Yeong-Joon Park

Effect of zirconia surface treatments on the shear bond strength of veneering ceramic

STATEMENT OF PROBLEM Various surface treatments of zirconia have been recommended for veneering ceramics. However, it has not been determined which of these treatments produces the highest bond strength. PURPOSE This study examined the effects of various surface treatments on the shear bond strength of zirconia and veneering ceramic. MATERIAL AND METHODS Square-shaped (5 × 10 × 10 mm) zirconia (Everest) specimens were divided into 4 groups (n=8) according to surface treatment as follows: group C, grinding with #320 diamond disc (control); group A, airborne-particle abrasion with 110 μm Al(2)O(3); group L, application of liner (Cerabien); and group AL, airborne-particle abrasion with 110 μm Al(2)O(3) and application of liner. A cylinder of veneering ceramic (2.4 mm in diameter and 3 mm in height) (Cerabien) was fabricated and fired on the zirconia specimens. The shear bond strength was tested using a universal testing machine. The data were analyzed statistically using a 1-way ANOVA and Tukeys multiple comparisons test (α=.05). The interface and fractured surfaces of the specimens were also evaluated by field emission scanning electron microscopy (FE-SEM). RESULTS The mean and SD values for the shear bond strength of the groups ranged from 27.87 ± 3.59 MPa (for group L) to 36.63 ± 2.96 MPa (for group A). The 1-way ANOVA revealed a significant difference between groups (P=.001). The airborne-particle abrasion group showed significantly higher bond strength than liner applied groups (L, AL) (P<.05). The SEM revealed that liner-applied groups (L, AL) showed primarily adhesive failure. Complete delamination and microspaces were also observed in the liner-applied groups. CONCLUSIONS The mean in vitro shear bond strength of veneering ceramic on zirconia treated with airborne-particle abrasion was significantly higher than that subjected to liner-applied treatments.

Improvement of the Properties of Mineral Trioxide Aggregate by Mixing with Hydration Accelerators

INTRODUCTION Mineral trioxide aggregate (MTA) is used widely in endodontic therapy. This study examined the setting time, compressive strength, and pH of MTA mixed with several hydration accelerators (calcium chloride, low-dose citric acid, calcium lactate gluconate solution). METHODS Group 1 (control) was obtained by mixing MTA with distilled water. In group 2, MTA containing 10% calcium chloride was mixed with distilled water. In group 3, MTA was mixed with 0.1% citric acid. In group 4, MTA was mixed with a calcium lactate gluconate solution. The setting time, compressive strength, and pH were examined. RESULTS The setting time of MTA mixed with hydration accelerators was significantly shorter than that of MTA mixed with water (P < .01). In particular, replacing distilled water with a calcium lactate gluconate solution provided a significant decrease in setting time. The compressive strengths of MTA mixed with hydration accelerators were significantly lower than that of MTA mixed with water (P < .01), but those values increased with time. The pH of MTA mixed with hydration accelerators was significantly lower than that of MTA mixed with water (P < .01) but stable at a high level (pH 11-12). CONCLUSIONS Hydration accelerators improved the setting time of MTA. Nevertheless, more study will be needed to improve MTA without impairing its preexisting advantages.

Effect of poling conditions on growth of calcium phosphate crystal in ferroelectric BaTiO3 ceramics

Recently, ceramic materials have been given a lot of attention as candidates for implant materials, since they possess biologically favorable characteristics for osseointegration. Among them, BaTiO3 (BTO) ceramics are ferroelectric and piezoelectric after poling treatments. However, little or no information is available on the poling condition of BTO and their effect on calcium phosphate (CaP) formation. In this study, the effect of poling conditions on the formation of CaP layer was investigated. It was observed from this study that CaP was formed on negatively charged BTO surfaces. An increase in Ca/P ratio to 1.67 was observed when the poling temperature was increased above the Curie temperature. On positively charged BTO, no CaP layer was observed.

Chemical constitution, physical properties, and biocompatibility of experimentally manufactured Portland cement.

