William T. M. Irvine

Lock and key colloids

New functional materials can in principle be created using colloids that self-assemble into a desired structure by means of a programmable recognition and binding scheme. This idea has been explored by attaching ‘programmed’ DNA strands to nanometre- and micrometre- sized particles and then using DNA hybridization to direct the placement of the particles in the final assembly. Here we demonstrate an alternative recognition mechanism for directing the assembly of composite structures, based on particles with complementary shapes. Our system, which uses Fischer’s lock-and-key principle, employs colloidal spheres as keys and monodisperse colloidal particles with a spherical cavity as locks that bind spontaneously and reversibly via the depletion interaction. The lock-and-key binding is specific because it is controlled by how closely the size of a spherical colloidal key particle matches the radius of the spherical cavity of the lock particle. The strength of the binding can be further tuned by adjusting the solution composition or temperature. The composite assemblies have the unique feature of having flexible bonds, allowing us to produce flexible dimeric, trimeric and tetrameric colloidal molecules as well as more complex colloidal polymers. We expect that this lock-and-key recognition mechanism will find wider use as a means of programming and directing colloidal self-assembly.

Cubic crystals from cubic colloids

We have studied the crystallization behavior of colloidal cubes by means of tunable depletion interactions. The colloidal system consists of novel micron-sized cubic particles prepared by silica deposition on hematite templates and various non-adsorbing watersoluble polymers as depletion agents. We have found that under certain conditions the cubes self-organize into crystals with a simple cubic symmetry, which is set by the size of the depletant. The dynamic of crystal nucleation and growth is investigated, monitoring the samples in time by optical microscopy. Furthermore, by using temperature sensitive microgel particles as depletant it is possible to fine tune depletion interactions to induce crystal melting. Assisting crystallization with an alternating electric field improves the uniformity of the cubic pattern allowing the preparation of macroscopic (almost defect-free) crystals that show visible Bragg colors.

Pleats in crystals on curved surfaces

Hexagons can easily tile a flat surface, but not a curved one. Introducing heptagons and pentagons (defects with topological charge) makes it easier to tile curved surfaces; for example, soccer balls based on the geodesic domes of Buckminster Fuller have exactly 12 pentagons (positive charges). Interacting particles that invariably form hexagonal crystals on a plane exhibit fascinating scarred defect patterns on a sphere. Here we show that, for more general curved surfaces, curvature may be relaxed by pleats: uncharged lines of dislocations (topological dipoles) that vanish on the surface and play the same role as fabric pleats. We experimentally investigate crystal order on surfaces with spatially varying positive and negative curvature. On cylindrical capillary bridges, stretched to produce negative curvature, we observe a sequence of transitions—consistent with our energetic calculations—from no defects to isolated dislocations, which subsequently proliferate and organize into pleats; finally, scars and isolated heptagons (previously unseen) appear. This fine control of crystal order with curvature will enable explorations of general theories of defects in curved spaces. From a practical viewpoint, it may be possible to engineer structures with curvature (such as waisted nanotubes and vaulted architecture) and to develop novel methods for soft lithography and directed self-assembly.

Robust long-distance entanglement and a loophole-free bell test with ions and photons.

Two trapped ions that are kilometers apart can be entangled by the joint detection of two photons, each coming from one of the ions, in a basis of entangled states. Such a detection is possible with linear optical elements. The use of two-photon interference allows entanglement distribution free of interferometric sensitivity to the path length of the photons. The present method of creating entangled ions also opens up the possibility of a loophole-free test of Bells inequalities.

Topological mechanics of gyroscopic metamaterials

Significance We have built a new type of mechanical metamaterial: a “gyroscopic metamaterial” composed of rapidly spinning objects that are coupled to each other. At the edges of these materials, we find sound waves that are topologically protected (i.e. they cannot be scattered backward or into the bulk). These waves, which propagate in one direction only, are directly analogous to edge currents in quantum Hall systems. Through a mathematical model, we interpret the robustness of these edge waves in light of the subtle topological character of the bulk material. Crucially, these edge motions can be controlled by distorting the metamaterial lattice, opening new avenues for the control of sound in matter. Topological mechanical metamaterials are artificial structures whose unusual properties are protected very much like their electronic and optical counterparts. Here, we present an experimental and theoretical study of an active metamaterial—composed of coupled gyroscopes on a lattice—that breaks time-reversal symmetry. The vibrational spectrum displays a sonic gap populated by topologically protected edge modes that propagate in only one direction and are unaffected by disorder. We present a mathematical model that explains how the edge mode chirality can be switched via controlled distortions of the underlying lattice. This effect allows the direction of the edge current to be determined on demand. We demonstrate this functionality in experiment and envision applications of these edge modes to the design of one-way acoustic waveguides.

