clouds followed the same path as the bromide cloud, but their rates of movement were retarded about 50% relative to bromide movement because of sorption onto the sediments.

Hydrogeologic processes in saline systems: Playas, sabkhas, and saline lakes

Abstract Pans, playas, sabkhas, salinas, saline lakes, and salt flats are hydrologically similar, varying only in their boundary conditions. Thus, in evaluating geochemical processes in these systems, a generic water and solute mass-balance approach can be utilized. A conceptual model of a coastal sabkha near the Arabian Gulf is used as an example to illustrate the various water and solute fluxes. Analysis of this model suggests that upward flux of ground water from underlying formations could be a major source of solutes in the sabkha, but contribute only a small volume of the water. Local rainfall is the main source of water in the modeled sabkha system with a surprisingly large recharge-to-rainfall ratio of more than 50%. The contribution of seawater to the solute budget depends on the ratio of the width of the supratidal zone to the total width and is generally confined to a narrow zone near the shoreline of a typical coastal sabkha. Because of a short residence time of water, steady-state flow is expected within a short time ( 50,000 years). The solute composition of the brine in a closed saline system depends largely on the original composition of the input water. The high total ion content in the brine limits the efficiency of water–rock interaction and absorption. Because most natural systems are hydrologically open, the chemistry of the brines and the associated evaporite deposits may be significantly different than that predicted for hydrologically closed systems. Seasonal changes in temperature of the unsaturated zone cause precipitation of minerals in saline systems undergoing evaporation. Thus, during the hot dry season months, minerals exhibit retrograde solubility so that gypsum, anhydrite and calcite precipitate. Evaporation near the surface is also a major process that causes mineral precipitation in the upper portion of the unsaturated zone (e.g. halite and carnallite), provided that the relative humidity of the atmosphere is less than the activity of water. The slope of the fresh/brine-water interface in saline lake systems is shallower than in fresh/seawater interface because of the greater density difference between the fresh/brine-water bodies. The interface between sabkha brines and seawater slopes seaward, unlike normal marine–fresh water systems that slope landward. Moreover, the brine/seawater interface does not achieve steady state because it is pushed toward the sea by the sabkhas brine.

Playa-lake basins on the Southern High Plains of Texas and New Mexico: Part I. Hydrologic, geomorphic, and geologic evidence for their development

Playa-lake basins of the Southern High Plains, Texas and New Mexico, may originate wherever water periodically can collect in a surficial depression. They expand, however, by hydrologic and geomorphic processes including (1) dissolution of lithologic carbonates by infiltrating water; (2) transport downward of fine-grained clastic and organic material by the infiltrating ground water, leading to continuing processes of oxidation and carbonate dissolution in the subsurface; and (3) eolian removal of clastic material from the floor of playa lakes, which at some sites appears to have deepened playa depressions. Evidence for largely hydrologic processes of playa-basin development on the Southern High Plains includes (1) a geographic occurrence restricted to relatively flat areas of the High Plains surface that have poorly developed fluvial drainage and which are underlain by generally unsaturated clastic and calcrete beds; (2) a tendency to occur where water collects and infiltrates, as along ephemeral streams and lineations suggestive of fracture systems; and (3) hydrologic, geochemical, petrographic, and bore-hole data, which suggest that recharge to the High Plains aquifer is principally from playa lakes, that various geochemical changes including carbonate dissolution and enhancement of secondary porosity occur as water moves downward through the unsaturated zone beneath playa lakes, and that calcrete beds often are missing or significantly dissolved beneath playa floors.

Intragranular Diffusion: An Important Mechanism Influencing Solute Transport in Clastic Aquifers?

Quantification of intragranular porosity in sand-size material from an aquifer on Cape Cod, Massachusetts, by scanning electron microscopy, mercury injection, and epifluorescence techniques shows that there are more reaction sites and that porosity is greater than indicated by standard short-term laboratory tests and measurement techniques. Results from laboratory and field tracer tests show solute nonequilibrium for a reacting ion consistent with a model of diffusion into, and exchange within, grain interiors. These data indicate that a diffusion expression needs to be included in transport codes, particularly for simulation of the transport of radioactive and toxic wastes.

