Wei Bing Ma

Resistivity-Temperature Properties of La(TixMn1-x)O3 Ceramics

Samples of La(TixMn1-x)O3 (0.1 ≤ x ≤ 0.7) were sintered at different temperatures. The experimental results showed that the resistivity-temperature curves of the samples match NTC characteristic. The crystal structure was analyzed using X-ray diffraction and the microstructure was observed by scanning electron microscope.

(Ba,Sr,Pb) TiO3-BaPbO3 System Compound PTC Ceramic

This paper made a thorough investigation on (Ba,Sr,Pb) TiO3-BaPbO3 system compound PTC ceramic. The optimum compound method is determined by lots of experiments in different compound schemes. Also the formula and process are optimized and improved. The best properties acquired are: ρroom-temperature=18.8Ω·cm, ρmax/ρmin >103. In the end, the phenomena in the experiment are illustrated with electron trap model.

Study of Graphite/Bakelite/BaTiO3-Based PTC Ceramics Composite

The influence of grahtite and bakelite content of Graphite/Bakelite/BaTiO3-based PTC ceramic composite on their properties was studied. It was found that the composites room- temperature resistivity was decreased and the PTC intensity was assured. This method offered a new way to solving the problem of high room-temperature resistivity of the BaTiO3-based PTC ceramic.

Effects of Glass-Additives on the Properties of Ni/Ceramic PTC Composites

The effects of glass additives on the sintering and properties of Ni/(Ba0.92Sr0.08)TiO3 composites were investigated. Due to the addition of glass additives, Ni/ceramic composites with low room-temperature resistivity and obvious PTC effect were obtained at a low sintering temperature. It was shown that glass-additives could form liquid phase that aided the solution and diffusion of solid atoms, acting as sintering aids to accelerate the sintering and lower the sintering temperature. The room-temperature resistivity decreased first and increased later with the increasing content of glassadditives, which was explained by two functions of glass-additives, decreasing interface contact resistance as sintering aids and adding volume resistance as insulators. Moreover, a suitable amount of glass-additives could enhance the PTC effect unexpectedly, which was attributed to the decrease of the contact resistance existing at the ceramic/ceramic interface.

Ni/Graphite/BaTiO3 PTCR Composites

Nickel/graphite/BaTiO3 PTC composites with lower room-temperature resistivity and higher resistance jump were fabricated by adding graphite and nickel powders into BaTiO3 PTC ceramics. Characteristics and conductive mechanism of the composites were discussed based on the experimental results.

Preparation of Ni/BaTiO3 Composites and PTC Effect

Ni/BaTiO3 composite was prepared by decomposition of NiC2O4·2H2O/BaTiO3 precursor, which was prepared by precipitating of nickel in the form of oxalate into the BaTiO3 slurry. The composite must be sintered in reducing atmosphere. Otherwise NTC effect would be introduced. The prepared composite almost had no PTC effect. But PTC effect of the Ni/BaTiO3 composite can be effectively renewed by heat-treatment in air. Under a proper composition and method, the composite shows low room-temperature resistivity (ρRT=6.0 Ω·cm) and obvious PTC effect (ρmax/ρmin=102).

Effect of BaCO3 and Pb3O4 on Properties of BaTiO3-Based PTCR Ceramics

High-performance PTCR ceramics with low resistivity (8Ω.cm) at room temperature and around four orders magnitude of the PTCR jump were obtained by adding BaCO3 and Pb3O4(B-P) in BaTiO3. The influence of adding B-P on the sintering behavior, the microstructure and the electrical properties of BaTiO3-based PTCR was investigated. The phase constituent in the sintered ceramics was analyzed by XRD and it was shown that the metallic layered Ba3Pb2O7 phase was synthesized during the sintering. Analysis suggested that making the weak reduction atmosphere at the grain boundary may decrease the grain-boundary resistivity.