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Featured researches published by Xiao Liang Luo.


Journal of the American Chemical Society | 1989

Homogeneous catalysis of silane alcoholysis via nucleophilic attack by the alcohol on an Ir(.eta.2-HSiR3) intermediate catalyzed by [IrH2S2(PPh3)2]SbF6 (S = solvent)

Xiao Liang Luo; Robert H. Crabtree


Journal of the American Chemical Society | 1990

Solution equilibrium between classical and nonclassical polyhydride tautomers [ReH4(CO)L3]+ and [ReH2(.eta.2-H2)(CO)L3]+ (L = PMe2Ph). Equilibrium isotope effects and an intermediate trihydrogen complex in intramolecular site exchange of dihydrogen and hydride ligands

Xiao Liang Luo; Robert H. Crabtree


Inorganic Chemistry | 1990

Reaction of ReH sub 7 (PPh sub 3 ) sub 2 with silanes: Preparation and characterization of the first silyl polyhydride complexes, ReH sub 6 (SiR sub 3 )(PPh sub 3 ) sub 2 (SiR sub 3 = SiPh sub 3 , SiEt sub 3 , SiHEt sub 2 )

Xiao Liang Luo; Denise Baudry; Philip Boydell; P. Charpin; Martine Nierlich; Michel Ephritikhine; Robert H. Crabtree


Journal of the American Chemical Society | 1990

Synthesis and structural studies of some new rhenium phosphine heptahydride complexes. Evidence for classical structures in solution

Xiao Liang Luo; Robert H. Crabtree


Inorganic Chemistry | 1990

Planar tricoordinate oxygens in a mixed aqua(tetrahydrofuran)iridium complex: x-ray crystal and molecular structure of [IrH2(THF)(H2O)(PPh3)2]SbF6.cntdot.THF

Xiao Liang Luo; Gayle K. Schulte; Robert H. Crabtree


Inorganic Chemistry | 1989

The first polyhydrides stabilized only by N-donor ligands, hexahydro[hydrotris(pyrazolyl)borato]rhenium and heptahydro[dipyrazolylmethane]rhenium

Douglas G. Hamilton; Xiao Liang Luo; Robert H. Crabtree


Inorganic Chemistry | 1993

Tungsten(VI) hexahydride complexes supported by chelating triphosphine ligands: Protonation to give [eta][sup 2]-dihydrogen complexes and catalytic dehydrogenation of cyclooctane to cyclooctene

Demetrius Michos; Xiao Liang Luo; J. W. Faller; Robert H. Crabtree


Inorganic Chemistry | 1992

Stretched H2 complexes: structural control in ReH7{P(C6H4-p-X)3}2 (X = CH3, H, F, CF3, OMe) complexes by electronic ligand effects

Demetrius Michos; Xiao Liang Luo; Judith A. K. Howard; Robert H. Crabtree


Inorganic Chemistry | 1992

Synthesis and spectroscopic characterization of ruthenium(II) .eta.2-dihydrogen complexes of the type [RuH(.eta.2-H2)(L)(triphos)]+ (L = CO, P(OCH2)3CEt, PMe2Ph; triphos = PPh(CH2CH2PPh2)2)

Demetrius Michos; Xiao Liang Luo; Robert H. Crabtree


Inorganic Chemistry | 1990

Testing the T1 method: a comparison of T1(min) and structural data

Xiao Liang Luo; Robert H. Crabtree

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Allen R. Siedle

Indiana University Bloomington

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Denise Baudry

Centre national de la recherche scientifique

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