Chloride mass-balance method for estimating ground water recharge in arid areas: examples from western Saudi Arabia

Abstract The chloride mass-balance method, which integrates time and aerial distribution of ground water recharge, was applied to small alluvial aquifers in the wadi systems of the Asir and Hijaz mountains in western Saudi Arabia. This application is an extension of the method shown to be suitable for estimating recharge in regional aquifers in semi-arid areas. Because the method integrates recharge in time and space it appears to be, with certain assumptions, particularly well suited for and areas with large temporal and spatial variation in recharge. In general, recharge was found to be between 3 to 4% of precipitation — a range consistent with recharge rates found in other and and semi-arid areas of the earth.

Eolian transport, saline lake basins, and groundwater solutes

Eolian processes associated with saline lakes are shown to be important in determining solute concentration in groundwater in arid and semiarid areas. Steady state mass balance analyses of chloride in the groundwater at Double Lakes, a saline lake basin in the southern High Plains of Texas, United States, suggest that approximately 4.5 × 105 kg of chloride is removed from the relatively small (4.7 km2) basin floor each year by deflation. This mass enters the groundwater down the wind gradient from the lake, degrading the water quality. The estimates of mass transport were independently determined by evaluation of solutes in the unsaturated zone and by solute mass balance calculations of groundwater flux. Transport of salts from the lake was confirmed over a short term (2 years) by strategically placed dust collectors. Results consistent with those at Double Lake were obtained from dune surfaces collected upwind and downwind from a sabkha near the city of Abu Dhabi in the United Arab Emirates. The eolian transport process provides an explanation of the degraded groundwater quality associated with the 30–40 saline lake basins on the southern half of the southern High Plains of Texas and New Mexico and in many other arid and semiarid areas.

Source of solutes to the coastal sabkha of Abu Dhabi

An ascending-brine model is proposed to address the observed isotope geochemistry, solute composition, and solute and water fluxes in the coastal sabkha of the Emirate of Abu Dhabi. Mass-balance measurements document that >95% of the solutes are derived from ascending continental brines; minor amounts are derived from rainfall and from groundwater entering from up- gradient areas. Nearly 100% of the annual water loss is from evaporation and not lateral discharge. Direct rainfall on the sabkha and subsequent recharge to the underlying aquifer account for ∼90% of the annual water input to the system; the remaining 10% comes from both lateral and ascending groundwater flow. Thus, the water and solutes in this system are from different sources. Solute concentrations of conservative (i.e., nonreactive) elements in the coastal, sabkha-covered aquifer are consistent with the fluid pore volumes of ascending brine calculated from hydrologic properties. Calcium to sulfate ratios and sulfur isotopes are consistent with this source of solute from the underlying Tertiary formations. Recharging rainwater dissolves halite and other soluble minerals on the surface, causing the solution to become more dense and sink to the bottom of the aquifer where it vertically mixes with less dense ascending brines. Solutes are returned to the surface by capillary forces and recycled or lost from the system by eolian or fluvial processes. Thus, the system becomes vertically mixed, consistent with the presence of tritium throughout the aquifer; but there is essentially no horizontal mixing of seawater with groundwater. The observed seawater solutes in the supratidal zone come from interstitial seawater trapped by the rapid progradation of the sediments into the Arabian Gulf and are not refluxed or laterally mixed. The ascending- brine model contrasts significantly with both the seawater-flooding and evaporative- pumping models previously proposed as a source of solutes to the coastal sabkha of the Emirate of Abu Dhabi. Use of these earlier models leads to incorrect conclusions and raises serious questions about their applicability in the evaluation of sabkhat in the geologic record.