INTRODUCTION An experimental Portland cement was manufactured with pure raw materials under controlled laboratory conditions. The aim of this study was to compare the chemical constitution, physical properties, and biocompatibility of experimentally manufactured Portland cement with those of mineral trioxide aggregate (MTA) and Portland cement. METHODS The composition of the cements was determined by scanning electron microscopy (SEM) and energy-dispersive x-ray analysis (EDAX). The setting time and compressive strength were tested. The biocompatibility was evaluated by using SEM and XTT assay. RESULTS SEM and EDAX revealed the experimental Portland cement to have a similar composition to Portland cement. The setting time of the experimental Portland cement was significantly shorter than that of MTA and Portland cement. The compressive strength of the experimental Portland cement was lower than that of MTA and Portland cement. The experimental Portland cement showed a similar biocompatibility to MTA. CONCLUSIONS The experimental Portland cement might be considered as a possible substitute for MTA in clinical usage after further testing.

Marginal accuracy and internal fit of machine-milled and cast titanium crowns

STATEMENT OF PROBLEM Titanium is an alternative tooth restorative material because of a its biocompatibility and mechanical properties. However, there is little information on the marginal accuracy of a complete titanium crown with different margin configurations. PURPOSE This study examined the effect of fabrication method and margin configuration on the marginal and internal fit of complete titanium crowns. MATERIAL AND METHODS An acrylic resin maxillary first molar was prepared with shoulder (buccal), chamfer (palatal), and knife edge (proximal) margin configurations. Forty crowns were produced and then divided into 2 groups according to the manufacturing method (casting method or CAD/CAM technique) (n=20). Each crown was luted to the original stone die with zinc phosphate cement. The margin of the crown, center point of the axial wall, and occlusal area were measured with a 3-dimensional measuring microscope. An independent t-test (internal gap) and repeated measures 2-way ANOVA (marginal gap) were used for statistical analysis (α=.05). RESULTS The mean marginal gap of the cast group was significantly smaller than that of the CAD/CAM group (P<.001). The margin configuration affected the measured marginal discrepancy (P<.001). In both groups, the mean marginal gap of the chamfer and shoulder margin was significantly smaller than that of the knife-edge margin (P<.001). CONCLUSIONS Castings-produced titanium crowns with a better marginal fit than the CAD/CAM technique. The knife-edge margin exhibited the greatest marginal discrepancy.

Functionally graded Ti/HAP coatings on Ti–6Al–4V obtained by chemical solution deposition

Graded Ti100−x/HAPx (x=0 – 100%) films were prepared on Ti–6Al–4V implants by chemical solution deposition using a titanium-isopropoxide chelated by acetylacetone, calcium nitrate and phosphoric acid as starting materials. Ti/HAP solutions with variable HAP contents from 0 to 100% at 10% intervals were spin coated on the substrates and prefired at 500 °C. X-ray diffraction and field emission-scanning electron microscope analysis showed that Ti/HAP coatings were obtained with a dense interface between coating and substrate by final annealing at 500 °C and higher. The effectiveness of the functionally graded HAP/Ti coatings was discussed based on the analysis of the variation of Ca and P contents in simulated body fluid as a function of annealing temperature.

Stress analysis of a cantilevered fixed partial denture with normal and reduced bone support

A two-dimensional finite element model was constructed to analyze the simulated mechanical behavior of a cantilevered fixed partial denture. The variations of the models were made by altering the degree of bone support, the number of splinted abutments, and the length of the pontics. High stress concentrations were observed around the connectors of the fixed prosthesis and the tooth closest to the cantilever. Reduced bone support increased the deflection and stress concentrations. There was reduction in displacement and stress concentration when the teeth were splinted together. To improve the prognosis of the fixed partial denture cantilever, the number of abutments should be increased and the number of pontics decreased.

