Yasser A. Shaban

Photocatalytic degradation of phenol in natural seawater using visible light active carbon modified (CM)-n-TiO2 nanoparticles under UV light and natural sunlight illuminations

The photocatalytic degradation of phenol in seawater was investigated under UV and natural sunlight using visible light active carbon modified (CM)-n-TiO2 nanoparticles, synthesized via a sol-gel method. Carbon modification of n-TiO2 was performed using titanium butoxide, carbon-containing precursor, as a source of both carbon and titanium. For comparison, unmodified n-TiO2 was also synthesized by hydrolysis and oxidation of titanium trichloride in the absence of any carbon source. The presence of carbon in CM-n-TiO2 nanoparticles was confirmed by energy dispersive spectroscopy (EDS) analysis. Carbon modification was found to be responsible for lowering the bandgap energy from 3.14eV for n-TiO2 to 1.86eV for CM-n-TiO2 which in turn enhanced the photocatalytic activity of CM-n-TiO2 towards the degradation of phenol in seawater under illumination of UV light as well as natural sunlight. This enhanced photoresponse of CM-n-TiO2 is in agreement with the UV-Vis spectroscopic results that showed higher absorption of light in both UV and visible regions. The effects of catalyst dose, initial concentration of phenol, and pH were studied. The highest degradation rate was obtained at pH 3 and catalyst dose of 1.0gL(-1). The data photocatalytic degradation of phenol in seawater using CM-n-TiO2 were successfully fitted to Langmuir-Hinshelwood model, and can be described by pseudo-first order kinetics.

Solar-driven photocatalytic degradation of phenol in aqueous solution using visible light active carbon-modified (CM)-n-TiO2 nanoparticles

AbstractVisible light active carbon-modified (CM)-n-TiO2 nanoparticles were synthesized by sol/gel method. Carbon modification of n-TiO2 was performed during the synthesis process by using titanium butoxide as a carbon source in addition of being a molecular precursor of TiO2. When compared to unmodified n-TiO2, CM-n-TiO2 nanoparticles exhibited significantly higher photocatalytic activity toward the photocatalytic degradation of phenol in aqueous solution under illumination of both UV light and real sunlight. Carbon modification was found to be responsible for narrowing the bandgap energy of CM-n-TiO2 from 3.14 to 1.86 eV. The effects of catalyst dose, initial concentration of phenol, and pH on the degradation kinetics of phenol were investigated. The highest degradation rate of phenol was obtained at the optimal conditions of pH 5 and 1.0 g L−1 of CM-n-TiO2. The photocatalytic degradation of phenol using CM-n-TiO2 obeyed a pseudo-first-order kinetics according to the Langmuir–Hinshelwood model.