Xueli Chen

Rapid co-pyrolysis of rice straw and a bituminous coal in a high-frequency furnace and gasification of the residual char

Rapid pyrolysis of rice straw (RS) and Shenfu bituminous coal (SB) separately, and rapid co-pyrolysis of RS/SB blends (mass ratio 1:4, 1:4, and 4:1), were carried out in a high-frequency furnace which can ensure both high heating rate and satisfying contact of fuel particles. Synergies between RS and SB during rapid co-pyrolysis were investigated. Intrinsic and morphological structures of residual char from co-pyrolysis, and their effects on gasification characteristics were also studied. Synergies occurred during rapid co-pyrolysis of RS and SB (RS/SB=1:4) resulting in decreasing char yields and increasing volatile yields. Synergies also happened during gasification of the char derived from co-pyrolysis of RS and SB with mass ratio of 1:4. The increased mass ratio of RS to SB did not only weaken synergies during co-pyrolysis, but significantly reduced the gasification rates of the co-pyrolysis char compared to the calculated values. Results can help to optimize co-conversion process of biomass/coal.

Study on CO2 gasification reactivity and physical characteristics of biomass, petroleum coke and coal chars

Gasification reactivities of six different carbonaceous material chars with CO2 were determined by a Thermogravimetric Analyzer (TGA). Gasification reactivities of biomass chars are higher than those of coke and coal chars. In addition, physical structures and chemical components of these chars were systematically tested. It is found that the crystalline structure is an important factor to evaluate gasification reactivities of different chars and the crystalline structures of biomass chars are less order than those of coke and coal chars. Moreover, initial gasification rates of these chars were measured at high temperatures and with relatively large particle sizes. The method of calculating the effectiveness factor η was used to quantify the effect of pore diffusion on gasification. The results show that differences in pore diffusion effects among gasification with various chars are prominent and can be attributed to different intrinsic gasification reactivities and physical characteristics of different chars.

Study on co-pyrolysis characteristics of rice straw and Shenfu bituminous coal blends in a fixed bed reactor.

Co-pyrolysis behaviors of rice straw and Shenfu bituminous coal were studied in a fixed bed reactor under nitrogen atmosphere. The pyrolysis temperatures were 700°C, 800°C and 900°C, respectively. Six different biomass ratios were used. Gas, tar components were analyzed by a gas chromatograph and a gas chromatography-mass spectrometry respectively. Under co-pyrolysis conditions, the gas volume yields are higher than the calculated values. Co-pyrolysis tar contains more phenolics, less oxygenate compounds than calculated values. The addition of biomass changes the atmosphere during the pyrolysis process and promotes tar decomposition. The SEM results show that the differences between the blended char and their parents char are not significant. The results of char yields and ultimate analysis also show that no significant interactions exist between the two kinds of particles. The changes of gas yield and components are caused by the secondary reactions and tar decomposition.

Co-pyrolysis behaviors of saw dust and Shenfu coal in drop tube furnace and fixed bed reactor

Co-pyrolysis behaviors of saw dust (SD) and Shenfu bituminous coal (SF) were studied in a drop tube furnace and a fixed bed reactor at different temperatures respectively. Six different biomass/coal ratios (B:C) were used. Compared the results with the calculated value obtained by the additional behavior, CO volume yields were lower while H2, CH4, CO2, volume yields were higher. Blend char yields had a good agreement with the calculated values, and their structures remained similar with SD and SF chars. Synergy effect occurred in gaseous phase, which was mainly caused by the secondary reactions. Compared the blend char yields in the drop tube furnace with those in the fixed bed reactor, the results showed the contacting way of biomass and coal particles had little influence on char yield in co-pyrolysis process. The reactivity index of blend char achieved the minimum at B:C=40:60 and the maximum at B:C=80:20.

Nitrogen conversion under rapid pyrolysis of two types of aquatic biomass and corresponding blends with coal.

Rapid pyrolysis of two types of aquatic biomass (blue-green algae and water hyacinth), and their blends with two coals (bituminous and anthracite) was carried out in a high-frequency furnace. Nitrogen conversions during rapid pyrolysis of the two biomass and the interactions between the biomass and coals on nitrogen conversions were investigated. Results show that little nitrogen retained in char after the biomass pyrolysis, and NH(3) yields were higher than HCN. During co-pyrolysis of biomass and coal, interactions between biomass and coal decreased char-N yields and increased volatile-N yields, but the total yields of NH(3)+HCN in volatile-N were decreased in which HCN formations were decreased consistently, while NH(3) formations were only decreased in the high-temperature range but promoted in the low-temperature range. Interactions between blue-green algae and coals are stronger than those between water hyacinth and coal, and interactions between biomass and bituminous are stronger than those between biomass and anthracite.

