William G. Morris

Battery-free radio frequency identification (RFID) sensors for food quality and safety

Market demands for new sensors for food quality and safety stimulate the development of new sensing technologies that can provide an unobtrusive sensor form, battery-free operation, and minimal sensor cost. Intelligent labeling of food products to indicate and report their freshness and other conditions is one important possible application of such new sensors. This study applied passive (battery-free) radio frequency identification (RFID) sensors for the highly sensitive and selective detection of food freshness and bacterial growth. In these sensors, the electric field generated in the RFID sensor antenna extends from the plane of the RFID sensor and is affected by the ambient environment, providing the opportunity for sensing. This environment may be in the form of a food sample within the electric field of the sensing region or a sensing film deposited onto the sensor antenna. Examples of applications include monitoring of milk freshness, fish freshness, and bacterial growth in a solution. Unlike other food freshness monitoring approaches that require a thin film battery for operation of an RFID sensor and fabrication of custom-made sensors, the passive RFID sensing approach developed here combines the advantages of both battery-free and cost-effective sensor design and offers response selectivity that is impossible to achieve with other individual sensors.

Development of radio-frequency identification sensors based on organic electronic sensing materials for selective detection of toxic vapors

Selective vapor sensors are demonstrated that involve the combination of (1) organic electronic sensing materials with diverse response mechanisms to different vapors and (2) passive 13.56 MHz radio-frequency identification (RFID) sensors with multivariable signal transduction. Intrinsically conducting polymers such as poly(3,4-ethylenedioxythiophene) and polyaniline (PANI) were applied onto resonant antennas of RFID sensors. These sensing materials are attractive to facilitate the critical evaluation of our sensing concept because they exhibit only partial vapor selectivity and have well understood diverse vapor response mechanisms. The impedance spectra Z(f) of the RFID antennas were inductively acquired followed by spectral processing of their real Zre(f) and imaginary Zim(f) parts using principal components analysis. The typical measured 1σ noise levels in frequency and impedance magnitude measurements were 60 Hz and 0.025 Ω, respectively. These low noise levels and the high sensitivity of the resona...

Position-independent chemical quantitation with passive 13.56-MHz radio frequency identification (RFID) sensors.

Recently, we have demonstrated an attractive approach to adapt conventional radio frequency identification (RFID) tags for multianalyte chemical sensing. These RFID sensors could be very attractive as ubiquitous distributed remote sensor networks. However, critical to the wide acceptance of the demonstrated RFID sensors is the analyte-quantitation ability of these sensors in presence of possible repositioning errors between the RFID sensor and its pickup coil. In this study, we evaluate the capability for such position-independent analyte quantification using multivariate analysis tools. By measuring simultaneously several parameters of the complex impedance from such an RFID sensor and applying multivariate statistical analysis methods, we were able to compensate for the repositioning effects such as baseline signal offset and magnitude of sensor response to an analyte.

Mechanism of surface smoothing of diamond by a hydrogen plasma

Abstract As-polished diamond (100)- and (111)-oriented single crystals and natural diamond powders of 0.12–25 μm diameter were treated in atomic hydrogen generated by a microwave plasma or by a hot tungsten filament. Post-treatment atomic force microscopy (AFM) showed smoothing and step bunching on (100) and (111) surfaces. Natural diamond powders, which were quite irregular and rough prior to treatment, remained the same size but became markedly smoother and well-faceted, as observed by scanning electron microscopy (SEM). The degree of faceting was sensitive to plasma power level or filament temperature and substrate temperature but was independent of H 2 flow rate. The size and degree of faceting appeared to be the same after plasma treatment for isolated and closely packed particles. We argue that surface diffusion is the dominant smoothing mechanism, but clear evidence of etching was observed at substrate temperatures of 975°C and above.

Domain studies on amorphous ribbons with transverse or oblique magnetic anisotropy

SEM techniques are used to study domain structures in amorphous ribbons with transverse or oblique magnetic anisotropy. Domain widths are much finer than in ribbons with longitudinal anisotropy, and vary with ribbon dimensions and anisotropy constant. The effects of applied magnetic fields and applied stresses are also discussed.

Magnetic domains in amorphous metal ribbons (invited)

The results of various static and dynamic studies of domains in amorphous metals by SEM and Bitter techniques are reviewed. Observations include domain widths and orientations, wall mobility and pinning, domain‐wall energy measurements, and the effects of various distributions of residual or applied stresses on domain patterns. Domain structures resulting from longitudinal, transverse, and perpendicular anisotropies are contrasted.