Cytotoxicity and physical properties of tricalcium silicate-based endodontic materials

Objectives The aim of this study was to evaluate the cytotoxicity, setting time and compressive strength of MTA and two novel tricalcium silicate-based endodontic materials, Bioaggregate (BA) and Biodentine (BD). Materials and Methods Cytotoxicity was evaluated by using a 2,3-bis(2-methoxy-4-nitro-5-sulfophenyl)-5-((phenylamino)carbonyl)-2H-tetrazolium hydroxide (XTT) assay. Measurements of 9 heavy metals (arsenic, cadmium, chromium, copper, iron, lead, manganese, nickel, and zinc) were performed by inductively coupled plasma-mass spectrometry (ICP-MS) of leachates obtained by soaking the materials in distilled water. Setting time and compressive strength tests were performed following ISO requirements. Results BA had comparable cell viability to MTA, whereas the cell viability of BD was significantly lower than that of MTA. The ICP-MS analysis revealed that BD released significantly higher amount of 5 heavy metals (arsenic, copper, iron, manganese, and zinc) than MTA and BA. The setting time of BD was significantly shorter than that of MTA and BA, and the compressive strength of BA was significantly lower than that of MTA and BD. Conclusions BA and BD were biocompatible, and they did not show any cytotoxic effects on human periodontal ligament fibroblasts. BA showed comparable cytotoxicity to MTA but inferior physical properties. BD had somewhat higher cytotoxicity but superior physical properties than MTA.

Effect of Nb on the Microstructure, Mechanical Properties, Corrosion Behavior, and Cytotoxicity of Ti-Nb Alloys

In this paper, the effects of Nb addition (5–20 wt %) on the microstructure, mechanical properties, corrosion behavior, and cytotoxicity of Ti-Nb alloys were investigated with the aim of understanding the relationship between phase/microstructure and various properties of Ti-xNb alloys. Phase/microstructure was analyzed using X-ray diffraction (XRD), SEM, and TEM. The results indicated that the Ti-xNb alloys (x = 10, 15, and 20 wt %) were mainly composed of α + β phases with precipitation of the isothermal ω phase. The volume percentage of the ω phase increased with increasing Nb content. We also investigated the effects of the alloying element Nb on the mechanical properties (including Vickers hardness and elastic modulus), oxidation protection ability, and corrosion behavior of Ti-xNb binary alloys. The mechanical properties and corrosion behavior of Ti-xNb alloys were found to be sensitive to Nb content. These experimental results indicated that the addition of Nb contributed to the hardening of cp-Ti and to the improvement of its oxidation resistance. Electrochemical experiments showed that the Ti-xNb alloys exhibited superior corrosion resistance to that of cp-Ti. The cytotoxicities of the Ti-xNb alloys were similar to that of pure titanium.

Surface characteristics of thermally treated titanium surfaces.

Purpose The characteristics of oxidized titanium (Ti) surfaces varied according to treatment conditions such as duration time and temperature. Thermal oxidation can change Ti surface characteristics, which affect many cellular responses such as cell adhesion, proliferation, and differentiation. Thus, this study was conducted to evaluate the surface characteristics and cell response of thermally treated Ti surfaces. Methods The samples were divided into 4 groups. Control: machined smooth titanium (Ti-S) was untreated. Group I: Ti-S was treated in a furnace at 300℃ for 30 minutes. Group II: Ti-S was treated at 500℃ for 30 minutes. Group III: Ti-S was treated at 750℃ for 30 minutes. A scanning electron microscope, atomic force microscope, and X-ray diffraction were used to assess surface characteristics and chemical composition. The water contact angle and surface energy were measured to assess physical properties. Results The titanium dioxide (TiO2) thickness increased as the treatment temperature increased. Additional peaks belonging to rutile TiO2 were only found in group III. The contact angle in group III was significantly lower than any of the other groups. The surface energy significantly increased as the treatment temperature increased, especially in group III. In the 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay, after 24 hours of incubation, the assessment of cell viability showed that the optical density of the control had a higher tendency than any other group, but there was no significant difference. However, the alkaline phosphatase activity increased as the temperature increased, especially in group III. Conclusions Consequently, the surface characteristics and biocompatibility increased as the temperature increased. This indicates that surface modification by thermal treatment could be another useful method for medical and dental implants.