Ya-Nang Wang

Factors affecting chelating extraction of Cr, Cu, and As from CCA-treated wood

The disposal of chromated copper arsenate (CCA)-treated waste wood is becoming a serious problem in many countries due to potential leaching of hazardous elements from in-service use in the environment or disposal of solutions after remediation; therefore, it is necessary to develop proper remediation techniques. The effects of concentration, extraction period, temperature, and sequential extraction on the extraction of Cr, Cu, and As from CCA-treated wood using [S,S]-ethylenediaminedisuccinic acid (EDDS), ethylenediaminetetraacetic acid (EDTA), and nitrilotriacetic acid (NTA) were studied. Mobility of metal in the samples was evaluated by using a sequential extraction scheme that could give the information needed to explain different extraction efficiencies for different metals. Results of long-term leaching tests of CCA-treated wood before and after EDDS extraction were used to evaluate Cr, Cu, and As leachability. Kinetic experiments showed that 6 h was the optimum extraction time for all metals and CCA-treated wood. Experimental results showed that EDDS is a very effective chelating agent for the extraction of Cr, Cu, and As from CCA-treated wood. Increased temperature significantly enhanced the extraction efficiency of CCA metals, especially Cr and As. The much better extractability of Cu compared to Cr and As by chelating agents can be attributed to the presence of larger weakly bound fractions. The CCA-treated woods after EDDS extraction have met the EPAs TCLP regulatory limit and could be classified as a non-hazardous waste according to identification standard of hazardous wastes.

Combining Cellulosic Ethanol Fermentation Waste and Municipal Solid Waste-derived Fiber with a Kraft Black Liquor-derived Binder for Recycled Paper Making

Rice straw cellulosic ethanol fermentation waste (CEFW) and municipal solid waste derived fiber (MSWF) were used as alternative fibers for recycled paper making. The fibers were mixed with old newspaper (ONP) fiber at different mass ratios to produce standard recycled papers and paperboards. A “green” adhesive binder derived from kraft black liquor (BLDB) was used to improve the physical properties of the waste-derived paper products. The values of these properties increased linearly with increasing average fiber lengths, regardless of the type of fiber used in the products. BLDB improved the physical properties of the products by 50% for papers and 85% for paperboards, and the performance of this binder was comparable to a commercial urea formaldehyde resin binder. Thermal pressing, however, did not improve the physical properties of the binder-enhanced paper products. With the addition of the adhesive binder, CEFW and MSWF showed reasonable substitution potential for ONP fiber by providing suitable tensile and bursting strength in the recycled paper products. The critical fiber length, which produced the minimum strength properties for the recycled paper products, was approximately 1020 m.