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Y. K. Mo

Case Western Reserve University

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Journal of Organometallic Chemistry | 1973

Organometallic chemistry : V. Protonation of acylferrocenes under stable ion conditions in fso3h-so2c1f solution

George A. Olah; Y. K. Mo

Abstract Protonation of acylferrocenes (FeCOR) in FSO3H-SO2CIF(SO2) solution was studied by PMR spectroscopy. The site of protonation is found to be at the carbonyl oxygen atom. Temperature dependent PMR spectra of protonated acylferrocenes FeCROH+ (R = CH3, C2H5, C6H5, OCH3) were observed indicating intermolecular hydrogen exchange with the acid solvent system. In addition the PMR spectra of acylferrocenes in FSO3 H-SO2 CIF(SO2) were found to be dependent upon the acid concentration.

Journal of the American Chemical Society | 1973

Electrophilic reactions at single bonds. XII. Hydrogen--deuterium exchange, protolysis (deuterolysis), and oligocondensation of alkanes with superacids

George A. Olah; Yuval Halpern; Jacob. Shen; Y. K. Mo

Journal of the American Chemical Society | 1972

Stable carbocations. CXXIV. Benzenium ion and monoalkylbenzenium ions

George A. Olah; Richard H. Schlosberg; Richard D. Porter; Y. K. Mo; David P. Kelly; Gheorghe D. Mateescu

Journal of the American Chemical Society | 1971

Electrophilic reactions at single bonds. III. H-D exchange and protolysis (deuterolysis) of alkanes with superacids. The mechanism of acid-catalyzed hydrocarbon transformation reactions involving the .sigma. electron pair donor ability of single bonds via three-center bond formation

George A. Olah; Yuval Halpern; Jacob. Shen; Y. K. Mo

Journal of the American Chemical Society | 1972

Stable carbocations. CXXIX. Mechanism of the benzidine and Wallach rearrangements based on direct observation of dicationic reaction intermediates and related model compounds

George A. Olah; Kenneth Dunne; David P. Kelly; Y. K. Mo

Journal of the American Chemical Society | 1972

Electrophilic reactions at single bonds. VII. Hydrogen-deuterium exchange accompanying protolysis (deuterolysis) of the borohydride and aluminum hydride anions with anhydrous strong acids. The intermediacy of pentahydroboron (BH5) and pentahydroaluminum (AlH5) and their structural relationship with the methonium ion (CH5+)

George A. Olah; Philip W. Westerman; Y. K. Mo; Gilles Klopman

Journal of Organic Chemistry | 1973

Stable carbocations. CXXXIV. Protonation of mono- and dihydroxybenzenes and their methyl ethers in superacids

George A. Olah; Y. K. Mo

Journal of the American Chemical Society | 1974

Onium ions. X. Structural study of acyclic and cyclic halonium ions by carbon-13 nuclear magnetic resonance spectroscopy. Question of intra- and intermolecular equilibration of halonium ions with haloalkylcarbenium ions

George A. Olah; Philip W. Westerman; Earl G. Melby; Y. K. Mo

Journal of the American Chemical Society | 1972

Stable carbocations. CXXXIX. Nitro- and chlorohexamethylbenzeneium ions and 1-nitro- and 1-chloro-2,4,6-trifluoromesitylenium ions

George A. Olah; Henry C. Lin; Y. K. Mo

Journal of the American Chemical Society | 1972

Stable carbocations. CXXXII. Protonated unsaturated aldehydes and ketones

George A. Olah; Yuval Halpern; Y. K. Mo; Gao Liang

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George A. Olah

University of Southern California

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Carl Djerassi

Stanford University

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E. Bunnenberg

Stanford University

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Gheorghe D. Mateescu

Case Western Reserve University

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Henry C. Lin

Case Western Reserve University

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Judith A. Olah

University of Southern California

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Peter Schilling

Case Western Reserve University

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Philip W. Westerman

California Institute of Technology

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Robert E. Linder

Stanford University

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Jacob. Shen

Case Western Reserve University

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