Xigao Jin
Chinese Academy of Sciences
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Publication
Featured researches published by Xigao Jin.
Journal of Macromolecular Science, Part B | 1999
Fuming Li; Liyan Huang; Yi Shi; Xigao Jin; Zongquan Wu; Zhihao Shen; Kathy C. Chuang; Richard E. Lyon; Frank W. Harris; Stephen Z. D. Cheng
Abstract Two organo-soluble aromatic polyimides have been synthesized by introducing pendant groups of trifluromethyl or methyl onto the 2- and 2′-positions of a biphenyl diamine and reacting each of them with biphenyltetracarboxylic dianhydride (BPDA): 2,2′-bis(trifluoromethyl)-4,4′-diaminobiphenyl (PFMB) or 2,2′-dimethyl-4,4′-diaminobiphenyl (DMB). These two polyimides, BPDA-PFMB and BPDA-DMB, are prepared via a one-step poly condensation method, and they can be fabricated into fibers, films, and other application forms. Our research shows that in fiber applications, these two fibers exhibit excellent mechanical properties and outstanding thermal and thermooxidative stability. Their long-term mechanical tensile performance at high temperatures is found to be critically associated with the type of side pendant groups at the 2- and 2′-positions of the diamines. High-resolution pyrolysis-gas chromatography/mass spectrometry (PyGC-MS) results show that the pyrorgams of these two polyimides possess more than...
Science China-chemistry | 1999
Liyan Huang; Yi Shi; Xigao Jin; Zongquan Wu; Fuming Li; Z. D. Stephen Cheng
The thermal degradation behavior of two organo-soluble polyimides was investigated by high resolution pyrolysis-gas chromatography/mass spectrometry. The pyrolyzates of the polymers at various temperatures were identified and characterized quantitatively. The relationship between the polymer structure and pyrolyzate distribution was discussed. The kinetic parameters of the thermal degradation were calculated based on thermogravimetric measurements. Finally, the thermal degradation mechanism for the polymers was suggested.
Journal of Macromolecular Science, Part B | 1998
Liusheng Chen; Ming Ni; Shijun Jia; Xigao Jin; Shouren Ge; Atsushi Takahara; Tisato Kajiyama
Abstract Atomic force microscopy (AFM) has been applied to observe single-chain polymethylmethacrylate (PMMA) particles that were stored for six months at room temperature after being sprayed from very dilute solutions in good solvents, good/poor mixed solvents, and a theta solvent. Nearly monodisperse PMMA standards of molecular weights ranging from 7.90 × 104 to 1.3 × 106 were used to investigate the effect of molecular weight (MW) on the size of the single-chain PMMA particles. These single-chain particles showed close to spherical shapes. The morphology of single-chain PMMA particles of a given molecular weight has found to be identical in spite of different solvents used for solution spraying. Molecular weight dependence of the particle dimension was also found. The diameters of single-chain PMMA particles after correction of tip-geometry effect were compared with the values estimated from molecular weight and density.
Journal of Thermal Analysis and Calorimetry | 2000
Zongquan Wu; Fuming Li; Liyan Huang; Yameng Shi; Xigao Jin; S. Fang; Kathy C. Chuang; Richard E. Lyon; Frank W. Harris; Stephen Z. D. Cheng
European Polymer Journal | 2005
Chaojun Jing; Liusheng Chen; Yi Shi; Xigao Jin
Journal of Analytical and Applied Pyrolysis | 2002
Xigao Jin; Liyan Huang; Yi Shi; Shiyong Yang; Aijun Hu
Chinese Chemical Letters | 2005
Chaojun Jing; Liusheng Chen; Yi Shi; Xigao Jin
Archive | 2006
Xigao Jin; Chaojun Jing; Liusheng Chen; Yi Shi
Chinese Journal of Polymer Science | 2002
Hongxiang Teng; Wen-hong Tang; Yi Shi; Xigao Jin
Acta Polymerica Sinica | 2009
Chaojun Jing; Liusheng Chen; Yi Shi; Xigao Jin