Xinmei Yang

Raman study of correlation between defects and ferromagnetism in graphite

The variation of ferromagnetism induced by 12C+ ion implantation in highly oriented pyrolytic graphite was systematically studied by using Raman spectroscopy in conjunction with magnetic moment measurements and annealing treatments. It was found that the magnetization of the implanted sample was closely correlated with the density of the defects, which was characterized by the Raman spectra, produced by the implantation. It is clear that by using consecutive implantation steps at different energies to increase the vacancy defects in the implanted layer, the magnetization of the sample increases with the number of the implantation steps until the fourth step of implantation, which causes the near surface layer to be highly disordered or amorphous, weakening the magnetic coupling and thus resulting in the decrease in magnetization. The annealing treatments of the sample indicate that the ferromagnetism induced by the implantations is stable at room temperature. However, when the sample is annealed at 473 K (the Wigner energy release temperature), the density of vacancies and interstitials is abruptly decreased and the magnetism induced by the implantations is extinguished. This finding gives a clear indication of the key role of the defects produced by C+ ion implantation in graphite.

The effect of magnetic perturbations on edge transport in TEXT

The effect of magnetic islands and stochastic fields on thermal transport, particle transport, and the radial electric field in TEXT is discussed. Both intrinsic and externally produced magnetic islands are found to enhance particle transport. Large amplitude m = 2 islands (width/a less-than-or-equal-to 0.25) are produced by neon puffing. Smaller amplitude m congruent-to 6 islands (width/a less-than-or-equal-to 0.07) are produced with resonant external coils at low coil current. Higher currents produce stochastic magnetic fields for r/a greater-than-or-equal-to 0.85. Stochastic fields significantly alter the radial electric field and enhance thermal transport but not particle transport. Experimentally observed transport changes are compared with analytic theories and are in reasonable agreement.

Effect of Ar+ ion irradiation on the microstructure of pyrolytic carbon

Pyrolytic carbon (PyC) coatings prepared by chemical vapor deposition were irradiated by 300 keV Ar+ ions. Then, atomic force microscopy, synchrotron-based grazing incidence X-ray diffraction, Raman spectroscopy, X-ray photoemission spectroscopy, and transmission electron microscopy were employed to study how Ar+ irradiation affects the microstructure of PyC, including the microstructural damage mechanisms and physics driving these phenomena. The 300 keV Ar+ ion irradiation deteriorated the structure along the c-axis, which increased the interlayer spacing between graphene layers. With increasing irradiation dose, the density of defect states on the surface of PyC coating increases, and the basal planes gradually loses their initial ordering resulting in breaks in the lattice and turbulence at the peak damage dose reaches 1.58 displacement per atom (dpa). Surprisingly, the PyC becomes more textured as it becomes richer in structural defects with increasing irradiation dose

High temperature in-situ synchrotron-based XRD study on the crystal structure evolution of C/C composite impregnated by FLiNaK molten salt

An in-situ real-time synchrotron-based grazing incidence X-ray diffraction was systematically used to investigate the crystal structural evolution of carbon fiber reinforced carbon matrix (C/C) composite impregnated with FLiNaK molten salt during the heat-treatment process. It was found that the crystallographic thermal expansion and contraction rate of interlayer spacing d002 in C/C composite with FLiNaK salt impregnation is smaller than that in the virgin sample, indicating the suppression on interlayer spacing from FLiNaK salt impregnated. Meanwhile the crystallite size LC002 of C/C composite with FLiNaK salt impregnation is larger than the virgin one after whole heat treatment process, indicating that FLiNaK salt impregnation could facilitate the crystallization of C/C composite after heat treatment process. This improved crystallization in C/C composite with FLiNaK salt impregnation suggests the synthetic action of the salt squeeze effect on crooked carbon layer and the release of internal residual stress after heating-cooling process. Thus, the present study not only contribute to reveal the interaction mechanism between C/C composite and FLiNaK salt in high temperature environment, but also promote the design of safer and more reliable C/C composite materials for the next generation molten salt reactor.