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Featured researches published by Yanxia Sun.


Ionics | 2018

Investigation of the synergetic effects of LiBF4 and LiODFB as wide-temperature electrolyte salts in lithium-ion batteries

Lijuan Zhang; Yanxia Sun; Yuan Zhou; Chunxi Hai; Shuqing Hu; Jinbo Zeng; Yue Shen; Shengde Dong; Guicai Qi; Faqiang Li

Herein, we present the use of lithium tetrafluoroborate (LiBF4) as an electrolyte salt for wide-temperature electrolytes in lithium-ion batteries. The research focused on the application of blend salts to exhibit their synergistic effect especially in a wide temperature range. In the study, LiCoO2 was employed as the cathode material; LiBF4 and lithium difluoro(oxalate)borate (LiODFB) were added to an electrolyte consisting of ethylene carbonate (EC), propylene carbonate (PC), and ethyl methyl carbonate (EMC). The electrochemical performance of the resulting electrolyte was evaluated through various analytical techniques. Analysis of the electrical conductivity showed the relationship among solution conductivity, the electrolyte composition, and temperature. Cyclic voltammetry (CV), charge-discharge cycling, and AC impedance measurements were used to investigate the capacity and cycling stability of the LiCoO2 cathode in different electrolyte systems and at different temperatures. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were applied to analyze the surface properties of the LiCoO2 cathode after cycling. The results indicated that the addition of a small amount of LiODFB into the LiBF4-based electrolyte system (LiBF4/LiODFB of 8:2) may enhance the electrochemical performance of the LiCoO2 cell over a relatively wide temperature range and improve the cyclability of the LiCoO2 cell at 60xa0°C.


CrystEngComm | 2017

Large-scale synthesis of uniformly dispersed hexagram-like gibbsite by a controlled replacement reaction

Chunxi Hai; Yuan Zhou; Lijuan Zhang; Yanxia Sun; Xiang Li; Yue Shen; Huaijin Zhan; Qier Han; Jianghua Liu; Hongbo Ren

A facile, convenient, and mild method has been developed for large-scale synthesis of uniformly dispersed 2D six-pointed star-like gibbsite micro–nano crystals with lateral size around 2.5 μm and thickness around 100 nm, through a replacement reaction between Al powder and water. Investigation of the influence of solvent in a series allows for conclusion that replacing the reactant solvent water with ethylene glycol not only effectively moderates the reaction, but also benefits control of shape, crystal structure, and dispersibility. In contrast, besides decreasing the reaction speed, the same function cannot be attributed to another inorganic solvent candidate absolute ethanol. This conclusion was supported by XRD, FE-SEM, TEM, FT-IR, TGA and PSD measurements. Moreover, the band gap of as-prepared gibbsite powder in EG–H2O mixture is 5.78 eV, which is mainly attributed to its surface low coordinated O2−. Theoretically, scale-up of this simple synthetic procedure for large-scale production of gibbsite powder with high crystallinity and purity should be very easy.


Materials Research Bulletin | 2017

Synthesis of MgO nanocrystals with abundant surface defects via a carbonization method employing CO2 gas as starting material

Chunxi Hai; Yuan Zhou; Yongsheng Du; Yanxia Sun; Jinbo Zeng; Yue Shen; Xiufeng Ren; Xiang Li; Lijuan Zhang; Ouyang Dong


Applied Surface Science | 2014

Effects of Si doping on the strain relaxation of metamorphic (Al)GaInP buffers grown on GaAs substrates

Kuilong Li; Jianrong Dong; Yanxia Sun; X.L. Zeng; Y.M. Zhao; Shuzhen Yu; Chunyu Zhao; H. Yang


Journal of Crystal Growth | 2013

Tilt generation and phase separation in metamorphic GaInP buffers grown on GaAs substrates by metal-organic chemical vapor deposition

Kuilong Li; Yanxia Sun; Jianrong Dong; Y.M. Zhao; Shuzhen Yu; Chunyu Zhao; H. Yang


Journal of Alloys and Compounds | 2017

Preparation and characterization of lithium-rich ternary cathode materials using novel chelating agent and solvent

Yanxia Sun; Yuan Zhou; Lijuan Zhang; Yue Shen; Jinbo Zeng


Journal of Alloys and Compounds | 2018

Facile triethanolamine-assisted combustion synthesized layered LiNi 1/3 Co 1/3 Mn 1/3 O 2 cathode materials with enhanced electrochemical performance for lithium-ion batteries

Jinbo Zeng; Chunxi Hai; Xiufeng Ren; Xiang Li; Yue Shen; Ouyang Dong; Lijuan Zhang; Yanxia Sun; Luxiang Ma; Xinxing Zhang; Shengde Dong; Yuan Zhou


Applied Surface Science | 2017

Humidity effects on scanning polarization force microscopy imaging

Yue Shen; Yuan Zhou; Yanxia Sun; Lijuan Zhang; Ying Wang; Jun Hu; Yi Zhang


Optical and Quantum Electronics | 2015

Effects of leakage current on the short circuit current in the dual-junction solar cells

Yanxia Sun; Kuilong Li; Jianrong Dong; X.L. Zeng; Shuzhen Yu; Yan Zhao; Chunyu Zhao; H. Yang


Journal of The Electrochemical Society | 2018

Study on Potassium Doped Modification of Li1.2Ni0.13Co0.13Mn0.54O2Materials Synthesized by Novel Method for Lithium Ion Battery

Yanxia Sun; Lijuan Zhang; Yuan Zhou; Yue Shen; Chunxi Hai; Xiang Li; Jinbo Zeng; Xiufeng Ren; Luxiang Ma; Xinxing Zhang; Shengde Dong; Guicai Qi

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Yuan Zhou

Chinese Academy of Sciences

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Yue Shen

Chinese Academy of Sciences

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Lijuan Zhang

Chinese Academy of Sciences

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Chunxi Hai

Chinese Academy of Sciences

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Jinbo Zeng

Chinese Academy of Sciences

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Xiang Li

Chinese Academy of Sciences

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Jianrong Dong

Chinese Academy of Sciences

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Kuilong Li

Chinese Academy of Sciences

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Shengde Dong

Chinese Academy of Sciences

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Shuzhen Yu

Chinese Academy of Sciences

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