Xingrui Deng

Plasma-assisted lubrication for the sliding between polymer and DLC

Diamond like carbon (DLC) has widespread applications in many fields because of its high hardness, low friction, chemical inertness, and other excellent properties. Recently, DLC is applied to machine parts as coating to reinforce the surface property. On the other hand, the use of polymer parts made of engineering plastics is increasing instead of metal ones because polymer is light, low cost and easily processed. It is expected in the future that the application of DLC to metal comes to be more frequent in order to further improve the sliding property between metal-polymer contact in sliding parts. For that reason, it is important to clarify the characteristic of friction between DLC and polymer. In this research, silicon doped DLC (a-C:H:Si), which is coated by plasma enhanced chemical vapor deposition (PECVD) on a steel disk (SUS304, JIS) 25 mm in diameter, was used as a mating material of sliding against Polyoxymethylene (POM) which is an engineering plastic. Friction tests were conducted in a roller-on-disk apparatus under dry condition, where the side surface of POM roller 5 mm in diameter and 5 mm in height was contacted to DLC-coated disk at a normal load of 1 N. Sliding test was conducted for 20 minutes at a rotation speed of 200 rpm, where the rotation radius of the roller changes from 5.5 to 10.5 mm along the roller axis. During the total sliding distance of 200 m, helium gas flow and helium plasma flow were irradiated for 50 to 100 m, and 100 to 150 m, respectively. Friction coefficient observed for the first 50 m without any irradiation was around 0.2, which was not changed by the following helium gas irradiation. Then, plasma irradiation caused seriously instable and high friction coefficient (around 1.0); however, after stopping the plasma irradiation, the friction coefficient rapidly fell down to around 0.066 and was stabilized. This result indicates the possibility of plasma-assisted lubrication for the sliding between polymer and DLC. (The authors gratefully acknowledge the funding by JST CREST, Japan.)

Effect of tetramethylsilane flow on the deposition and tribological behaviors of silicon doped diamond-like carbon rubbed against poly(oxymethylene)

In this study, silicon doped diamond-like carbon (Si-DLC) was deposited on stainless steel (JIS SUS304) by using surface wave-excited plasma (SWP). The effects of tetramethylsilane (TMS) flow on the composition, topography, mechanical properties and tribological behavior were investigated. Pin-on-disc tribo-meter was used to investigate the tribological behavior of the Si-DLC coating rubbed against poly(oxymethylene) (POM). The results show that the deposition rate, roughness of Si-DLC increased and the hardness of Si-DLC decreased with the increase of TMS flow rate from 2 to 4 sccm; the roughness increase therein led to the increase of ploughing term of friction. The increase of adhesion term was also seen with the increase of TMS flow rate, being attributed to the decrease of hydrogen concentration in the coating. It was considered that more POM transferred onto the Si-DLC deposited at higher TMS flow rate due to larger heat generation by friction.