Yeong-Deuk Shin
Gwangju Institute of Science and Technology
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Featured researches published by Yeong-Deuk Shin.
Polymer | 2003
Jun-Hwan Ahn; Yeong-Deuk Shin; Sun-Young Kim; Jae-Suk Lee
n-Hexyl isocyanate (HIC) was polymerized at different reaction temperatures and times, using alkali metal naphthalenide, via anionic polymerization in THF. To prevent the formation of trimers, the polymerization of HIC was also performed utilizing sodium tetraphenylborate (NaBPh4) as a common ion salt. As the reaction temperature decreases, yield of the polymer increases due to stabilization of the active amidate anion at low temperature. In the absence of the additive, a quantitative yield was obtained at −98 °C. However, after most of the monomer was polymerized, further reaction led to trimerization. This was prevented in the presence of NaBPh4 effectively and the living polymerization was performed successfully at −98 °C. The reaction rate retarded with increasing concentration of NaBPh4, the optimum concentration of NaBPh4 was 10 times the concentration of the initiator for the living polymerization of HIC. The living system led to the polymers of molecular weight (MW) as high as 50,000 g/mol. The observed MW was well in agreement with the calculated one. At the higher reaction temperature, −78 °C, the quantitative yield was obtained at 2 min of the reaction time, however the living character was not observed at longer reaction time. The study indicated that the amidate anion was stabilized using NaBPh4 having bulky contact ion pair. The block copolymer of HIC with isoprene, poly(HIC-b-isoprene-b-HIC), was synthesized with help of the living character of polyisoprene and NaBPh4. The morphology and composition of the block copolymers were investigated using TEM and 1H NMR, respectively.
Polymer | 2001
Yeong-Deuk Shin; Jun-Hwan Ahn; Jae-Suk Lee
Abstract Polyisocyanates of 2-[4-(4-nitrophenylazo)-N-ethylphenyl amino]ethoxy carbonyl amino hexyl isocyanate, DR1NCO, and (s)-(−)-2-methyl-1-butyloxy carbonyl amino hexyl isocyanate, MBI, were synthesized by anionic polymerization using sodium naphthalenide as an initiator in THF at −98°C. In the polymerization reaction, crown ether (15C5) and octyl isocyanate (Oct-NCO) were used to suppress side reactions such as backbiting or chain transfer reaction. In the homopolymerization of DR1NCO, the polymers with high yield (∼94%) were obtained due to suppression of backbiting by 15C5. In the random copolymerization of DR1NCO with MBI, the chain transfer reaction was suppressed due to the low reactivity of anionic chain end induced by octyl isocyanate. The random copolymers showed the optical activity in CD and ORD measurements, and specific rotations increased with increasing the component of MBI.
Macromolecular Rapid Communications | 2001
Yeong-Deuk Shin; Jun-Hwan Ahn; Jae-Suk Lee
A chiral polyisocyanate, poly[6-{1-[(S)-(–)-2-methylbutyl]oxycarbonylamino}hexyl isocyanate], was synthesized using sodium diphenylmethanide and sodium naphthalenide as unidirectional and bidirectional initiators, respectively, via anionic polymerization in THF at –98°C. NaBPh4 as a common ion salt was used to produce the polymer in quantitative yield and with narrow molecular-weight distribution. The polymer showed different optical activity depending on the nature of the initiator.
Molecular Crystals and Liquid Crystals | 2001
Eun-Mi Seo; Mi Jeong Kim; Yeong-Deuk Shin; Jae-Suk Lee; Dong-Yu Kim
Abstract The surface of azobenzene polymer films could be photo-fabricated into various surface relief structures. Most of surface grating formation studies were focused on polymeric materials because of the easy film formation. In this work, we investigated the photo-manipulation of low molecular weight tri-isocyanate cyclic compounds containing azobenzenes which form glassy films upon spin casting. Theses non-polymeric films were capable of forming efficient surface gratings when irradiated to an interference pattern of polarized laser beams. We examined the difference of the grating formation behaviors between the isocyanate trimer and polyisocyanate films containing azobenzene groups with the same chemical compositions. The surface grating formation on the trimer film was more efficient than on the polymer films even though both films have similar Tgs.
Molecular Crystals and Liquid Crystals | 2000
Yeong-Deuk Shin; Young-Sun Cho; Jang-Joo Kim; Jae-Suk Lee; S. H. Han; J. W. Wu
Abstract Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with optically functionalized isocyanates containing disperse red 1 (DR1NCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78°C for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.
Molecular Crystals and Liquid Crystals | 2001
Yeong-Deuk Shin; Jun-Hwan Ahn; Jae-Suk Lee
Abstract Random copolymers, an optically functionalized isocyanate containing disperse red 1 (DR1NCO) with a chiral isocyanate containing (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization in THF at -98°C with Na-Naph as a two-directional initiator. As the contents of MBI in the copolymer increased, the optical rotation of the polymer was also increased. To study about the optical activity change with initiator systems, homo polymer of MBI was synthesized with one-directional and two-directional initiator. The difference of optical activity in both systems was investigated using Circular Dichroism (CD) spectroscopy and optical rotation.
Macromolecules | 2001
Yeong-Deuk Shin; Sun-Young Kim; Jun-Hwan Ahn; Jae-Suk Lee
Journal of the American Chemical Society | 2005
Jun-Hwan Ahn; Yeong-Deuk Shin; G. Yogendra Nath; Sang-Yoon Park; M. Shahinur Rahman; Shashadhar Samal; Jae-Suk Lee
Journal of Polymer Science Part A | 2005
Yeong-Deuk Shin; Sang-Ho Han; Shashadhar Samal; Jae-Suk Lee
Optical Materials | 2007
Chaemin Chun; Eun-Mi Seo; Mi Jeong Kim; Yeong-Deuk Shin; Jae-Suk Lee; Dong-Yu Kim