Yasubumi Furuya

The effect of grain boundary microstructure on Barkhausen noise in ferromagnetic materials

Abstract The Barkhausen noise (BHN) was measured in ferromagnetic materials to investigate the interaction between the grain boundary microstructure and magnetic domain walls. The grain-size effect of the BHN was studied for pure iron specimens. The Hall–Petch type relationship between the grain-size and the BHN power was found. The effect of the grain-boundary misorientation on the BHN was also studied for silicon steel specimens. The BHN power increased with increasing the grain boundary misorientation angle. It has been suggested that the arrangement of magnetic domains along a grain boundary can be affected by the grain boundary character and that hysteresis of magnetization can be optimized by controlling the grain boundary microstructure in ferromagnetic materials. The importance of understanding the behavior of magnetic domains was discussed in terms of the control of magnetic properties in ferromagnetic materials.

Microstructures and magnetic properties of rapidly solidified CoNiGa ferromagnetic shape memory alloys

The transformation characteristics of CoNiGa ribbons resemble those of bulk alloys. However, the transformation temperatures in the ribbons are higher than those of the bulk suggesting stress-induced martensites. TEM observations reveal arch typical twins and precursor tweed structures. The twins can be wavy suggesting a small boundary energy.

Combinatorial investigation of magnetostriction in Fe–Ga and Fe–Ga–Al

A high-throughput high-sensitivity optical technique for measuring magnetostriction of thin-film composition-spread samples has been developed. It determines the magnetostriction by measuring the induced deflection of micromachined cantilever unimorph samples. Magnetostriction measurements have been performed on as-deposited Fe–Ga and Fe–Ga–Al thin-film composition spreads. The thin-film Fe–Ga spreads display a similar compositional variation of magnetostriction as bulk. A previously undiscovered peak in magnetostriction at low Ga content was also observed and attributed to a maximum in the magnetocrystalline anisotropy. Magnetostrictive mapping of the Fe–Ga–Al ternary system reveals the possibility of substituting up to 8at.% Al in Fe70Ga30 without significant degradation of magnetostriction.

Effect of Ta content on martensitic transformation behavior of RuTa ultrahigh temperature shape memory alloys

Abstract Effects of Ta content on martensitic transformation (MT) behavior of Ru 100− x Ta x ( x =46–54 at.%) alloys have been investigated by differential scanning calorimetry, dilatometry, X-ray diffraction and optical microscopy. Ta content significantly affects the MT behavior of RuTa alloys. The one-stage reservible MT occurs in Ta-poor RuTa alloys with Ta content less than 49 at.%. The two-stage reservible MT takes place in near-equiatomic RuTa alloys. No reservible MT is observed in Ta-rich alloys with Ta content more then 52 at.% Ta. The MT temperatures and hysteresis of RuTa alloys decrease with increasing Ta content. The aged and thermal cycled processes are nearly no effect on the MT behavior of these alloys. The deforming way of RuTa alloys is twinning. The Ru 50 Ta 50 alloy is of the most excellent MT behavior among these RuTa alloys.

Effect of rapid solidification on giant magnetostriction in ferromagnetic shape memory iron-based alloys

Abstract Ferromagnetic shape memory Fe–29.6 at.% Pd alloy ribbons prepared by the rapid solidification, melt-spinning method, showed a giant magnetostriction of 830 microstrain when an external magnetic field of 7 kOe was applied nearly normal to the ribbon surface at room temperature. This ribbon’s magnetostriction was several times as large as conventional polycrystalline bulk’s one before rapid solidification. The magnetostriction in the rolling direction depended strongly on a direction of applied magnetic field. We considered that this phenomenon is caused by a rearrangement of activated martensite twin variants just below the austenite phase transformation temperature. We investigated their basic material properties, i.e. the dependencies of magnetostriction on temperature as well as on magnetic angular orientation to the surface, magnetic properties, crystal structure, surface texture morphology and shape memory effect of Fe–29.6 at.% Pd ribbon samples by comparing with conventional bulk sample. It can be concluded that the remarkable anisotropy of giant magnetostriction of ribbon sample is caused by the unique uniaxial-oriented fine grain structure formed by the melt-spinning method. In addition, we confirmed the possibility of rapidly solidified Fe–Pt ribbon as a new kind of iron-based ferromagnetic shape memory alloys for magnetostrictive material.

Fatigue design curve of a TiNi/Al shape memory alloy composite for aircraft stringer design

In this study, a TiNi/Al6061 shape memory alloy (SMA) composite was fabricated by the hot press method, and pressed by a roller for its strength improvement using the shape memory fiber shrinkage phenomenon. These two kinds of specimens were fabricated with 0% and 5% volume ratio and 0%, 10 % and 20% reduction ratio of TiNi alloy fiber, respectively. A fatigue test has been performed to evaluate the fatigue life for the fabricated TiNi/Al SMA composite as an S–N curve. The results from the Goodman diagram is able to illustrate the failure criterion and fatigue limit between tensile and bending fatigue strength in the fatigue characterization of TiNi/Al SMA composites.