Strong coupling through optical positioning of a quantum dot in a photonic crystal cavity

crystal cavities have relied largely on random chance 5,6 and often required the measurement of many devices before finding a cavity in which a quantum dot is both spectrally and spatially in resonance with the cavity mode. These devices have the additional complication that the photonic crystal cavity typically interacts with many emitters due to the large quantum dot density required to find a strongly coupled device. A deterministic coupling method based on using atomic force microscopy to locate the strain sites of buried quantum dots has previously been demonstrated. 7,8 Here, we present an all-optical method for measuring the positions of individual quantum dots that allows us to deterministically achieve strong coupling between a quantum dot and a photonic crystal cavity. This versatile method can be performed in the measurement setup at a very low quantum dot density and could be applied to many emitter-cavity systems. Our technique relies on the precise determination of the optical

Tying Knots in Light Fields

We construct analytically, a new family of null solutions to Maxwells equations in free space whose field lines encode all torus knots and links. The evolution of these null fields, analogous to a compressible flow along the Poynting vector that is shear free, preserves the topology of the knots and links. Our approach combines the construction of null fields with complex polynomials on S3. We examine and illustrate the geometry and evolution of the solutions, making manifest the structure of nested knotted tori filled by the field lines.

Lock and key colloids through polymerization-induced buckling of monodisperse silicon oil droplets

We have developed a new simple method to fabricate bulk amounts of colloidal spheres with well defined cavities from monodisperse emulsions. Herein, we describe the formation mechanism of “reactive” silicon oil droplets that deform to reproducible shapes via a polymerization-induced buckling instability. Owing to their unique shape, the resulting particles can be successfully used as colloidal building blocks in the assembly of composite clustersvia “lock-and-key” interactions.

Nonlinear Photonic Crystals as a Source of Entangled Photons

Nonlinear photonic crystals can be used to provide phase matching for frequency conversion in optically isotropic materials. The phase-matching mechanism proposed here is a combination of form birefringence and phase velocity dispersion in a periodic structure. Since the phase matching relies on the geometry of the photonic crystal, it becomes possible to use highly nonlinear materials. This is illustrated considering a one-dimensional periodic Al0.4Ga0.6As/air structure for the generation of 1.5 microm light. We show that phase-matching conditions used in schemes to create entangled photon pairs can be achieved in photonic crystals.

Helicity conservation by flow across scales in reconnecting vortex links and knots

Significance Ideal fluids have a conserved quantity—helicity—which measures the degree to which a fluid flow is knotted and tangled. In real fluids (even superfluids), vortex reconnection events disentangle linked and knotted vortices, jeopardizing helicity conservation. By generating vortex trefoil knots and linked rings in water and simulated superfluids, we observe that helicity is remarkably conserved despite reconnections: vortex knots untie and links disconnect, but in the process they create helix-like coils with the same total helicity. This result establishes helicity as a fundamental building block, like energy or momentum, for understanding the behavior of complex knotted structures in physical fields, including plasmas, superfluids, and turbulent flows. The conjecture that helicity (or knottedness) is a fundamental conserved quantity has a rich history in fluid mechanics, but the nature of this conservation in the presence of dissipation has proven difficult to resolve. Making use of recent advances, we create vortex knots and links in viscous fluids and simulated superfluids and track their geometry through topology-changing reconnections. We find that the reassociation of vortex lines through a reconnection enables the transfer of helicity from links and knots to helical coils. This process is remarkably efficient, owing to the antiparallel orientation spontaneously adopted by the reconnecting vortices. Using a new method for quantifying the spatial helicity spectrum, we find that the reconnection process can be viewed as transferring helicity between scales, rather than dissipating it. We also infer the presence of geometric deformations that convert helical coils into even smaller scale twist, where it may ultimately be dissipated. Our results suggest that helicity conservation plays an important role in fluids and related fields, even in the presence of dissipation.