Won Sun Kim

Organic-inorganic hybrid photopolymer with reduced volume shrinkage

An organic-inorganic hybrid photopolymer containing surface-photoreactive nanoparticles, which exhibits a significant enhancement in optical properties is reported. The photopolymer containing surface-photoreactive nanoparticles showed high diffraction efficiency near 90% and reduced volume shrinkage without affecting the energetic sensitivity and optical quality of the photopolymer.

Nanoparticle-induced refractive index modulation of organic-inorganic hybrid photopolymer

An organic-inorganic photopolymers have been studied for their potential in of reducing the volume shrinkage during photopolymerization and enhancing the dimensional stability of photopolymers. We demonstrate the diffraction efficiency of photopolymers could be significantly enhanced by the interfacial interactions induced at the surface of inorganic nanoparticles.

Effect of photoreactivity of polyimide on the molecular orientation of liquid crystals on photoreactive polymer/polyimide blends

We prepared blend alignment layers from polymethacrylate with coumarin side chains (PMA-g-coumarin) and polyimides for the orientation of liquid crystals (LCs) using linearly polarized ultraviolet (UV) irradiation. We used two different polyimides, namely 4,4′-(hexafluoro-isopropylidene) diphthalic anhydride-3,5-diamino-benzoic acid (6FDA-DBA) and pyromellitic dianhydride-4,4′-oxydianiline (PMDA-ODA). It was found that the molecular orientation of the LC depended on the type of polyimide in the blend alignment layer. The thermal stability of the LC orientation was enhanced regardless of the type of polyimide, while the direction of LC orientation was different for each type of polyimide. The photoreactivity of the polyimide was a very important factor in determining the molecular orientation of the LC on the blend alignment layer. This may be attributed to the different mechanisms of LC orientation on PMA-g-coumarin and polyimide induced by the polarized UV irradiation. The direction of the LC orientation could be changed by controlling the photoreaction of the polyimides using the appropriate UV filter for the polarized UV irradiation.

P‐171: Effect of Plasticization of Poly(Vinyl Cinnamate) on Liquid Crystal Orientation Stability

A cinnamate group is a well-known compound group used in the dimerization reaction by ultraviolet irradiation, and cinnamate polymers are studied as photoalignment materials. In this study, the radical reaction of cinnamate side groups attached to a flexible polymer backbone is considered feasible using thermal energy. To induce the thermal reaction of cinnamate side groups, we modified the flexibility of poly(vinyl cinnamate) by introducing a plasticizer into the polymers and investigated the thermal reaction behavior of cinnamate side groups. The plasticization of poly(vinyl cinnamate) makes the induction of the thermal reaction of cinnamate side groups easier than that of unmodified poly(vinyl cinnamate). The thermal reaction of cinnamate side groups is closely related to the enhancement of the thermal stability of the liquid crystal orientation of polymer films with polarized UV irradiation.

Optical properties of a photopolymer with large refractive index modulation for holographic application

Optical transparency and high diffraction efficiency are two essential factors for high performance of the photopolymer. Optical transparency mainly depends on the miscibility between polymer binder and photopolymerized polymer, while diffraction efficiency depends on the refractive index modulation between polymer binder and photopolymerized polymer. For most of organic materials, the large refractive index difference between two polymers accompanies large structural difference that leads to the poor miscibility and thus poor optical quality via light scattering. Therefore, it is difficult to design a high-performance photopolymer satisfying both requirements. In this work, we prepared a new phase-stable photopolymer with large refractive index modulation and investigated the optical properties. Our photopolymer is based on modified poly (methyl methacrylate) as a polymer binder, acryl amide as a photopolymerizable monomer, triethanolamine as initiator, and yellow eosin as a photosensitizer at 532nm. Diffraction efficiency over 85% and optical transmittance over 90% were obtained for the photopolymer.

A new type of photopolymer with nanoporous structure based on ionomers

In the present work, a new type of photopolymer containing nano-sized photosensitive domains was proposed and optical properties including diffraction efficiency and optical transparency were investigated. By introducing nano-sized photosensitive domains, the phase stability of the photopolymer was greatly enhanced and recording stability was also enhanced.

Introduction of Multilayered Photorefractive Polymer Composite for the Enhancement of Recording Stability

In the present work, multilayered photorefractive polymer composites were introduced in order to enhance the recording stability without sacrificing the recording speed of the photorefractive polymer composites. In the multilayered photorefractive polymer composite, the gain coefficient, diffraction efficiency, and the recording stabilty could be enhanced without sacrificing the response time of the photorefractive polymer composite.