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Dive into the research topics where Wolfgang Hell is active.

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Featured researches published by Wolfgang Hell.


Chemistry-an Asian Journal | 2008

Trinuclear Rhodium Complexes and Their Relevance for Asymmetric Hydrogenation

Angelika Preetz; Wolfgang Baumann; Hans-Joachim Drexler; Christian Fischer; Jiangtao Sun; Anke Spannenberg; Oswald Zimmer; Wolfgang Hell; Detlef Heller

Various trinuclear rhodium complexes of the type [Rh(3)(PP)(3)(mu(3)-OH)(x)(mu(3)-OMe)(2-x)]BF(4) (where PP = Me-DuPhos, dipamp, dppp, dppe; different ligands and mu-bridging anions) are presented, which are formed upon addition of bases such as NEt(3) to solvate complexes [Rh(PP)(solvent)(2)]BF(4). They were extensively characterized by X-ray diffraction and NMR spectroscopy ((103)Rh, (31)P, (13)C, (1)H). Their in situ formation resulting from basic additives (NEt(3)) or basic prochiral olefins (without addition of another base) can cause deactivation of the asymmetric hydrogenation. This effect can be reversed by means of acidic additives.


Archive | 2007

Process for the Preparation of (1R,2R)-3-(3-dimethylamino-1-ethyl-2-methylpropyl)-phenol

Wolfgang Hell; Oswald Zimmer; Helmut Buschmann; Jörg Holenz; Stefan Gladow


Archive | 2004

Method for the production of substituted 3-aryl-butyl amine compounds

Wolfgang Hell; Markus Kegel; Bernhard Akteries; Helmut Buschmann; Jörg Holenz; Hartmut Löbermann; Detlef Heller; Hans-Joachim Drexler; Stefan Gladow


Archive | 2005

Process for the preparation of substituted 3-aryl-butylamine compounds

Wolfgang Hell; Markus Kegel; Bernhard Akteries; Helmut Buschmann; Joerg Holenz; Hartmut Loebermann; Detlef Heller; Hans-Joachim Drexler; Stefan Gladow


Archive | 2005

Process for the preparation of substitued 3-aryl-butylamine compounds

Wolfgang Hell; Markus Kegel; Berhard Akteries; Helmut Buschmann; Joerg Holenz; Harmut Loebermann; Detlef Heller; Hans-Joachim Drexler; Stefan Gladow


Archive | 2006

Separation of Stereoisomeric N,N-Dialkylamino-2Alkyl-3-Hydroxy-3-Phenylalkanes

Helmut Heinrich Buschmann; Wolfgang Hell


Archive | 2008

Process for Preparing a Substituted Dimethyl-(3-arylbutyl)amine Compound by Homogeneous Catalysis

Wolfgang Hell; Markus Kegel; Helmut Buschmann; Felix Spindler; Detlef Heller; Hans-Joachin Drexler


Archive | 2006

Process for preparing substituted dimethyl(3-arylbutyl)amine compounds by means of homogeneous catalysis

Wolfgang Hell; Markus Kegel; Helmut Buschmann; Felix Spindler; Detlef Heller; Hans-Joachim Drexler


Archive | 2006

Crystalline forms of (1rs,3rs,6rs)-6-dimethvlaminomethvl-1-(3-methoxv- phenyl)cyclohexane-1 ,3-diol hydrochloride

Michael Gruss; Helmut Buschmann; Andreas Fischer; Wolfgang Hell; Dagmar Lischke


Archive | 2006

Separation of stereoisomeric n,n-dialkylamino-2-alkyl-3-phenyl alkanes

Helmut Heinrich Buschmann; Wolfgang Hell

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