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Metallurgical transactions. A, Physical metallurgy and materials science | 1991

Thermochemical nature of minor elements in copper smelting mattes

David C. Lynch; S. Akagi; William G. Davenport

AbstractEquilibrium distribution measurements of As, Sb, and Bi between molten copper and white metal were conducted at 1473 K using a static system. The results of this investigation have been used to evaluate the activity of those elements in white metal, and the results are compared to other data in the literature. An empirical model is presented and used to correlate the activity of As and Sb in matte as a function of the number of vacant electronegative sites in the matte, VS, and a parameter, ψ, used to represent the strength of the bond between Fe and the minor element in comparison to that which occurs with Cu. The activity coefficients of As and Sb in matte were found to be represented by the following equations:


Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals | 2011

Electrowinning of Nickel from Purified Nickel Solutions

Frank K. Crundwell; Michael S. Moats; Timothy G. Robinson; William G. Davenport


Extractive Metallurgy of Copper (Fifth Edition) | 2011

Chapter 21 – Byproduct and Waste Streams

Mark E. Schlesinger; Matthew J. King; Kathryn C. Sole; William G. Davenport

\log \gamma _{As} /\gamma _{As}^{SD = O} = - 0.256 + 93.0VS


Extractive Metallurgy of Copper | 2002

Solvent Extraction Transfer of Cu from Leach Solution to Electrolyte

William G. Davenport; M. King; M. Schlesinger; A.K. Biswas


Extractive Metallurgy of Copper | 2002

Copper Loss in Slag

William G. Davenport; M. King; M. Schlesinger; A.K. Biswas


Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals | 2011

Converting – Final Oxidation of Iron From Molten Matte

Frank K. Crundwell; Michael S. Moats; Timothy G. Robinson; William G. Davenport


Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals | 2011

Smelting of Laterite Ores to Ferronickel

Frank K. Crundwell; Michael S. Moats; Timothy G. Robinson; William G. Davenport

\log \gamma _{Sb} /\gamma _{Sb}^{SD = O} = - 0.192 + 73.0VS


Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals | 2011

Upgrading of Laterite Ores

Frank K. Crundwell; Michael S. Moats; Timothy G. Robinson; William G. Davenport


Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals | 2011

Refining of the Platinum-Group Metals

Frank K. Crundwell; Michael S. Moats; Timothy G. Robinson; William G. Davenport

where VS =Xs + XMe- Xcu/2 −, ψXFe, Me = As or Sb and


Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals | 2011

Recycling of Nickel, Cobalt and Platinum-Group Metals

Frank K. Crundwell; Michael S. Moats; Timothy G. Robinson; William G. Davenport

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Michael S. Moats

Missouri University of Science and Technology

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M. Schlesinger

Missouri University of Science and Technology

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A.K. Biswas

University of Queensland

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