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Featured researches published by Yasuhiro Kabasawa.


Tetrahedron Letters | 1985

Photochemical rearrangement approach to the total synthesis of (±)-pinguisone and (±)-deoxopinguisone

Tadao Uyehara; Yasuhiro Kabasawa; Tadahiro Kato; Toshiaki Furuta

Abstract The total synthesis of (±)-pinguisone and (±)-deoxopinguisone, the unusual [5–6], fused-ring sesquiterpenes, was accomplished by the photochemical transformation of the bicyclo [3.2.2]non-6-en-2-one into the bicyclo [4.3.0]non-4-en-7-one.


Tetrahedron Letters | 1984

Total synthesis of “(±)-senoxydene”

Tetsuto Tsunoda; Yasuhiro Kabasawa; Shô Itô; Mitsuaki Kodama

Abstract A triquinane having the structure proposed for senoxydene has been synthesized in a regio and stereoselective manner. However, the difference in their spectral data suggests that the structure of the natural senoxydene is incorrect and requires revision.


Journal of The Chemical Society, Chemical Communications | 1986

Total synthesis of (±)-ptilocaulin starting from tropolone

Tadao Uyehara; Toshiaki Furuta; Yasuhiro Kabasawa; Jun-ichi Yamada; Tadahiro Kato

A rearrangement approach to the antitumour antibiotic (±)-ptilicaulin was accomplished by photochemical [1,3]-acyl migration of 1-butyl-exo-8-methylbicyclo[3.2.2]non-6-en-2-one, derived from 1-methoxy-exo-3-methylbicyclo[3.2.2]non-6-en-2-one via the pinacol-type rearrangement, to give the [5–6] fusedring skeleton.


Bulletin of the Chemical Society of Japan | 1986

Rearrangement Approaches to Cyclic Skeletons. IV. The Total Synthesis of (±)-Pinguisone and (±)-Deoxopinguisone Based on Photochemical [1,3] Acyl Migration of a Bicyclo[3.2.2]non-6-en-2-one

Tadao Uyehara; Yasuhiro Kabasawa; Tadahiro Kato


Bulletin of the Chemical Society of Japan | 1986

Rearrangement Approaches to Cyclic Skeletons. III. Practical Route to cis-Bicyclo[4.3.0]non-4-en-7-ones Based on Photochemical [1,3] Acyl Migration of Bicyclo[3.2.2]non-6-en-2-ones

Tadao Uyehara; Yasuhiro Kabasawa; Toshiaki Furuta; Tadahiro Kato


Chemistry Letters | 1984

Alkoxide-accelerated [1,3] sigmatropic shifts of bicyclo[3.2.2]non-6-en-2-ols. Substituent effects and tandem [1,3]-[3,3] sigmatropic rearrangements

Tadao Uyehara; Kazuhiro Ohmori; Yasuhiro Kabasawa; Tadahiro Kato


ChemInform | 1986

Rearrangement Approaches to Cyclic Skeletons. Part 3. Practical Route to cis-Bicyclo[4.3.0]non-4-en-7-ones Based on Photochemical [1,3] Acyl Migration of Bicyclo[3.2.2]non-6-en-2-ones.

Tadao Uyehara; Yasuhiro Kabasawa; Toshiaki Furuta; Tadahiro Kato


ChemInform | 1986

Total Synthesis of (±)-Ptilocaulin Starting from Tropolone.

Tadao Uyehara; Toshiaki Furuta; Yasuhiro Kabasawa; Jun-ichi Yamada; Tadahiro Kato


ChemInform | 1985

PHOTOCHEMICAL REARRANGEMENT APPROACH TO THE TOTAL SYNTHESIS OF (.+-.)-PINGUISONE AND (.+-.)-DEOXOPINGUISONE

Tadao Uyehara; Yasuhiro Kabasawa; Tadahiro Kato; Toshiaki Furuta


ChemInform | 1985

ALKOXIDE-ACCELERATED (1,3) SIGMATROPIC SHIFTS OF BICYCLO(3.2.2)NON-6-EN-2-OLS. SUBSTITUENT EFFECTS AND TANDEM (1,3)-(3,3) SIGMATROPIC REARRANGEMENTS

Tadao Uyehara; K. Ohmori; Yasuhiro Kabasawa; Tadahiro Kato

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Mitsuaki Kodama

Tokushima Bunri University

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Shô Itô

Tokushima Bunri University

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