Xinjing Li

Geological characteristics and resource potential of shale gas in China

With Sichuan Basin as focus, this paper introduces the depositional environment, geochemical and reservoir characteristics, gas concentration and prospective resource potential of three different types of shale in China: marine shale, marine-terrigenous shale and terrigenous shale. Marine shale features high organic abundance (TOC: 1.0%–5.5%), high-over maturity (Ro: 2%–5%), rich accumulation of shale gas (gas concentration: 1.17–6.02 m3/t) and mainly continental shelf deposition, mainly distributed in the Paleozoic in the Yangtze area, Southern China, the Paleozoic in Northern China Platform and the Cambrian-Ordovician in Tarim Basin; Marine-terrigenous coalbed carbonaceous shale has high organic abundance (TOC: 2.6%–5.4%) and medium maturity (Ro: 1.1%–2.5%); terrigenous shale in the Mesozoic and Cenozoic has high organic abundance (TOC: 0.5%–22.0%) and mid-low maturity (Ro: 0.6–1.5%). The study on shale reservoirs in the Lower Paleozoic in Sichuan Basin discoveried nanometer-sized pores for the first time, and Cambrian and Silurian marine shale developed lots of micro- and nanometer-sized pores (100–200 nm), which is quite similar to the conditions in North America. Through comprehensive evaluation, it is thought that several shale gas intervals in Sichuan Basin are the practical targets for shale gas exploration and development, and that the Weiyuan-Changning area in the Mid-South of Sichuan Basin, which is characterized by high thermal evolution degree (Ro: 2.0%–4.0%), high porosity (3.0%–4.8%), high gas concentration (2.82–3.28 m3/t), high brittle mineral content (40%–80%) and proper burial depth (1500–4500 m), is the core area for shale gas exploration and development, the daily gas production for Well Wei 201 is 1×104–2×104 m3.

Organic Carbon and Stable C-O Isotopic Study of the Lower Silurian Longmaxi Formation Black Shales in Sichuan Basin, SW China: Paleoenvironmental and Shale Gas Implications

In order to better decipher the paleoenvironment of the Early Silurian black shale in the southern Sichuan Basin and constrain their shale gas potential, organic carbon and stable C-O isotopic studies have been performed on the Longmaxi Formation from Well N203. The organic carbon isotopic studies show a relative low δ13Corg value at the lower part of the Longmaxi Formation, corresponding to the negative stable carbon isotope (δ13C) excursion and positive oxygen isotope (δ18O) excursion. These isotopic features indicate an anoxic environment at the lower part of the Longmaxi Formation, which might be related to the high atmosphere temperature and sea-level rise. The anoxic environment is also proved by framboidal pyrites studies, which present diameter of most framboids in the range of 3–5 μm. The anoxic environment promoted the deposition of organic carbon, leading to the high TOC content at the lower part. This anoxic environment only lasted for a short period, with a gradually evolution to oxic environment at the middle and upper part of the Longmaxi Formation, evidenced by very low TOC content, increasing δ13Corg values, positive δ13C values and negative δ18O values. Our studies have further constrained the best source of rocks for shale gas at the lower part of the Longmaxi Formation.

Major controlling factors for the high-quality shale of Wufeng–Longmaxi Formation, Sichuan Basin:

Research on major controlling factors of the high-quality shale in Upper Ordovician Wufeng–Lower Silurian Longmaxi Formation is a major subject. Based on the information of outcrops and drilling data acquired from Southern Sichuan combined with geochemical elemental analysis and biostratigraphy, this paper analyzed the sedimentary characteristics of Wufeng–Longmaxi organic-rich shale in Sichuan Basin, including plate movements, fluctuation of sea level, paleoproductivity, deposition rates, and paleogeographic environment, and revealed the distribution and sedimentary controlling factors of high-quality shale. Four preliminary conclusions were drawn: (1) The collision and joint of Yangtze Plate and its periphery plates, as well as the intraplate deformation, were gentle in early stage, strong in late stage, gentle in northwest, while strong in southeast, thus forming the northwestward migration of sedimentation center in Sichuan Basin, and the evolution of southern Sichuan sea closeness from weak to strong. (2) Sea level changed following the cycle of deep→shallow→deep→shallow at the turn of Ordovician–Silurian. High sea level and stable ocean basin in early stage created extensive anoxic tectonic sedimentary space which was in favor of organic matter preservation. (3) Influenced by tectonic movements and sea closeness, paleoproductivity of Southern Sichuan marine presented the trend of high in early stage and low in late stage, while the deposition rate also changed from slow in the early stage to fast in the late stage. (4) Extensive deposition and distribution of organic-rich silicic shale was mainly controlled by stable sea basin of low deposition rate, relatively high sea level, semienclosed water, and low deposition rate. The research showed that the high-quality shale in Sichuan Basin is characterized by multiphase superimposition, horizontal extension, and northwest renewal of sedimentary age; Wufeng–Rhuddanian is the main depositional period of high-quality shale, Aeronian comes next; the main exploration layers are Wufeng–Rhuddanian in southern–eastern Sichuan depression, Rhuddanian–Aeronian in Weiyuan, and Wufeng–Telychian in central-northern Sichuan.