Selective quantitation of vapors and their mixtures using individual passive multivariable RFID sensors

We demonstrate passive (battery-free) radio frequency identification (RFID) devices for selective and sensitive chemical vapor sensing in the presence of ambient interfering gases. We developed two approaches for RFID sensing (1) when a sensing material is applied onto the resonant antenna to alter its impedance response and (2) when a complementary sensor is attached across an antenna and an integrated circuit (IC) memory chip to alter the impedance response of the sensor. In both approaches, these RFID sensors combine several measured parameters of impedance response with the multivariate analysis of these parameters. Thus, these individual sensors provide a unique capability of multiparameter sensing and rejection of environmental interferences. Sensitivity of developed RFID sensors provides detection of vapors at part-per-billion and part-per-million concentrations. Selectivity of developed RFID sensors facilitates selective quantitation of different individual vapors and their mixtures with a single sensor. Our passive RFID sensors were interrogated by the sensor reader at distances ranging from 0 to 33 cm and demonstrated their reliable operation even at the largest tested distance. In our sensing implementations, not the sensor but the sensor reader provides a 16-bit resolution and high signal-to-noise of the acquired signal. Rejection of interferences with a single sensor and the independence from costly proprietary RFID memory chips that have an analog input promise to impact numerous sensing applications.

Wireless resonant sensor array for high-throughput screening of materials

Screening of materials arrays for their viscoelastic, gas-sorbing, and dielectric properties is important in a wide variety of combinatorial materials science applications. Impedance analysis is an attractive approach to analyze these materials properties and to generate the required new knowledge. Often, these measurements are performed by applying a material onto a suitable sensor and monitoring the changes in materials properties. However, when such a sensor is positioned into a test cell, a direct-wired connection to the analyzer becomes complicated. These complications further increase dramatically when a whole array of sensors is being tested in the test cell. To eliminate these complications, we developed a wireless proximity resonant sensor array system. In the developed system, tested materials are applied onto an array of thickness-shear mode (TSM) resonators operating at 10 MHz and arranged for performance testing in a test chamber. Each TSM resonator is coupled to a receiver coil (antenna). An array of these coils is read with a single scanning transmitter coil or an array of transmitter coils. This high-throughput screening approach of sensing materials permits their evaluation in complex environments where additional wiring is not desirable or adds a prohibitively complex design. We demonstrated the applicability of the wireless sensor materials screening approach for the rapid evaluation of the effects of conditioning of polymeric sensing films at different temperatures on the vapor-response patterns to several vapors of industrial, health, law enforcement, and security interest (ethanol, acetonitrile, and water vapors).

RFID sensors as the common sensing platform for single-use biopharmaceutical manufacturing

The lack of reliable single-use sensors prevents the biopharmaceutical industry from fully embracing single-use biomanufacturing processes. Sensors based on the same detection platform for all critical parameters in single-use bioprocess components would be highly desirable to significantly simplify their installation, calibration and operation. We review here our approach for passive radio-frequency identification (RFID)-based sensing that does not rely on costly proprietary RFID memory chips with an analog input but rather implements ubiquitous passive 13.56 MHz RFID tags as inductively coupled sensors with at least 16 bit resolution provided by a sensor reader. The developed RFID sensors combine several measured parameters from the resonant sensor antenna with multivariate data analysis and deliver unique capability of multiparameter sensing and rejection of environmental interferences with a single sensor. This general sensing approach provides an elegant solution for both analytical measurement and identification and documentation of the measured location.

Theory and practice of ubiquitous quantitative chemical analysis using conventional computer optical disk drives.

We demonstrate a new attractive approach for ubiquitous quantitative chemical or biological sensing when analog signals are acquired from conventional optical disk drives, and these signals are used for quantitative detection of optical changes of sensing films deposited on conventional CD and DVD optical disks. Our developed analytical model of the operation of this Lab-on-DVD system describes the optical response of sensing films deposited onto the read surface of optical disks by taking into account the practical aspects of system performance that include possible reagent leaching effects, water sampling (delivering) efficiency, and possible changes of the film morphology after water removal. By applying a screen-printing process, we demonstrated a laboratory-scale automated production of sensing films with an average thickness of approximately 10 microm and a thickness relative standard deviation of <3% across multiple films. Finally, we developed a system for delivery of water-sample volumes to sensing films on the disk that utilized a multifunctional jewel case assembly.