AQUEOUS GEOCHEMISTRY AND DIAGENESIS IN THE EASTERN SNAKE RIVER PLAIN AQUIFER SYSTEM, IDAHO.

Water budget and isotopic analyses of water in the eastern Snake River Plain aquifer system confirm that most, if not all, of the water is local meteoric in origin. Solute mass-balance arguments suggest that ∼5 × 10 9 moles of calcite and 2.6 × 10 9 moles of silica are precipitated annually in the aquifer. Isotopic evaluations of calcite and petrographic observation of silica support the low-temperature origin of these deposits. Approximately 2.8 × 10 9 moles of chloride, 4.5 × 10 9 moles of sodium, 1.4 × 10 9 moles of sulfate, and 2 × 10 9 moles of magnesium are removed annually from the aquifer framework by solution. Proposed weathering reactions are shown to be consistent with mass balance, carbon isotopes, observed mineralogy, and chemical thermodynamics. Large quantities of sodium, chloride, and sulfate are being removed from the system relative to their abundances in the rock. Sedimentary interbeds, which are estimated to compose 2 )/yr or less than half the average of the North American continent. This contrasts with the rate for the eastern Snake River basin, 34 (Mg/km 2 )/yr, which is almost identical to the average for the North American continent. Identification and quantification of reactions controlling solute concentrations in ground water in the eastern plain indicate that the aquifer is not an “inert bathtub” that simply stores and transmits water and solutes but is undergoing active diagenesis and is both a source and sink for solutes.

Playa-lake basins on the Southern High Plains of Texas and New Mexico: Part II. A hydrologic model and mass-balance arguments for their development

Hydrologic, geologic, geomorphic, and mass-balance data suggest that most of the ∼30,000 playa lake basins on the Southern High Plains have developed by a combination of dissolution of caliche and piping of surface material into the unsaturated zone rather than by eolian processes as has generally been stated. A conceptual model suggests that particulate organic material, much of which is sorbed on smectite clays, is carried downward from the surface into the unsaturated zone by recharging water. The organic material is oxidized to CO 2 , which dissolves in the water, forms carbonic acid, and dissolves lithologic carbonates. Because organic material is transported and oxidized deep in the unsaturated zone, CO 2 concentrations are much higher at depth than in the soil zone, and recharging water remains thermodynamically subsaturated with respect to carbonates and thus able to dissolve them throughout the unsaturated zone. Dissolution promotes lithologic instability, leading to piping and eluviation of material within the unsaturated zone. Playa basins expand laterally as recharge is concentrated at the edge of the playa floor because of lowered permeability in the center that results from accumulation of clays and other fine sediment. Mass-balance calculations of gas, liquid, and solid fluxes beneath a playa basin suggest that sufficient mass is transported to account for the volume of the depression. Particulate flux is estimated by relating it to the CO 2 flux out of the unsaturated zone. Solute flux is estimated from the difference between input values from the playa lake water and that observed in ground water. Gas flux is measured directly from gas samples at specific depths below the: surface.

Origin of caves and other solution openings in the unsaturated (vadose) zone of carbonate rocks: A model for CO2 generation

The enigma that caves and other solution openings form in carbonate rocks at great depths below land surface rather than forming from the surface downward can be explained by the generation of CO 2 within the aquifer system. In the proposed model, CO 2 is generated by the oxidation of particulate and/or dissolved organic carbon that is transported from the land surface deep into the unsaturated zone by recharging ground water. The organic material is oxidized to CO 2 by aerobic bacteria utilizing oxygen that diffuses in from the atmosphere. Because gas transport in the unsaturated zone is controlled largely by diffusion, steady-state generation of even minute amounts of CO 2 deep in the unsaturated zone results in the creation of large concentrations of CO 2 at depth as it establishes a concentration gradient to the surface or other sink. Ground water descending into these areas of high CO 2 concentration becomes thermodynamically subsaturated with respect to carbonate minerals and is able to dissolve them, thus forming the observed solution opening at depth.