Yih-Her Chang

Preparation of gradient-index (GRIN) polymer fibers for imaging applications

A closed extrusion process combined with a core-shell separation die design is developed in this study for preparing gradient index (GRIN) polymer fibers with a quadratic distribution of the refractive index. The material system used in this investigation is methyl methacrylate (MMA, n = 1.49) and benzyl methacrylate (BzMA, n = 1.568). The refractive index differences between the center and the periphery (Δn) of the prepared polymer fibers increase from 0.0115 to 0.020 when BzMA in the reactant mixtures increases from 17 to 28%. This finding would suggest that increasing the high refractive index monomer in the reactant mixture increased Δn. The Δn values decrease from 0.018 to 0.0135 when the diffusion zone temperature increases from 70 to 90°C. The diffusion rates of the monomers increase with the temperature, thereby causing BzMA and MMA to distribute more uniformly at a higher temperature than at a lower one. This uniform distribution leads to the decrease of Δn with an increasing temperature. The prepared GRIN polymer fibers have potential applications as imaging lenses for scanners, fax machines, and copiers.

A novel method for preparing gradient index (GI) plastic rods

SummaryThe initiator diffusion technique was used in this study to prepare the gradient index(GI) plastic rods, in which two kinds of initiators were used, i.e., thermal initiator and redox initiator. Experimental results showed that a GI plastic rod with a parabolic profile of refractive index was obtained by the initiator diffusion technique. The difference of the refractive index from the center to the periphery (Δn) of the plastic rods was in the range of 0.004–0.014. Δn increased with increasing temperature due to the increase of the gel effect and diffusion rates of monomers at a higher temperature. Furthermore, the GI plastic rod had substantially less defects, e.g., bubbles and opaqueness, than that prepared from interfacial-gel copolymerization.