Xiongzhi Zhang

Synthesis of salt responsive spherical polymer brushes

A facile preparation of novel salt responsive spherical polymer brushes (SPB) consisting of a carbon spheres core and a shell of sodium polystyrene sulfonate (PSSNa) was described. The SPB were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). The radius R of carbon spheres and hydrodynamic radius Rh of SPB were ca. 370 nm and 785 nm, respectively. The brushes had Mw of 393600 g/mol with polydispersity Mw/Mn of 1.58. Furthermore, the dependence of PSSNa brushes on ionic strength and pH was investigated.

Designed synthesis of tunable amorphous carbon nanotubes (a-CNTs) by a novel route and their oxidation resistance properties

Tunable amorphous carbon nanotubes (a-CNTs) were successfully synthesized using V3O7·H2O and glucose solution as the starting materials by a novel route for the first time. The as-obtained samples were separately characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), energy-dispersive spectrometer (EDS), elemental analysis (EA), Fourier transform infrared spectroscopy (FT-IR) and Raman spectrum. The results showed that the as-obtained a-CNTs had uniform diameters with outer diameter ranging from 140 to 250 nm and inner diameter about 28 nm on an average, and their length was up to several micrometres. No VOx residues remaining in a-CNTs showed the as-obtained a-CNTs with high purity. The as-prepared a-CNTs were a kind of hydrogenated a-CNTs containing both the sp3- and sp2-type carbons. Furthermore, the thermal stability of the as-obtained a-CNTs in the air atmosphere were investigated by thermo-gravimetric/differential thermal analyser (TG-DTA), revealing that the as-obtained a-CNTs had good thermal stability and oxidation resistance below 300 °C in air.