Fabrication of multiferroic composite actuator material by combining superelastic TiNi filler and a magnetostrictive Ni matrix

This research aims to design and verify a new magnetically driven multiferroic composite actuator material which is characterized by large strain and a rapid response speed. The composite actuator material is designed to consist of a magnetostrictive Ni matrix and superelastic TiNi alloy fiber fillers whose volume fraction was changed. The spark plasma sintering (SPS) method which is characterized by short time and low temperature processing was used to join these two different material elements. Cross-sectional observation by optical micrograph, mechanical compression tests, and magnetostriction measurements were carried out to verify the perfection of the adhesion state of the TiNi filler and nickel matrix as well as the amplification effect of magnetostriction. As the experimental result, the amplification effect of about a maximum of 1.5 times magnetostriction was verified in the fabricated composite actuator.

Magnetoelectric Coupling in Multi-Ferro Fe-Pd/PZT/Fe-Pd Laminate Composites

Magnetoelectric(ME) coupling in multi-ferroic composite designed by using two material elements of Pb(Zr, Ti)O3 (PZT: 260μm) and magnetostrictive alloys(Galfenol based Fe-Ga-X(X=Al, Co), ferromagnetic shape memory Fe-Pd) was investigated. Output ME Voltage under the driving a.c.magnetic field Hac at f = 1 Hz in Fe81Ga19/PZT/ Fe81Ga19, Fe80Ga15Al5 /PZT/ Fe80Ga15Al5, Fe76Ga17Co7/PZT/ Fe76Ga17Co7 composites, in which the magnetostrictive foils(50μm thickness) were prepared by rapid solidification, increased in proportion to the actuated force than the magnetostriction.Moreover，output ME Voltage in Fe70Pd30 / PZT/ Fe70Pd30 laminates, in which the Fe70Pd30 films (10μm thickness) on PZT were deposited by sputtering method, exhibited 8 V at Hac of 175Oe, which is larger than 7.16 V for Fe76Ga17Co7 (50μm)/PZT/ Fe76Ga17Co7 (50μm) composites

Magnetic Properties and Microstructures of Rapidly Solidified FePd Alloy Ribbons

It is well known that FePd alloys are effective as a magneto-thermoelastic actuator material, because they have large magnetostriction and shape memory effect. In order to use the alloys for a micro-actuator, magnetic properties and microstructures have been examined as for rapidly solidified Fe-29.6 at% Pd alloy ribbons. The ribbons exhibit a large magnetostriction at room temperature and good shape memory effect. Magnetostriction and coercive force of the ribbons markedly depend on the direction of the applied magnetic field. Maximum values of magnetostriction and coercive force are obtained at θ = 85 degree (θ is the angle between the magnetic field and the ribbon plane). Relief effects corresponding to the formation of FCT martensite variants are observed on the grains. X-ray diffraction profile at room temperature shows that FCT martensitic phase and FCC parent phase coexist in the ribbon. Dense striations are observed in the TEM bright field images of FCT martensite plates. Selected area electron diffraction patterns revealed the striations to be thin twins.

Detection of cellular damage by hydrogen peroxide using SV40-T2 cells on shear horizontal surface acoustic wave (SH-SAW) sensor

The rat lung epithelial cell line SV40-T2 was used to develop a cellular biosensing system to assay for environmental toxicants. The novel approach on which this system is based involves direct attachment of cultured rat or human cells onto a cell-adhesive matrix on the device through which shear horizontal surface acoustic waves (SH-SAW) are transmitted using 50 MHz SAW resonator. This novel design enables sensitive monitoring of changes of the electrophysical characteristics of cells, such as their conductivity and relative permittivity. A time-dependent change of phase of SAW and change of insertion loss (change of amplitude) were observed when the cells were treated with 0.5 or 1.0 mM H2O2. The change of insertion loss was biphasic, with an early phase (1-3 h) and a late phase (3-6 h). The late phase coincided with the destruction of cell-cell tight junctions detected by measurement of the transepithelial electrical resistance and paracellular permeability; in contrast, the early phase coincided with the destruction of intracellular actin filaments by H2O2. The early-phase effect of H2O2 on phase shift may be attributable to the change of intracellular permittivity by a change of cellular polarity. Immunofluorescence microscopy showed the disappearance of zonula occludens protein 1 from the region of cell-cell contact. These results suggest the correlation between the change of insertion loss as an SAW parameter and the destruction of tight junctions of the cells on the SH-SAW device in the late phase.