Co-pyrolysis characteristic of biomass and bituminous coal.

Co-pyrolysis characteristics of biomass and bituminous coal have been studied in this work. The temperature was up to 900°C with the heating rates of 10, 15, 20, 25 and 30°C/min. Rice straw, saw dust, microcrystalline cellulose, lignin and Shenfu bituminous coal were chosen as samples. Six different biomass ratios were used. The individual thermal behavior of each sample was obtained. The experimental weight fractions of the blended samples and the calculated values were compared. The results show that the weight fractions of the blended samples behave differently with calculated ones during the co-pyrolysis process. With the increasing biomass ratio, relative deviations between experimental weight fractions and calculated ones are larger. H/C molar ratio, heat transfer properties of biomass would affect to the interaction between biomass and coal. The maximum degradation rates are slower than the calculated ones. The activation energy distributions also changed by adding some biomass into coal.

Investigation on the high-temperature flow behavior of biomass and coal blended ash.

The high-temperature flow behavior of biomass (straw) and coal blended ash was studied. The variation of viscosity and the temperature of critical viscosity with different straw content were investigated. It is found that the straw ash with high viscosity is unsuitable for directly gasification and the 20% straw content sample can effectively decrease the viscosity. The solid phase content and mineral matters variation calculated by FactSage demonstrate the change of viscosity. In addition, the network theory illustrates that the Si-O-Si bond decreases to improve the viscosity of 20% straw content sample. The variation of mineral matters in XRD analysis validates the change of viscosity. Furthermore, the temperature of critical viscosity and lowest operation temperature reach the minimum when the straw content is 20%. Hysteresis between heating and cooling process of the sample with 20% straw content is more obvious than that of the samples with 40% and 80% straw content.

Effect of torrefaction on the properties of rice straw high temperature pyrolysis char: Pore structure, aromaticity and gasification activity

The influence of torrefaction on the physicochemical characteristics of char during raw and water washed rice straw pyrolysis at 800-1200°C is investigated. Pore structure, aromaticity and gasification activity of pyrolysis chars are compared between raw and torrefied samples. For raw straw, BET specific surface area decreases with the increased torrefaction temperature at the same pyrolysis temperature and it approximately increases linearly with weight loss during pyrolysis. The different pore structure evolutions relate to the different volatile matters and pore structures between raw and torrefied straw. Torrefaction at higher temperature would bring about a lower graphitization degree of char during pyrolysis of raw straw. Pore structure and carbon crystalline structure evolutions of raw and torrefied water washed straw are different from these of raw straw during pyrolysis. For both raw and water washed straw, CO2 gasification activities of pyrolysis chars are different between raw and torrefied samples.

Preparation of Coal Slurry with Alcohol Fermentation Wastewater

Abstract The feasibility of substituting alcohol fermentation wastewater of maize and cassava for water to prepare coal slurries was explored. The rheological and stability properties of coal alcohol fermentation wastewater slurries were studied and compared with that of coal water slurry. The results showed that both coal maize and cassava alcohol fermentation wastewater slurries exhibited shear-thinning behavior. Because of the oxygen-containing functional groups (carboxylic) with exchangeable cations in alcohol fermentation wastewater and its low pH value, coal maize and cassava alcohol fermentation wastewater slurries exhibited the higher apparent viscosities, the stronger shear-thinning behavior, and worse stabilities compared with the coal water slurry. In addition, alcohol fermentation wastewater should be diluted for preparing coal slurries to meet industrial need in apparent viscosity and solid concentration at the same time.

2 Dimensional finite stochastic breakup model of biomass particle breakup

Due to the high content of cellulose, hemicellulose and lignin, the anisotropy of biomass particle in spatial structure induces the difference of mechanical properties in different directions. In this paper, based on the finite stochastic breakup model and anisotropy of biomass particles, 2-dimensional finite stochastic breakup model (2D-FSBM) of biomass particle was proposed, and the breakup process of biomass particle was investigated. In this model, the strength difference in different directions and the minimum mass ratio of a sub-particle to the parent particle were both considered. The simulation results agreed well with the experimental results in particle shapes, which indicated that 2D-FSBM could predict the breakup process of biomass particles.